A transparent conductive film includes a metal chalcogenide compound doped with a halogen and having a sheet resistance at room temperature of less than or equal to about 60 ohm/sq.

A transparent conductive film includes a metal chalcogenide compound doped with a halogen and having a sheet resistance at room temperature of less than or equal to about 60 ohm/sq.

A method of producing an inorganic material (S10) according to the present invention includes a vitrification step (S12) of applying shearing stress and compressive stress to a mixed powder (MP) of a plurality of kinds of inorganic compound powders by using a ring ball mill mechanism (70) to vitrify at least a part of the mixed powder (MP); and a dispersion step (S13) of dispersing the vitrified mixed powder (MP) after the vitrification step (S12), where a combined step of the vitrification step (S12) and the dispersion step (S13) is performed a plurality of times to obtain a vitrified inorganic material powder from the mixed powder.

A sulfide solid electrolyte containing the following (A) and (B): (A) a sulfide solid electrolyte having an argyrodite-type crystal structure; and (B) a sulfide solid electrolyte having a crystal structure different from the argyrodite-type crystal structure of the above-mentioned (A).

There is provided an inorganic solid electrolyte-containing composition containing an inorganic solid electrolyte and a polymer binder, in which the polymer binder contains a specific polymer, and the weight-average molecular weight and content of the polymer binder satisfy relationships represented by specific expressions. There are also provided a sheet for an all-solid state secondary battery and an all-solid state secondary battery, in which this inorganic solid electrolyte-containing composition is used, and manufacturing methods for a sheet for an all-solid state secondary battery, and an all-solid state secondary battery.

The positive electrode material according to an aspect of the present disclosure includes a first solid electrolyte, a positive electrode active material, and a coating material coating the surface of the positive electrode active material. The first solid electrolyte is represented by the following compositional formula: Li.sub.aM.sub.bO.sub.cX.sub.d. In the compositional formula, a, b, c, and d are positive real numbers; M is at least one selected from the group consisting of Ta and Nb; and X is at least one selected from the group consisting of Cl, Br, and I.

Provided is a sulfide-based solid electrolyte comprising lithium, phosphorus, sulfur, and a halogen, as a novel solid electrolyte capable of suppressing generation of hydrogen sulfide and securing ionic conductivity. The solid electrolyte is characterized by comprising Li.sub.7−aPS.sub.6−aHa.sub.a (wherein Ha represents a halogen, and “a” satisfies 0.2<a≤1.8) having an argyrodite-type crystal structure, and Li.sub.3PS.sub.4, wherein, in an X-ray diffraction (XRD) pattern obtained through measurement by an X-ray diffraction method, the ratio of the peak intensity of a peak appearing at a position in a range of diffraction angle 2θ=26.0° to 28.8° derived from Li.sub.3PS.sub.4, relative to the peak intensity of a peak appearing at a position in a range of diffraction angle 2θ=24.9° to 26.3° derived from the argyrodite-type crystal structure, is 0.04 to 0.3.

A sulfide glass solid electrolyte sheet can be protected from reaction with moisture by a thin metal layer coating converted to a thin electrochemically functional and protective compound layer. The converted protective compound layer is electrochemically functional in that it allows for through transport of lithium ions.

Provided is a method for producing a solid electrolyte having peaks at 2θ=20.2°±0.5° and 23.6°±0.5° in X-ray diffractometry using a CuKα ray and containing a lithium element, a phosphorus element, a sulfur element, and a halogen element, the method including using raw materials containing yellow phosphorus and a compound containing a lithium element, a sulfur element, and a halogen element.

A sulfide solid electrolyte to be used in a lithium-ion secondary battery, including: a crystal phase; and an anion existing in a crystal structure of the crystal phase, in which the crystal phase includes an argyrodite crystal containing Li, P, S, and Ha; Ha is at least one element selected from the group consisting of F, Cl, Br, and I; the anion includes an oxide anion having a Q0 structure having an M-O bond that is a bond of M and O; and M is at least one element selected from the group consisting of metal elements and semimetal elements belonging to Groups 2 to 14 of a periodic table.