A method is provided for restoring an electrolyte of vanadium (V) redox flow battery (VRFB). Electrolyte data of an original system are analyzed in advance. A reusable positive electrode is further equipped with a V electrolyte. A reductant for a stack of VRFB is used in coordination as an electrolysis device. After a long-term reaction with a VRFB having a high valence (greater than 3.5), an electrolyte at the positive electrode is directed out to a negative electrode of the electrolysis device; and, then, electrolysis is processed after accurate calculation. In the end, the internal fluid balancing method of the original system is combined. Thus, a harmless and quick valence restoration is processed for the electrolyte of the original system, which is a final resort for the restoration of V electrolyte.

There is provided an energy management method, comprising steps of conducting (304) electric energy from an energy production plant (110, 112, 114, 140) to an energy storage facility (120, 220), applying, in the energy storage facility (120, 220), the received electric energy on a chemical compound (222) to separate the chemical compound to a first component (224) and a second component (226), and storing (306), in the energy storage facility (120, 220), the first component and the second component separately.

Embodiments of the present disclosure are directed to a diesel reforming system comprising: a diesel autothermal reformer; a liquid desulfurizer disposed upstream of the diesel autothermal reformer and configured to remove sulfur compounds from diesel fuel prior to feeding to the diesel autothermal reformer; a combustor in communication with the liquid desulfurizer and configured to provide heat for the liquid desulfurizer; a regulating valve in communication with the liquid desulfurizer and the combustor, the regulating valve being configured to control diesel fuel feeds to the liquid desulfurizer and the combustor; and a post-reformer disposed downstream of the diesel autothermal reformer.

Embodiments of the present disclosure are directed to a diesel reforming system comprising: a diesel autothermal reformer; a liquid desulfurizer disposed upstream of the diesel autothermal reformer and configured to remove sulfur compounds from diesel fuel prior to feeding to the diesel autothermal reformer; a combustor in communication with the liquid desulfurizer and configured to provide heat for the liquid desulfurizer; a regulating valve in communication with the liquid desulfurizer and the combustor, the regulating valve being configured to control diesel fuel feeds to the liquid desulfurizer and the combustor; and a post-reformer disposed downstream of the diesel autothermal reformer.

Methods and systems are provided for a rebalancing reactor of a flow battery system. In one example, a pH of a battery electrolyte may be maintained by the rebalancing reactor by applying a negative potential to a catalyst bed of the rebalancing reactor. A performance of the rebalancing reactor may further be maintained by treating the catalyst bed with deionized water.

A method of operating a flow cell. The method comprises providing a flow cell suitable for generating electrical power from hydrogen and a metal electrolyte. Said flow cell comprises a precipitate of metal oxi and said metal oxide comprises vanadium or manganese. The method further comprises electrochemically generating a redox active precipitate removal species from a precursor species, wherein said redox active precipitate removal species is capable of converting said metal oxide. The method further comprises exposing said metal oxide to said redox active precipitate removal species to effect conversion of the metal oxide.

A method of operating a flow cell. The method comprises providing a flow cell suitable for generating electrical power from hydrogen and a metal electrolyte. Said flow cell comprises a precipitate of metal oxi and said metal oxide comprises vanadium or manganese. The method further comprises electrochemically generating a redox active precipitate removal species from a precursor species, wherein said redox active precipitate removal species is capable of converting said metal oxide. The method further comprises exposing said metal oxide to said redox active precipitate removal species to effect conversion of the metal oxide.

Methods and systems for removing impurities from electrolyte solutions having three or more valence states. In some embodiments, a method includes electrochemically reducing an electrolyte solution to lower its valence state to a level that causes impurities to precipitate out of the electrolyte solution and then filtering the precipitate(s) out of the electrolyte solution. In embodiments in which the electrolyte solution is desired to be at a valence state higher than the precipitation valence state, a method of the disclosure includes oxidizing the purified electrolyte solution to the target valence.

An electrolyte manufacturing device includes an electrolytic cell including a diaphragm separating an anode chamber from a cathode chamber, a circulator circulating an anolyte to the anode chamber and circulating a catholyte to the cathode chamber, and a power source supplying current. A cathode in the electrolytic cell includes a carbon fiber layer on a plane facing the diaphragm. The electrolytic cell includes an anode net placed between the anode and the diaphragm, and a cathode net placed between the cathode and the diaphragm. The circulator circulates the anolyte at a flow rate that is greater than the flow rate of the catholyte and is equal to or greater than twice the volume of gaseous oxygen generated in the anode chamber per unit time at 0° C.

An electrolyte manufacturing device includes an electrolytic cell including a diaphragm separating an anode chamber from a cathode chamber, a circulator circulating an anolyte to the anode chamber and circulating a catholyte to the cathode chamber, and a power source supplying current. A cathode in the electrolytic cell includes a carbon fiber layer on a plane facing the diaphragm. The electrolytic cell includes an anode net placed between the anode and the diaphragm, and a cathode net placed between the cathode and the diaphragm. The circulator circulates the anolyte at a flow rate that is greater than the flow rate of the catholyte and is equal to or greater than twice the volume of gaseous oxygen generated in the anode chamber per unit time at 0° C.