Patent classifications
G03G5/061446
ELECTROPHOTOGRAPHIC PHOTORECEPTOR, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS
An electrophotographic photoreceptor includes a conductive substrate, and a lamination type photosensitive layer disposed on the conductive substrate and including a charge generation layer and a charge transport layer in this order, in which the charge transport layer contains at least one resin selected from a polyester resin or a polycarbonate resin, and in a case where a Martens hardness and an indentation hardness, which are acquired by an indentation test performed on the charge transport layer to a depth of 0.5 μm, are respectively defined as HM (N/mm.sup.2) and nIT (N/mm.sup.2), Relational Equation (0) is satisfied, an elastic deformation modulus is 45% or greater and 70% or less, and a tensile elastic modulus of the charge transport layer is 2,300 MPa or greater and 5,000 MPa or less,
nIT=a×HM−b(a=2±0.2,b=100±20). (0)
ELECTROPHOTOGRAPHIC PHOTORECEPTOR, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS
An electrophotographic photoreceptor includes a conductive substrate, and a lamination type photosensitive layer disposed on the conductive substrate and including a charge generation layer and a charge transport layer, in which the charge transport layer contains a polyester resin having a structure represented by Formula (1) at a terminal and a charge transport material, and in a case where a weight-average molecular weight Mw of the polyester resin is defined as A (×10,000), a value of a ratio M1/M2 of a mass M1 of the charge transport material to a mass M2 of an entire charge transport layer is defined as Cs, and an average thickness of the charge transport layer is defined as Ds (μm), expressions of 7≤A≤40, 0.28≤Cs≤0.55, 27≤Ds≤50, and 5.0≤(A×Ds)/(Cs×100)≤70 are satisfied,
##STR00001## in Formula (1), nd represents an integer of 0 or greater and 4 or less, nd number of Rd's each independently represent a hydrocarbon group having 1 or more and 4 or less carbon atoms, L represents an ether bond or a —O—C(═O)— group, and * represent a bonding portion.
Positive charging electrophotographic photoreceptor, electrophotographic cartridge and image forming apparatus
The object of the present invention is to provide a positive charging electrophotographic photoreceptor having high sensitivity, low residual potential, and excellent chargeability, and relates to a positive charging electrophotographic photoreceptor including a conductive support, a photosensitive layer, and a protective layer in this order, the photosensitive layer containing a charge generation substance, a positive hole transport substance, and an electron transport substance in the same layer, in which the positive hole transport substance includes at least one of the compounds represented by any one of the following formulas (1) to (5), and a binder resin of the protective layer is an alcohol-soluble thermoplastic resin, providing that the symbols in the formula are defined in the specification. ##STR00001##
Terphenyl compound, electrophotographic photosensitive member, and method for producing terphenyl compound
A compound is represented by general formula (1). In general formula (1), R.sup.1 and R.sup.2 each represent, independently of one another, a hydrogen atom, a methyl group, or an ethyl group, and a sum of the number of carbon atoms of the chemical group represented by R.sup.1 and the number of carbon atoms of the chemical group represented by R.sup.2 is 2. R.sup.3 and R.sup.4 each represent, independently of one another, a hydrogen atom, a methyl group, or an ethyl group, and a sum of the number of carbon atoms of the chemical group represented by R.sup.3 and the number of carbon atoms of the chemical group represented by R.sup.1 is 2. A photosensitive layer of an electrophotographic photosensitive member contains at least a charge generating material, a hole transport material, and a binder resin. The hole transport material includes a compound represented by general formula (1) ##STR00001##
ELECTROPHOTOGRAPHIC PHOTOCONDUCTOR, METHOD OF MANUFACTURING THE SAME, AND ELECTROPHOTOGRAPHIC DEVICE
Provided are an electrophotographic photoconductor being resistant to abrasion even in long-term use, having highly sensitive electric characteristics, being capable of maintaining a high retention rate, and being capable of providing a stable image without filming, a method of manufacturing the same, and an electrophotographic device. The photoconductor includes an electroconductive substrate (1), a charge generation layer (3), and a charge transport layer (4); the charge transport layer contains a hole transport material, a resin binder, an electron transport material, and an inorganic oxide; the charge generation layer contains a charge generation material; the masses of the hole transport material, the resin binder, the electron transport material, and the inorganic oxide in the charge transport layer respectively denoted by a to d satisfy 1.5≤b/a≤5.7, 0.005≤c/a≤0.35, 0.05≤d/a≤0.70, a≥c+d, and c/d≥0.01; the hole transport material contains a compound expressed by formula (A-1); and the charge generation material contains titanyl phthalocyanine having an exothermic peak at 251±5° C., a half-value width of the exothermic peak equal to or less than 15° C., and a heating value equal to or greater than 1.0 mJ/mg when a temperature rise condition is 20° C./min in differential scanning calorimetry, and having an X-ray diffraction peak at 27.2±0.3°.
##STR00001##
Electrophotographic photosensitive member, process cartridge, and image forming apparatus
An electrophotographic photosensitive member includes a conductive substrate and a photosensitive layer. The photosensitive layer is a single layer. The photosensitive layer contains a charge generating material, a hole transport material, an electron transport material, and a binder resin. The hole transport material includes a compound represented by chemical formula (1-1) or (1-2). The photosensitive layer further contains an n-type pigment. The n-type pigment is preferably an azo pigment or a perylene pigment. ##STR00001##
Electrophotographic photosensitive member, process cartridge, and image forming apparatus
A photosensitive layer included in an electrophotographic photosensitive member contains at least a charge generating material, a hole transport material, and a binder resin. The hole transport material includes a compound (1). The binder resin includes a polyarylate resin having at least one repeating unit (10) and at least one repeating unit (11). Alternatively, the binder resin includes a polycarbonate resin having a repeating unit (20) and a repeating unit (21). The general formulas (1), (10), (11), (20), and (21) are as follows ##STR00001##
Photosensitive body for electrophotography, method for producing same and electrophotographic apparatus
An electrophotographic photoreceptor includes a conductive substrate; and a photosensitive layer arranged on the conductive substrate and containing, as a charge generating material, any one material selected from the group consisting of titanyl phthalocyanines, metal-free phthalocyanines, chlorogallium phthalocyanines and hydroxygallium phthalocyanines; and, as an electron transporting material, a naphthalene tetracarboxylic acid diimide compound represented by Formula (1) below, where R.sup.1 and R.sup.2 each represent a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, an alkylene group, an alkoxy group, an alkyl ester group, a phenyl group optionally having a substituent, a naphthyl group optionally having a substituent, or a halogen element; and R.sup.1 and R.sup.2 are optionally the same or different: ##STR00001##
The photoreceptor realizes a stable print density even in a low-temperature environment by suppressing a reduction in print density that is caused by potential fluctuation of the photoreceptor in the low-temperature environment.
Image forming apparatus and image forming method
In an image forming apparatus, a cleaning member is pressed against a circumferential surface of an image bearing member and collects a toner remaining on the circumferential surface of the image bearing member. The toner has a number average roundness of 0.965 to 0.998. The toner has a D.sub.50 of 4.0 m to 7.0 m. A linear pressure of the cleaning member on the circumferential surface of the image bearing member is 10 N/m to 40 N/m. The image bearing member includes a single-layer photosensitive layer containing a charge generating material and a hole transport material. Ionization potential Ip.sub.HTM of the hole transport material and ionization potential Ip.sub.CGM of the charge generating material satisfy mathematical formula (1) Ip.sub.HTM5.30 eV, mathematical formula (2) Ip.sub.CGM5.30 eV, and mathematical formula (3) 0.09 eV|Ip.sub.HTMIp.sub.CGM|0.30 eV.
ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS
An electrophotographic photosensitive member includes a conductive substrate and a photosensitive layer of a single layer. The photosensitive layer contains a charge generating material, a binder resin, a hole transport material, and an electron transport material. The binder resin includes a polyester resin and a polycarbonate resin. The polyester resin includes a first repeating unit represented by general formula (1) shown below and a second repeating unit represented by general formula (2) shown below. The polycarbonate resin includes a third repeating unit represented by general formula (3) shown below and a fourth repeating unit represented by general formula (24) shown below.
##STR00001##
A content percentage of the polyester resin in the photosensitive layer is at least 0.3% by mass and no greater than 7.0% by mass.