There is provided herein a process of integrating electrically conductive material into a surface layer of an electrically conductive polymer, comprising the steps of including an electrically conductive material in a polymerisation mixture capable of forming an electrically conductive polymer, such that the material is provided across an uppermost and/or a lowermost region of the polymerisation mixture; and subsequently polymerising the polymerisation mixture. Also provided is an electrically conductive polymer and a supercapacitor formed using the process.

The present invention provides an on-chip all-solid-state supercapacitor, which includes a first electrode and a second electrode, and both the first electrode and the second electrode include a substrate, a laminated structure, a conductive thin film layer and a solid electrolyte. The laminated structure is disposed on a surface of the substrate and is provided with at least one deep trench structure; an inner surface of the deep trench structure is provided with a sacrificial layer trench, which increases the electrode area of the on-chip all-solid-state supercapacitor, and further increases the capacitance density and energy density; the conductive thin film layer covers the inner surface of the deep trench structure, an inner surface of the sacrificial layer trench, the surface of the substrate exposed in the deep trench structure and a surface of the laminated structure facing away from the substrate; the solid electrolyte is filled inside the sacrificial layer trench and the deep trench structure covered by the conductive thin film layer; the solid electrolyte also covers a surface of the conductive thin film layer facing away from the substrate, and the solid electrolyte of the first electrode and the solid electrolyte of the second electrode are bonded together. The present invention also provides a preparation method of an on-chip all-solid-state supercapacitor.

An outer packaging for electrical storage devices is composed of a laminate provided with at least a substrate layer, a barrier layer, an adhesive layer, and a thermally adhesive resin layer in this order, wherein the peak melting temperature for the thermally adhesive resin layer is observed at 130° C. or lower, the peak melting temperature for the adhesive layer is observed at 135° C. or higher, the resin constituting the thermally adhesive resin layer has a polyolefin skeleton, and the resin constituting the adhesive layer has a polyolefin skeleton

An object is to suppress electrochemical decomposition of an electrolyte solution and the like at a negative electrode in a lithium ion battery or a lithium ion capacitor; thus, irreversible capacity is reduced, cycle performance is improved, or operating temperature range is extended. A negative electrode for a power storage device including a negative electrode current collector, a negative electrode active material layer which is over the negative electrode current collector and includes a plurality of particles of a negative electrode active material, and a film covering part of the negative electrode active material. The film has an insulating property and lithium ion conductivity.

Representative embodiments provide a liquid or gel separator utilized to separate and space apart first and second conductors or electrodes of an energy storage device, such as a battery or a supercapacitor. A representative liquid or gel separator comprises a plurality of particles, typically having a size (in any dimension) between about 0.5 to about 50 microns; a first, ionic liquid electrolyte; and a polymer. In another representative embodiment, the plurality of particles comprise diatoms, diatomaceous frustules, and/or diatomaceous fragments or remains. Another representative embodiment further comprises a second electrolyte different from the first electrolyte; the plurality of particles are comprised of silicate glass; the first and second electrolytes comprise zinc tetrafluoroborate salt in 1-ethyl-3-methylimidalzolium tetrafluoroborate ionic liquid; and the polymer comprises polyvinyl alcohol (“PVA”) or polyvinylidene fluoride (“PVFD”). Additional components, such as additional electrolytes and solvents, may also be included.

Representative embodiments provide a liquid or gel separator utilized to separate and space apart first and second conductors or electrodes of an energy storage device, such as a battery or a supercapacitor. A representative liquid or gel separator comprises a plurality of particles, typically having a size (in any dimension) between about 0.5 to about 50 microns; a first, ionic liquid electrolyte; and a polymer. In another representative embodiment, the plurality of particles comprise diatoms, diatomaceous frustules, and/or diatomaceous fragments or remains. Another representative embodiment further comprises a second electrolyte different from the first electrolyte; the plurality of particles are comprised of silicate glass; the first and second electrolytes comprise zinc tetrafluoroborate salt in 1-ethyl-3-methylimidalzolium tetrafluoroborate ionic liquid; and the polymer comprises polyvinyl alcohol (“PVA”) or polyvinylidene fluoride (“PVFD”). Additional components, such as additional electrolytes and solvents, may also be included.

Disclosed is a functional layer for an electrochemical device that comprises inorganic particles and a particulate polymer, wherein the functional layer comprises a particle-detached portion, in a plan view of a surface of the functional layer, a ratio of an area of the particle-detached portion in a total area of the particulate polymer and the particle-detached portion is 0.1% or more and 40.0% or less, and a volume-average particle diameter of the particulate polymer is larger than a thickness of an inorganic particle layer comprising the inorganic particles.

A power storage device includes a positive electrode and a negative electrode facing each other, a separator disposed between the positive electrode and the negative electrode, the separator being porous, and a sealing member made of a resin and sealing a space between the positive electrode and the negative electrode. The separator includes a material having a melting temperature higher than a melting temperature of a resin material of the sealing member. The separator has an edge portion sandwiched and held in the sealing member in a state where the edge portion is joined to a melted-then-solidified portion of the resin material of the sealing member.

Ultra-thin lithium ion capacitors with ultra-high power performance are provided. Ultra-thin electrodes and ultra-thin lithium films can be used for the ultra-thin lithium ion capacitor. A lithium ion capacitor can include a first positive electrode and a second positive electrode, a negative electrode disposed between the first positive electrode and the second positive electrode, a first lithium film disposed between the first positive electrode and the negative electrode, and a second lithium film disposed between the second positive electrode and the negative electrode. Each of the first and second lithium films can include an electrolyte. In addition, at least one separator can be provided between the first positive electrode and the first lithium film, and at least one separator can be provided between the second positive electrode and the second lithium film.

Ultra-thin lithium ion capacitors with ultra-high power performance are provided. Ultra-thin electrodes and ultra-thin lithium films can be used for the ultra-thin lithium ion capacitor. A lithium ion capacitor can include a first positive electrode and a second positive electrode, a negative electrode disposed between the first positive electrode and the second positive electrode, a first lithium film disposed between the first positive electrode and the negative electrode, and a second lithium film disposed between the second positive electrode and the negative electrode. Each of the first and second lithium films can include an electrolyte. In addition, at least one separator can be provided between the first positive electrode and the first lithium film, and at least one separator can be provided between the second positive electrode and the second lithium film.