A sulfide solid electrolyte material with favorable ion conductivity and high reduction resistance. The object is attained by providing sulfide solid electrolyte material comprising: Li element; Ge element; P element; and S element, wherein the sulfide solid electrolyte material peaks at a position of 2θ=29.58°±0.50° in X-ray diffraction measurement using CuKα ray, the sulfide solid electrolyte material does not peak at a position of 2θ=27.33°±0.50° in X-ray diffraction measurement using CuKα ray or when diffraction intensity at the peak of 2θ=29.58°±0.50° is regarded as I.sub.A and diffraction intensity at the peak of 2θ=27.33°±0.50° is regarded as I.sub.B, a value of I.sub.B/I.sub.A is less than 1.0, and part of the P element in a crystal phase peaking at the position of 2θ=29.58°±0.50° is substituted with a B element.

A sulfide solid electrolyte material with favorable ion conductivity and high reduction resistance. The object is attained by providing sulfide solid electrolyte material comprising: Li element; Ge element; P element; and S element, wherein the sulfide solid electrolyte material peaks at a position of 2θ=29.58°±0.50° in X-ray diffraction measurement using CuKα ray, the sulfide solid electrolyte material does not peak at a position of 2θ=27.33°±0.50° in X-ray diffraction measurement using CuKα ray or when diffraction intensity at the peak of 2θ=29.58°±0.50° is regarded as I.sub.A and diffraction intensity at the peak of 2θ=27.33°±0.50° is regarded as I.sub.B, a value of I.sub.B/I.sub.A is less than 1.0, and part of the P element in a crystal phase peaking at the position of 2θ=29.58°±0.50° is substituted with a B element.

A sulfide solid electrolyte material includes Li, K, Si, P and S elements; a peak at 2θ=29.58°±0.50° and not having a peak at a position of 2θ=27.33°±0.50° in X-ray diffraction measurement using a CuKα ray, or when a diffraction intensity at the peak of 2θ=29.58°±0.50° is regarded as I.sub.A and a diffraction intensity at the peak of 2θ=27.33°±0.50° is regarded as I.sub.B having a peak at the position of 2θ=27.33°±0.50°, a value of I.sub.B/I.sub.A is less than 1; a P element molar fraction (P/(Si+P)) to a Si element total and the P element satisfies 0.5≦P/(Si+P)≦0.7, and a K element molar fraction (K/(Li+K)) to a Li element total and the K element satisfies 0<K/(Li+K)≦0.1.

Proposed is a new sulfide-based solid electrolyte for lithium ion batteries, the sulfide-based solid electrolyte relating to a compound that has a cubic argyrodite type crystal structure and is represented by Li.sub.7-x-2yPS.sub.6-x-yCl.sub.x, and having excellent water resistance and oxidation resistance. Proposed is a sulfide-based solid electrolyte for lithium ion batteries, the sulfide-based solid electrolyte containing a compound that has a cubic argyrodite type crystal structure and is represented by compositional formula (1) : Li.sub.7-x-2yPS.sub.6-x-yCl.sub.x, in which compositional formula, conditions: 0.8 ≦x≦1.7 and 0<y≦−0.25x+0.5 are satisfied.

Proposed is a new sulfide-based solid electrolyte for lithium ion batteries, the sulfide-based solid electrolyte relating to a compound that has a cubic argyrodite type crystal structure and is represented by Li.sub.7-x-2yPS.sub.6-x-yCl.sub.x, and having excellent water resistance and oxidation resistance. Proposed is a sulfide-based solid electrolyte for lithium ion batteries, the sulfide-based solid electrolyte containing a compound that has a cubic argyrodite type crystal structure and is represented by compositional formula (1) : Li.sub.7-x-2yPS.sub.6-x-yCl.sub.x, in which compositional formula, conditions: 0.8 ≦x≦1.7 and 0<y≦−0.25x+0.5 are satisfied.

In one aspect, an apparatus includes: a mixer to receive a radio frequency (RF) signal and downconvert the RF signal into a second frequency signal; an amplifier coupled to the mixer to amplify the second frequency signal; an image rejection (IR) circuit coupled to the programmable gain amplifier (PGA) to orthogonally correct a gain and a phase of the amplified second frequency signal to output a corrected amplified second frequency signal; and a complex filter to filter the corrected amplified second frequency signal.

Provided is a sulfide-based solid electrolyte, including: a Na element; a Ge element; a P element; and a S element, wherein an atomic percentage (at. %) of each of the Na element, the Ge element, the P element, and the S element is as follows when a total of the respective elements is 100 at. %, Na: from 38.8 at. % to 48.4 at. % Ge: from 0.5 at. % to 8.9 at. % P: from 3.9 at. % to 7.9 at. % S: from 43.6 at. % to 48.6 at. %.

Provided is a sulfide-based solid electrolyte, including: a Na element; a Ge element; a P element; and a S element, wherein an atomic percentage (at. %) of each of the Na element, the Ge element, the P element, and the S element is as follows when a total of the respective elements is 100 at. %, Na: from 38.8 at. % to 48.4 at. % Ge: from 0.5 at. % to 8.9 at. % P: from 3.9 at. % to 7.9 at. % S: from 43.6 at. % to 48.6 at. %.

A main object of the present invention is to provide a method for manufacturing a sulfide solid electrolyte that enables a sulfide solid electrolyte whose ion-conducting characteristic is easy to be improved, to be manufactured. The present invention is a method for manufacturing a sulfide solid electrolyte including loading a raw material for manufacturing a sulfide solid electrolyte which is mainly composed of a substance represented by the general formula of (100−x)(0.75Li.sub.2S.0.25P.sub.2S.sub.5).xLiI (here, 0<x<100), into a vessel; and amorphizing the raw material after said loading, wherein a reaction site temperature in the vessel is controlled so that x included in the general formula and the reaction site temperature y [° C.] in the vessel in said amorphizing satisfy y<−2.00x+1.79×10.sup.2.

A main object of the present invention is to provide a method for manufacturing a sulfide solid electrolyte that enables a sulfide solid electrolyte whose ion-conducting characteristic is easy to be improved, to be manufactured. The present invention is a method for manufacturing a sulfide solid electrolyte including loading a raw material for manufacturing a sulfide solid electrolyte which is mainly composed of a substance represented by the general formula of (100−x)(0.75Li.sub.2S.0.25P.sub.2S.sub.5).xLiI (here, 0<x<100), into a vessel; and amorphizing the raw material after said loading, wherein a reaction site temperature in the vessel is controlled so that x included in the general formula and the reaction site temperature y [° C.] in the vessel in said amorphizing satisfy y<−2.00x+1.79×10.sup.2.