Disclosed are azeotropic or azeotrope-like compositions containing Z-1,1,1,4,4,4-hexafluoro-2-butene and methyl perfluoropropyl ether. Also disclosed is process of using the azeotropic or azeotrope-like composition as blowing agents for preparing a thermoplastic or thermoset foam. Also disclosed is a process of using the azeotropic or azeotrope-like composition as a refrigerant for producing cooling or heating. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as solvents. Also disclosed is a process of using the azeotropic or azeotrope-like composition as propellants for producing an aerosol. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as heat transfer media. Also disclosed is a process of extinguishing or suppressing a fire by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as dielectrics.

Disclosed are azeotropic or azeotrope-like compositions containing Z-1,1,1,4,4,4-hexafluoro-2-butene and methyl perfluoropropyl ether. Also disclosed is process of using the azeotropic or azeotrope-like composition as blowing agents for preparing a thermoplastic or thermoset foam. Also disclosed is a process of using the azeotropic or azeotrope-like composition as a refrigerant for producing cooling or heating. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as solvents. Also disclosed is a process of using the azeotropic or azeotrope-like composition as propellants for producing an aerosol. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as heat transfer media. Also disclosed is a process of extinguishing or suppressing a fire by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as dielectrics.

An electrical apparatus for electrical energy handling includes a housing with at least one insulation space, in which an electrical component is arranged and which contains an insulation medium surrounding the electrical component. The insulation medium includes an organofluorine compound and at least one further gaseous component. The apparatus further includes a gas flow generating device for flowing an initial gas mixture, containing the organofluorine compound and at least one further component of the insulation medium, out of the insulation space through an outlet opening arranged in the housing. A substance recovery device downstream of outlet opening includes a separator for separating the organofluorine compound from the at least one further component of the initial gas mixture, the separator being a liquefaction device for liquefying and/or solidification device for solidifying the organofluorine compound.

An electrical apparatus for electrical energy handling includes a housing with at least one insulation space, in which an electrical component is arranged and which contains an insulation medium surrounding the electrical component. The insulation medium includes an organofluorine compound and at least one further gaseous component. The apparatus further includes a gas flow generating device for flowing an initial gas mixture, containing the organofluorine compound and at least one further component of the insulation medium, out of the insulation space through an outlet opening arranged in the housing. A substance recovery device downstream of outlet opening includes a separator for separating the organofluorine compound from the at least one further component of the initial gas mixture, the separator being a liquefaction device for liquefying and/or solidification device for solidifying the organofluorine compound.

The present application discloses compositions comprising hydrogen fluoride and fluorinated compounds (e.g., hydrofluorocarbons), wherein the fluorinated compound is present in the composition in an amount effective to form an azeotrope composition or azeotrope-like composition with the hydrogen fluoride.

This application provides azeotropic and near-azeotropic compositions of Z-1233zd and a second component selected from the group consisting of methyl formate, dimethoxymethane, HFC-43-10-mee and HFC-245fa. The inventive compositions are useful as aerosol propellants, refrigerants, cleaning agents, expansion agents for thermoplastic and thermoset foams, solvents, heat transfer media, gaseous dielectrics, fire extinguishing and suppression agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, and displacement drying agents. The compositions were modeled based on Vapor-Liquid Equilibria data such as those illustrated in the figures.

This application provides azeotropic and near-azeotropic compositions of Z-1233zd and a second component selected from the group consisting of methyl formate, dimethoxymethane, HFC-43-10-mee and HFC-245fa. The inventive compositions are useful as aerosol propellants, refrigerants, cleaning agents, expansion agents for thermoplastic and thermoset foams, solvents, heat transfer media, gaseous dielectrics, fire extinguishing and suppression agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, and displacement drying agents. The compositions were modeled based on Vapor-Liquid Equilibria data such as those illustrated in the figures.

A device or component thereof is provided for generation, transmission, distribution and/or use of electrical energy. In at least one insulation space formed within the device, there is a current-conducting component. The insulation space includes a dielectric insulation medium that surrounds the current-conducting component. This insulation medium includes a) at least one organofluorine compound selected from the group consisting of fluoroketones, fluoronitriles, and mixtures thereof and b) a carrier gas comprising at least one component selected from the group consisting of air, an air component, CO.sub.2, or a mixture of these components. The device includes at least one gas seal for sealing of the at least one insulation space from a further space. The gas seal includes butyl rubber as seal material.

A device or component thereof is provided for generation, transmission, distribution and/or use of electrical energy. In at least one insulation space formed within the device, there is a current-conducting component. The insulation space includes a dielectric insulation medium that surrounds the current-conducting component. This insulation medium includes a) at least one organofluorine compound selected from the group consisting of fluoroketones, fluoronitriles, and mixtures thereof and b) a carrier gas comprising at least one component selected from the group consisting of air, an air component, CO.sub.2, or a mixture of these components. The device includes at least one gas seal for sealing of the at least one insulation space from a further space. The gas seal includes butyl rubber as seal material.

Disclosed are compositions comprising HCFC-243db, HCFO-1233xf, HCFC-244db and/or HFO-1234yf and at least one additional compound. For the composition comprising 1234yf, the additional compound is selected from the group consisting of HFO-1234ze, HFO-1243zf, HCFC-243db, HCFC-244db, HFC-245cb, HFC-245fa, HCFO-1233xf, HCFO-1233zd, HCFC-253fb, HCFC-234ab, HCFC-243fa, ethylene, HFC-23, CFC-13, HFC-143a, HFC-152a, HFC-236fa, HCO-1130, HCO-1130a, HFO-1336, HCFC-133a, HCFC-254fb, HCFC-1131, HFO-1141, HCFO-1242zf, HCFO-1223xd, HCFC-233ab, HCFC-226ba, and HFC-227ca. Compositions comprising HCFC-243db, HCFO-1233xf, and/or HCFC-244db are useful in processes to make HFO-1234yf. Compositions comprising HFO-1234yf are useful, among other uses, as heat transfer compositions for use in refrigeration, air-conditioning and heat pump systems.