The disclosure relates to a molecular crowding type electrolyte that comprises at least one type of water-miscible/soluble polymer which acts as molecular crowding agent, a salt and a water. The disclosure also relates to a battery comprising the molecular crowding type electrolyte, and a method of using the molecular crowding electrolyte in electrochemical system such as battery that comprises an anode, a cathode and the molecular crowding type electrolyte.

Provided is encapsulated electroactive materials for use in rechargeable aqueous zinc cells, batteries, systems, and associated methods. A core-shell composite particle includes a core of electrochemically active material, and a shell of a polyelectrolyte matrix, substantially insoluble in water, yet allowing the transport of zinc cations to and from the electrochemically active core. A method for preparing the core-shell composite electrochemically active particle includes mechanically dispersing the electrochemically active material particles in association with the polyelectrolyte solution, insolubilizing the polyelectrolyte in the presence of the dispersed electrochemically active material particles, washing the encapsulated particles particle with water, and drying the washed encapsulated particles

The present disclosure relates to a single-ion solid electrolyte and its method of preparation. More particularly, the present disclosure relates to a single-ion conducting polymer solid electrolyte containing a network polymer, inorganic nanoparticles, and an electrolyte, wherein the network polymer contains a structural unit containing a cationic group, and its method of preparation.

The invention relates to the simultaneous use of a first salt comprising a nitrate anion (NO.sub.3.sup.−) and a second salt comprising an anion other than nitrate, at least one of the first and second salts being a lithium salt, as ionic conductivity promoters in a rechargeable lithium-metal-gel battery. The invention also relates to a lithium-gel battery comprising a mixture of said first salt and said second salt, to a non-aqueous gel electrolyte comprising such mixture and to a lithium battery positive electrode comprising said mixture.

Disclosed is a calcium salt, Ca(HMDS).sub.2, where HMDS is the hexamethyldisilazide anion (also known as bis(trimethylsilyl)amide), enables high current densities and high coulombic efficiency for calcium metal deposition and dissolution. These properties facilitate the use of this salt in batteries based on calcium metal. In addition, the salt is significant for batteries based on metal anodes, which have higher specific energies than batteries based on intercalation anodes, such as LiC.sub.6. In particular, a calcium based rechargeable battery includes Ca(HMDS).sub.2 salt and at least one solvent, the solvent suitable for calcium battery cycling. The at least one solvent can be diethyl ether, diisopropylether, methyl t-butyl ether (MTBE), 1,3-dioxane, 1,4-dioxane, tetrahydrofuran (THF), tetrahydropyran, glyme, diglyme, triglyme or tetraglyme, or any mixture thereof.

An electrode assembly includes an electrode subassembly forming by winding a first electrode plate and a second electrode plate. The first electrode plate includes a first electrode plate unit. The first electrode plate unit includes a bipolar current collector, a first active layer, and a second active layer. The bipolar current collector is disposed between the first active layer and the second active layer. The first active layer is electrically connected to the second active layer. The second electrode plate includes a composite current collector, a third active layer, and a fourth active layer. The composite current collector is disposed between the third active layer and the fourth active layer. The third active layer is electrically insulated from the fourth active layer. The disclosure further provides a battery including the electrode assembly.

Use of a copolyester film in the manufacture of a lithium-ion wet cell battery comprising an anode, a cathode and an electrolyte, wherein the copolyester film comprises a copolyester which comprises repeating units derived from a diol, a dicarboxylic acid and a poly(alkylene oxide)glycol.

A printed energy storage device includes a first electrode including zinc, a second electrode including manganese dioxide, and a separator between the first electrode and the second electrode, the first electrode, second, electrode, and separator printed onto a substrate. The device may include a first current collector and/or a second current collector printed onto the substrate. The energy storage device may include a printed intermediate layer between the separator and the first electrode. The first electrode, and the second electrode may include 1-ethyl-3-methylimidazolium tetrafluoroborate (C.sub.2mimBF.sub.4). The first electrode and the second electrode may include an electrolyte having zinc tetrafluoroborate (ZnBF.sub.4) and 1-ethyl-3-methylimidazolium tetrafluoroborate (C.sub.2mimBF.sub.4). The first electrode, the second electrode, the first current collector, and/or the second current collector can include carbon nanotubes. The separator may include solid microspheres.

A method of fabricating a flexible battery comprises forming a first substrate on a first release liner, forming at least one current collector layer on each of the first and second substrate, forming an anode side of the battery by forming an anode on the current collector of the first substrate, forming a cathode side of the battery by forming a cathode on the current collector of the second substrate, depositing electrolyte on one or both of the anode and cathode, adhering and sealing the anode side and cathode side together such that the anode and cathode face one another with the electrolyte In between, and removing the flexible battery from the release liners. The battery may be a primary battery or a secondary battery. The method may be implemented using a roll-to-roll process.

An electrically conductive hybrid membrane, including a solid membrane substrate including a curable material; and electrically conductive particle disposed on the solid membrane substrate, wherein the solid membrane substrate has an elastic modulus of about 10 MPa to about 1000 MPa, and the electrically conductive particle is exposed on both sides of the solid membrane substrate.