A multi-layer electrophotographic photosensitive member includes a conductive substrate and a photosensitive layer. The photosensitive layer includes a charge generating layer and a charge transport layer. The charge generating layer contains a charge generating material. The charge transport layer contains a charge transport material, a binder resin, and silica particles. The charge transport layer is a monolayer. The charge transport layer is disposed as an outermost surface layer of the multi-layer electrophotographic photosensitive member. The silica particles have a content of at least 0.5 parts by mass and no greater than 15 parts by mass relative to 100 parts by mass of the binder resin. The binder resin includes a polyarylate resin. The polyarylate resin has a repeating unit represented by general formula (I) shown below. In general formula (I), R.sub.1-R.sub.3 and Y are defined as those described in the specification. ##STR00001##

Electrophotographic photoreceptor including a conductive substrate, an organic photosensitive layer on an outer peripheral surface of the conductive substrate, and an inorganic protective layer on an outer peripheral surface of the organic photosensitive layer, the inorganic protective layer containing gallium and oxygen. A volume resistivity of an inner region of the inorganic protective layer, the inner region extending 0.2 m or about 0.2 m from an inner peripheral surface of the inorganic protective layer in a thickness direction, and a volume resistivity of an outer region of the inorganic protective layer, the outer region extending 0.2 m or about 0.2 m from an outer peripheral surface of the inorganic protective layer in the thickness direction, are both 6.010.sup.7 .Math.cm or more and 4.010.sup.8 .Math.cm or less or about 6.010.sup.7 .Math.cm or more and about 4.010.sup.8 .Math.cm or less.

An electrophotographic photoreceptor causing no image defect even in long-term use and has excellent wear performance, a method of producing the same, and an electrophotographic device are provided. The electrophotographic photoreceptor includes a photosensitive layer on a conductive substrate. The slope k of a straight line obtained by plotting the average film density of outermost layer and the boiling point of solvent used for the formation of the outermost layer along the ordinate and the abscissa, respectively, is 1.50E-4 (g/cm.sup.3.Math. C.) or greater, and the difference in film density of the outermost layer between the surface side and the side close to the conductive substrate is 0.030 g/cm.sup.3 or less.

An electrophotographic photoreceptor includes a conductive substrate and a photosensitive layer of a single-layer type disposed on the conductive substrate. The photosensitive layer has an absorption coefficient of 0.008 or less at a wavelength of 1000 nm and contains a binder resin, a charge generating material, an electron transporting material, and a hole transporting material. The charge generating material is at least one selected from a hydroxygallium phthalocyanine pigment and a chlorogallium phthalocyanine pigment and is contained in an amount of 0.9% by weight or more and 1.8% by weight or less relative to the binder resin.

A method of forming an overcoat layer. The method comprises providing a substrate having an imaging structure formed thereon, the imaging structure comprising (i) a charge transport layer and a charge generating layer, or (ii) an imaging layer comprising both charge generating material and charge transport material. An overcoat composition is deposited on the imaging structure, the overcoat composition comprising a charge transport molecule, a fluorinated building block, a leveling agent, a liquid carrier and optionally a first catalyst. The fluorinated building block is a fluorinated alkyl monomer substituted at the and positions with a hydroxyl, carboxyl, carbonyl or aldehyde functional group or the anhydrides of any of those functional groups. The overcoat composition is cured to form an overcoat layer that is a fluorinated structured organic film, the curing comprising treating an outer surface of the overcoat composition with at least one cross-linking process. The crosslinking process forms a cross-linking gradient in the overcoat layer. If the overcoat composition comprises the first catalyst, there is an insufficient amount of the first catalyst to fully cross-link the overcoat layer.

An electrophotographic photosensitive member with suppressed potential variation even in the case that a protective layer including a cured material of a composition having a polymerizable functional group is used is provided. An electrophotographic photosensitive member including a support, a charge generation layer, a charge transport layer containing a charge transporting material, and a protective layer, in the order presented, wherein the charge transport layer contains a polycarbonate resin having a structure selected from a group A and a structure selected from a group B, and the protective layer includes a cured material of a composition containing a compound having at least a functional group selected from chain-polymerizable functional groups and sequential polymerizable functional groups.

An electrophotographic photoreceptor includes a conductive substrate and a single-layer-type photosensitive layer on the conductive substrate. The single-layer-type photosensitive layer contains a binder resin, a charge generating material, an electron transporting material, and two hole transporting materials having different redox potentials. The two hole transporting materials are a hole transporting material A and a hole transporting material B that has a redox potential lower than that of the hole transporting material A. The ratio A/B of a weight of the hole transporting material A to a weight of the hole transporting material B is about 12/1 or more and about 36/1 or less.

An electrophotographic photosensitive member includes a conductive base, and a single-layer photosensitive layer disposed directly on the conductive base and containing a charge generation material. A difference between a work function of the conductive base and an electron affinity of the charge generation material is in a range of from about 0.1 to about +0.1 eV. A difference between a current Ia and a current Ib is in a range of from about 5.510.sup.8 to about 9.210.sup.8 [A/cm.sup.2] when a gold electrode is provided on the photosensitive layer, where the current Ia is a current when an electric field is applied by applying a voltage so that the gold electrode becomes positive, and the current Ib is a current when an electric field is applied by applying a voltage so that the conductive base becomes positive.

An electrophotographic photosensitive member includes a conductive substrate and a photosensitive layer. The photosensitive layer is a single-layer photosensitive layer. The photosensitive layer contains a charge generating material, a hole transport material, an electron transport material, and a binder resin. The binder resin contains a polyarylate resin (1). The polyarylate resin is represented by general formula (1). The photosensitive layer has a scratch resistance depth of no greater than 0.50 m. The photosensitive layer has a Vickers hardness of at least 17.0 HV.

##STR00001##

An electrophotographic photosensitive member includes a conductive substrate and a photosensitive layer. The photosensitive layer is a single layer. The photosensitive layer contains a charge generating material, a hole transport material, an electron transport material, and a binder resin. The photosensitive layer has a scratch resistance depth of no greater than 0.50 m.