A separator for an electrochemical cell, in particular a lithium cell, and a corresponding manufacturing method. In order to provide a separator having an elevated dendrite resistance, in particular ion-conducting, particles are introduced into pores of a polymer layer and frictionally retained between polymer walls delimiting pores. An electrochemical cell equipped therewith is also described.

A process can be used to produce a charge storage unit, especially a secondary battery, the electrodes of which contain an organic redox-active polymer, and which includes a polymeric solid electrolyte. The solid electrolyte is obtained by polymerizing from mixtures of acrylates with methacrylates in the presence of at least one ionic liquid, which imparts advantageous properties to the charge storage unit.

A method of controlling the ionic conductivity of a polymer member, including providing a plurality of particles of bi-doped garnet, dispersing the plurality of particles of bi-doped garnet in a PEO matrix to yield a polymer member, nucleating spherulites at bi-doped garnet particle sites, and growing spherulites to a critical density to provide ionic conductivity pathways throughout the polymer member.

The invention discloses a high voltage rechargeable Zn—MnO.sub.2 battery. The structure of the Zn—MnO.sub.2 battery includes zinc electrode/alkaline electrolyte/ion exchange membrane/acid electrolyte/MnO.sub.2 electrode. The ion exchange membrane comprises a cation exchange membrane, an anion exchange membrane or a proton exchange membrane. According to the invention, by using a composite electrolyte system (alkaline electrolyte/ion exchange membrane/acid electrolyte), a high voltage rechargeable Zn—MnO.sub.2 battery is obtained. According to the invention, an open circuit voltage of up to 2.7V is obtained, greatly improving the discharge voltage, and at the same time increasing the discharge capacity and enabling cyclic charge and discharge. The invention is of great importance in science research, beneficial to society and economics.

This invention discloses high-modulus, ion-conductive gel electrolytes and methods of making the gel electrolytes and electrochemical devices. The gel electrolytes include an ionic liquid and nanosheets mixed in the ionic liquid. The nanosheets in one example include exfoliated hexagonal boron nitride (hBN) nanosheets. Compared to conventional bulk hBN microparticles, exfoliated hBN nanosheets improve the mechanical properties of the gel electrolytes by about 2 orders of magnitude, while retaining high ionic conductivity at room temperature. Moreover, exfoliated hBN nanosheets are compatible with high-voltage cathodes, and impart exceptional thermal stability that allows high-rate operation of solid-state rechargeable lithium-ion batteries at high temperatures.

The present invention is provided to reduce the influence of expansion and contraction of an active material, form a favorable interface between the solid electrolyte and the active material, and increase ion conductivity in the electrolyte, thereby obtaining a wide operation temperature range. A secondary battery composite electrolyte includes an inorganic compound having an Li ion conductivity at room temperature that is 1×10.sup.−10 S/cm or more and having particle diameter of 0.05 μm or more and less than 8 μm, and an organic electrolyte. The weight ratio between the organic electrolyte and the inorganic compound is 0.1% or more and 20% or less.

A method of manufacturing an all-solid-state battery and an apparatus for manufacturing the same are provided. The method of manufacturing the all-solid-state battery includes: (a) a step of forming a non-woven fabric having a fiber made of a resin; (b) a step of applying a slurry containing solid electrolyte particles onto the non-woven fabric; (c) a step of drying the slurry on the non-woven fabric by a heater; (d) a step of pressurizing the slurry on the non-woven fabric by a roller; (e) a step of forming a positive electrode member on one surface of the solid electrolyte membrane; and (f) a step of forming a negative electrode member on the other surface of the solid electrolyte membrane. The step (a) is a step of forming the non-woven fabric by making a resin containing a polar filler fibrous by a laser electrospinning method. By such a method, the all-solid-state battery (a laminated body of a positive electrode member, a solid electrolyte membrane, and a negative electrode member) can be efficiently manufactured.

The present disclosure relates to a composite material of formula (I): (LPS).sub.a(OIPC).sub.b wherein each of a and b is a mass % value from 1% to 99% such that a+b is 100%; (LPS) is a material selected from the group consisting of Li.sub.3PS.sub.4, Li.sub.7P.sub.3S.sub.11, Li.sub.10GeP.sub.2S.sub.11, and a material of formula (II): xLi.sub.2S.yP.sub.2S.sub.5.(100−x−y)LiX; wherein X is I, Cl or Br, each of x and y is a mass % value of from 33.3% to 50% such that x+y is from 75% to 100% and the total mass % of Li.sub.2S, P.sub.2S.sub.5 and LiX is 100%; and (OIPC) is a salt of a cation and a closo-borane cluster anion.

To provide an anode material that can improve the efficiency of the initial charging and discharging, the anode material includes an amorphous glassy carbon material that is an anode active material, and a NaMH compound that is a solid electrolyte.

The present invention is provided to reduce the influence of expansion and contraction of an active material, form a favorable interface between a solid electrolyte and an active material, and improve the high temperature durability and cycle lifespan of a battery. A secondary battery composite electrolyte includes an inorganic compound having an Li ion conductivity at 25° C. that is less than 1×10.sup.−10 S/cm and an organic electrolyte. The weight ratio between the organic electrolyte and the inorganic compound is 0.1% or more and 20% or less.