Patent classifications
H01B1/08
GALLIUM-SUBSTITUTED SOLID ELECTROLYTE MATERIAL, AND ALL-SOLID-STATE LITHIUM ION SECONDARY BATTERY
Provided is a novel solid electrolyte material of high density and high ionic conductivity, and an all-solid-state lithium ion secondary battery that utilizes the solid electrolyte material. The solid electrolyte material has a chemical composition represented by Li.sub.7-3xGa.sub.xLa.sub.3Zr.sub.2O.sub.12 (0.08≤x<0.5), has a relative density of 99% or higher, belongs to space group I-43d, in the cubic system, and has a garnet-type structure. The lithium ion conductivity of the solid electrolyte material is 2.0×10.sup.−3 S/cm or higher. The solid electrolyte material has a lattice constant a such that 1.29 nm≤a≤1.30 nm, and lithium ions occupy the 12a site, the 12b site and two types of 48e site, and gallium occupies the 12a site and the 12b site, in the crystal structure. The all-solid-state lithium ion secondary battery has a positive electrode, a negative electrode, and a solid electrolyte. The solid electrolyte is made up of the solid electrolyte material of the present invention.
Oxide superconducting wire
An oxide superconducting wire includes a superconducting laminate including an oxide superconducting layer disposed, either directly or indirectly, on a substrate, and a stabilization layer which is a Cu plating layer covering an outer periphery of the superconducting laminate. An average crystal grain size of the Cu plating layer is 3.30 μm or more and equal to or less than a thickness of the Cu plating layer.
Oxide superconducting wire
An oxide superconducting wire includes a superconducting laminate including an oxide superconducting layer disposed, either directly or indirectly, on a substrate, and a stabilization layer which is a Cu plating layer covering an outer periphery of the superconducting laminate. An average crystal grain size of the Cu plating layer is 3.30 μm or more and equal to or less than a thickness of the Cu plating layer.
CONDUCTIVE PASTE FOR SOLAR CELL ELECTRODE AND SOLAR CELL MANUFACTURED BY USING SAME
The present disclosure provides a conductive paste for a solar cell electrode, comprising a metal powder, a glass frit, a metal oxide, an organic binder and a solvent, wherein the metal oxide comprises at least one metal oxide selected from the group consisting of tungsten (W), antimony (Sb), nickel (Ni), copper (Cu), magnesium (Mg), calcium (Ca), ruthenium (Ru), molybdenum (Mo), and bismuth (Bi).
Precursor materials for Li-ion battery cathode synthesis
Provided are processes for the production of particles for use as a precursor material for synthesis of Li-ion cathode active material of a lithium-ion cell comprising: a non-lithiated nickel oxide particle of the formula MO.sub.x wherein M comprises 80 at % Ni or greater and wherein x is 0.7 to 1.2, M optionally excluding boron in the MO.sub.x crystal structure; and a modifier oxide intermixed with, coated on, present within, or combinations thereof the non-lithiated nickel oxide particle, wherein the modifier oxide is associated with the non-lithiated nickel oxide such that a calcination at 500 degrees Celsius for 2 hours results in crystallite growth measured by XRD of 2 nanometers or less.
Precursor materials for Li-ion battery cathode synthesis
Provided are processes for the production of particles for use as a precursor material for synthesis of Li-ion cathode active material of a lithium-ion cell comprising: a non-lithiated nickel oxide particle of the formula MO.sub.x wherein M comprises 80 at % Ni or greater and wherein x is 0.7 to 1.2, M optionally excluding boron in the MO.sub.x crystal structure; and a modifier oxide intermixed with, coated on, present within, or combinations thereof the non-lithiated nickel oxide particle, wherein the modifier oxide is associated with the non-lithiated nickel oxide such that a calcination at 500 degrees Celsius for 2 hours results in crystallite growth measured by XRD of 2 nanometers or less.
Li ion conductor and process for producing same
A Li ion conductor having a composition different from a conventional composition is provided. The Li ion conductor contains at least one selected from a group Q consisting of Ga, V, and Al, Li, La and O. A part of an Li site is optionally substituted with a metal element D, a part of an La site is optionally substituted with a metal element E, and parts of Ga, V and Al sites are optionally substituted with a metal element J. A mole ratio of an amount of Li to a total amount of La, the element E, Ga, V, Al, and the element J is not lower than 8.1/5 and not higher than 9.5/5. A mole ratio of a total amount of Ga, V, and Al to a total amount of La and the element E is not lower than 1.1/3 and not higher than 2/3.
Li ion conductor and process for producing same
A Li ion conductor having a composition different from a conventional composition is provided. The Li ion conductor contains at least one selected from a group Q consisting of Ga, V, and Al, Li, La and O. A part of an Li site is optionally substituted with a metal element D, a part of an La site is optionally substituted with a metal element E, and parts of Ga, V and Al sites are optionally substituted with a metal element J. A mole ratio of an amount of Li to a total amount of La, the element E, Ga, V, Al, and the element J is not lower than 8.1/5 and not higher than 9.5/5. A mole ratio of a total amount of Ga, V, and Al to a total amount of La and the element E is not lower than 1.1/3 and not higher than 2/3.
Contact structure and electronic device having the same
The present disclosure provides a contact structure and an electronic device having the same. The contact structure includes: a substrate; a copper layer disposed on the substrate; an adhesion promotion layer disposed on the copper layer, wherein the adhesion promotion layer forms a monomolecular adsorption layer on the surface of the copper layer; and a silver nanowire layer disposed on the adhesion promotion layer, and the adhesive force between the copper layer and the silver nanowire layer is 3B or more. In the present disclosure, by disposing the adhesion promotion layer on the copper layer, in the stacked structure of the copper layer and the silver nanowire layer, the adhesive force between the copper layer and the silver nanowire layer is increased, so as to prevent a peeling phenomenon of the copper layer occurring in the subsequent yellow-light process.
ELECTRON-EMITTING CERAMIC
Embodiments are directed to the field of ceramics and relate to electron-emitting ceramics such as those which can be used as cathode material for electron emissions in space flight systems, for example. Embodiments specify an electron-emitting ceramic which has an improved temperature conductivity with a simultaneously continuous electron emission. The electron-emitting ceramic contains at least>70 vol. % C12A7 electride and a proportion of Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Re, Fe, Ru, Os, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, In, Sn, Sb, Te, Tl, Pb, or Bi as metal and/or with Ti, wherein the proportion of the metals lies between>0 and<30 vol. %, and the ceramic has a density of at least 85% of the theoretical density of the ceramic and the ceramic contains 0 to maximally 10 vol. % production-specific impurities.