Various designs and configurations of and methods of operating fuel cell units, fuel cell systems and combined heat and power systems are provided that permit efficient thermal management of such units and systems to improve their operation.

Methods and systems are provided for a rebalancing reactor of a flow battery system. In one example, a pH of a battery electrolyte may be maintained by the rebalancing reactor by applying a negative potential to a catalyst bed of the rebalancing reactor. A performance of the rebalancing reactor may further be maintained by treating the catalyst bed with deionized water.

A system is described that is capable of operating as an energy conversion system that functions as a fuel cell and generates electrical current from a fuel or fuels, or as a reactor for conversion of starter materials into more complex molecules through ion-ion and ion-molecules and which may preferably be adapted to operate as a gas to liquid (GTL) process. The system ionises at least one fuel or starter material and manipulates, selects and transports ions for reaction by means of suitable electrostatic or electrodynamic ion guides, filters or drift tubes. The system of the present application replaces the electrolyte, catalyst and/or membrane found in classic fuel cells or GTL processes with an electrostatic or electrodynamic ion manipulation region such as an ion guide, analyser, drift tube or filter.

A carbon dioxide recovery system for collecting carbon dioxide from an exhaust gas generated in a facility including a combustion device includes: a first exhaust gas passage through which the exhaust gas containing carbon dioxide flows; a fuel cell including an anode, a cathode disposed on the first exhaust gas passage so that the exhaust gas from the first exhaust gas passage is supplied to the cathode, and an electrolyte transferring, from the cathode to the anode, a carbonate ion derived from carbon dioxide contained in the exhaust gas from the first exhaust gas passage; and a second exhaust gas passage diverging from the first exhaust gas passage upstream of the cathode so as to bypass the cathode. A part of the exhaust gas is introduced to the second exhaust gas passage.

A carbon dioxide recovery system for collecting carbon dioxide from an exhaust gas generated in a facility including a combustion device includes: a first exhaust gas passage through which the exhaust gas containing carbon dioxide flows; a fuel cell including an anode, a cathode disposed on the first exhaust gas passage so that the exhaust gas from the first exhaust gas passage is supplied to the cathode, and an electrolyte transferring, from the cathode to the anode, a carbonate ion derived from carbon dioxide contained in the exhaust gas from the first exhaust gas passage; and a second exhaust gas passage diverging from the first exhaust gas passage upstream of the cathode so as to bypass the cathode. A part of the exhaust gas is introduced to the second exhaust gas passage.

A device includes a container having a top plate containing an array of oxygen limiting pinholes and a chamber to hold a chemical hydride fuel, a fuel cell proton exchange membrane electrode assembly supported within the container between the top plate and the chamber, a first gas diffusion layer supported between the fuel cell proton exchange membrane electrode assembly and the top plate, and a second gas diffusion layer supported between the fuel cell proton exchange membrane electrode assembly and the chamber.

A method of cleansing a redox flow battery system may include operating the redox flow battery system in a charge, discharge, or idle mode, and responsive to a redox flow battery capacity being less than a threshold battery capacity, mixing the positive electrolyte with the negative electrolyte. In this way, battery capacity degradation following cyclic charging and discharging of the redox flow battery system can be substantially reduced.

The present invention is directed to a redox flow battery comprising at least one electrochemical cell in fluid communication with a balancing cell, said balancing cell comprising: a first and second half-cell chamber, wherein the first half-cell chamber comprises a first electrode in contact with a first aqueous electrolyte of the redox flow battery; and wherein the second half-cell chamber comprises a second electrode comprising a catalyst for the generation of O.sub.2; and wherein the second half-cell chamber does not contain an aqueous electrolyte.

A hybrid fuel cell system includes a fuel supply system including a fuel tank, a start-up subsystem, a reforming subsystem and a depressurization system. The reforming subsystem is to receive fuel and to reform fuel to generate a hydrogen enriched gases and steam mixture. The hybrid fuel cell system includes a water supply system that provides water for the steam generator. The water supply system includes a water condenser directly downstream from the reforming subsystem that is in fluid communication with the hydrogen enriched gases and steam mixture to condense the hydrogen enriched gases and steam mixture into water and hydrogen enriched gases. The depressurization system is to reduce a pressure of the hydrogen enriched gases. The hybrid fuel cell system includes a fuel cell stack downstream from the depressurization system and having an anode inlet in fluid communication with the depressurization system to receive the hydrogen enriched gases.

A hybrid fuel cell system includes a fuel supply system including a fuel tank, a start-up subsystem, a reforming subsystem and a depressurization system. The reforming subsystem is to receive fuel and to reform fuel to generate a hydrogen enriched gases and steam mixture. The hybrid fuel cell system includes a water supply system that provides water for the steam generator. The water supply system includes a water condenser directly downstream from the reforming subsystem that is in fluid communication with the hydrogen enriched gases and steam mixture to condense the hydrogen enriched gases and steam mixture into water and hydrogen enriched gases. The depressurization system is to reduce a pressure of the hydrogen enriched gases. The hybrid fuel cell system includes a fuel cell stack downstream from the depressurization system and having an anode inlet in fluid communication with the depressurization system to receive the hydrogen enriched gases.