A lithium battery as a secondary battery includes a positive electrode composite material containing a solid electrolyte and a positive electrode active material containing lithium, a negative electrode as an electrode provided at one face of the positive electrode composite material, and a current collector provided at another face of the positive electrode composite material, wherein the solid electrolyte is a garnet-type fluorine-containing lithium composite metal oxide that is represented by the following compositional formula (1) or (2) and that conducts lithium.
(Li.sub.7−3xGa.sub.x)(La.sub.3−yNd.sub.y)Zr.sub.2O.sub.12−zF.sub.z   (1)
(Li.sub.7−3x+yGa.sub.x)(La.sub.3−yCa.sub.y)Zr.sub.2O.sub.12−zF.sub.z   (2) Provided that 0.1≤x≤1.0, 0<y≤0.2, and 0<z≤1.0.

The present invention provides a conductive material including: (A) a π-conjugated polymer, (B) a dopant polymer which contains one or more repeating units selected from “a1” to “a4” respectively represented by the following general formula (1) and has a weight-average molecular weight in the range of 1,000 to 500,000, and (C) one or more metal oxide nanoparticles whose metal oxide is selected from indium-tin oxides, tin oxides, antimony-tin oxides, antimony-zinc oxides, antimony oxides, and molybdenum oxides having a particle diameter of 1 to 200 nm. There can be provided a conductive material that has excellent film-formability and also can form a conductive film having high transparency and conductivity, superior flexibility and flatness when the film is formed from the material. ##STR00001##

The present invention provides a conductive material including: (A) a π-conjugated polymer, (B) a dopant polymer which contains one or more repeating units selected from “a1” to “a4” respectively represented by the following general formula (1) and has a weight-average molecular weight in the range of 1,000 to 500,000, and (C) one or more metal oxide nanoparticles whose metal oxide is selected from indium-tin oxides, tin oxides, antimony-tin oxides, antimony-zinc oxides, antimony oxides, and molybdenum oxides having a particle diameter of 1 to 200 nm. There can be provided a conductive material that has excellent film-formability and also can form a conductive film having high transparency and conductivity, superior flexibility and flatness when the film is formed from the material. ##STR00001##

The present inventions concerns compositions for producing thermoset polyurethanes, comprising polyisocyanates and polyols selected from a list consisting of allieyclic, aromatic compounds and branched polyesters. The films obtained from these compositions exhibit a high transparency, high thermal stability and good chemical resistance, and a method to produce the same. The said polyurethane films can be widely used in electronics industry where high transparency, high thermal resistance and good chemical resistance are the main requirements. Particularly, these films can be used as the substrates for conductive coatings and barrier coatings. These functionally coated films are particularly useful in applications such as touch panels or photo-voltaic cells.

A membrane electrode assembly includes an electrode consisting of at least one compound selected from the group consisting of lanthanum strontium cobalt complex oxide, lanthanum strontium cobalt ferrite complex oxide, lanthanum strontium ferrite complex oxide, and lanthanum nickel ferrite complex oxide or consisting of a composite of the compound and an electrolyte material, and a first solid electrolyte membrane represented by a composition formula of BaZr.sub.1-xln.sub.xO.sub.3−δ (0<x<1). The electrode is in contact with the first solid electrolyte membrane.

Provided is a ceramic member in which the difference in thermal expansion coefficient between an insulating ceramic material and an electrically conductive ceramic material is extremely small and therefore any mismatch caused in association with this difference in thermal expansion coefficient does not occur, and which does not undergo any failure such as breakage, cracking, detachment or destruction. The ceramic member (1) includes an electrically conductive ceramic material (2) which contains yttrium oxide as the main component and additionally contains a fibrous electrically conductive substance such as carbon nanotubes in an amount of 0.1 to 3 vol % inclusive and an insulation ceramic material (3) which contains yttrium oxide as the main component, wherein the electrically conductive ceramic material (2) and the insulation ceramic material (3) are adhered to each other in an integrated manner through an adhesive layer (4) which includes an inorganic adhesive material.

Provided is a ceramic member in which the difference in thermal expansion coefficient between an insulating ceramic material and an electrically conductive ceramic material is extremely small and therefore any mismatch caused in association with this difference in thermal expansion coefficient does not occur, and which does not undergo any failure such as breakage, cracking, detachment or destruction. The ceramic member (1) includes an electrically conductive ceramic material (2) which contains yttrium oxide as the main component and additionally contains a fibrous electrically conductive substance such as carbon nanotubes in an amount of 0.1 to 3 vol % inclusive and an insulation ceramic material (3) which contains yttrium oxide as the main component, wherein the electrically conductive ceramic material (2) and the insulation ceramic material (3) are adhered to each other in an integrated manner through an adhesive layer (4) which includes an inorganic adhesive material.

Provided are an apparatus for preparing a cathode active material precursor for lithium secondary batteries including a cylindrical outer chamber, an inner cylinder that has the same central axis as the outer chamber and is mounted to rotatably move along the central axis, an electric motor to transfer power to rotate the inner cylinder, a reactant inlet disposed on the outer chamber, to add reactants to a space between the outer chamber and the inner cylinder, and an outlet disposed in the outer chamber, to obtain reaction products after reaction in the space between the outer chamber and the inner cylinder, and a method for preparing a cathode active material precursor for lithium secondary batteries using the apparatus.

Provided are an apparatus for preparing a cathode active material precursor for lithium secondary batteries including a cylindrical outer chamber, an inner cylinder that has the same central axis as the outer chamber and is mounted to rotatably move along the central axis, an electric motor to transfer power to rotate the inner cylinder, a reactant inlet disposed on the outer chamber, to add reactants to a space between the outer chamber and the inner cylinder, and an outlet disposed in the outer chamber, to obtain reaction products after reaction in the space between the outer chamber and the inner cylinder, and a method for preparing a cathode active material precursor for lithium secondary batteries using the apparatus.

Single crystals of the new semiconducting oxychalcogenide phase were synthesized using a novel crystal growth method. The crystals had low defects and homogeneous composition as characterized by single crystal X-ray diffraction and scanning electron microscopy, respectively. Heat capacity and resistivity measurements were in agreement with the calculated band structure calculations indicating semiconductivity, with a band gap of about 3 eV.