Patent classifications
H01G11/68
Current collector, electrode structure, nonaqueous electrolyte battery and electrical storage device, and method for producing current collector
Current collector, an electrode structure, a non-aqueous electrolyte battery, and an electrical storage device having superior shut down function are provided. According to the present invention, a current collector having a resin layer on at least one side of a conductive substrate is provided. Here, thermoplastic resin particles substantially free of a conductive agent are dispersed in a thermosetting resin base material containing the conductive agent to structure the resin layer; a value of mass ratio given by (thermoplastic resin particles)/(conductive agent) is 0.3 to 1.5; and a value given by (average thickness of conductive agent)/(average thickness of thermoplastic resin particles) is 0.3 to 4.0.
Supercapacitor configurations with graphene-based electrodes and/or peptide
One embodiment is an EDLC with a capacitor cell that includes two electrodes of opposite polarity aligned in parallel, and a peptide separator disposed between the electrodes. The separator may be a peptide coating on an electrode surface. Another embodiment is an electrode for an electrochemical energy storage device, such as an EDLC, the electrode including graphene and coated with peptide. The peptide may act as a separator for the EDLC. A further embodiment is an electrode for an electrochemical energy storage device, the electrode-unit including: two graphene layers, CNTs, and electrolyte. The graphene layers are arranged separated along a first axis and aligned with parallel surfaces, where at least one graphene layer is coated with peptide. The CNTs are arranged along a second axis orthogonal to the first axis and disposed between the graphene layers. The electrolyte is impregnated within the volume defined between the graphene layers and CNTs.
Supercapacitor configurations with graphene-based electrodes and/or peptide
One embodiment is an EDLC with a capacitor cell that includes two electrodes of opposite polarity aligned in parallel, and a peptide separator disposed between the electrodes. The separator may be a peptide coating on an electrode surface. Another embodiment is an electrode for an electrochemical energy storage device, such as an EDLC, the electrode including graphene and coated with peptide. The peptide may act as a separator for the EDLC. A further embodiment is an electrode for an electrochemical energy storage device, the electrode-unit including: two graphene layers, CNTs, and electrolyte. The graphene layers are arranged separated along a first axis and aligned with parallel surfaces, where at least one graphene layer is coated with peptide. The CNTs are arranged along a second axis orthogonal to the first axis and disposed between the graphene layers. The electrolyte is impregnated within the volume defined between the graphene layers and CNTs.
ELECTRODE COMPRISING ORGANIC SEMICONDUCTOR MATERIAL, METHOD FOR MANUFACTURING ELECTRODE, AND SUPERCAPACITOR COMPRISING ELECTRODE
The present invention relates to: an electrode comprising a current collector and a film located on the current collector, wherein the film comprises an organic semiconductor material and one selected from a carbon material, a metal oxide and a conductive polymer; a method for manufacturing the electrode; and a supercapacitor comprising the electrode.
ELECTRODE COMPRISING ORGANIC SEMICONDUCTOR MATERIAL, METHOD FOR MANUFACTURING ELECTRODE, AND SUPERCAPACITOR COMPRISING ELECTRODE
The present invention relates to: an electrode comprising a current collector and a film located on the current collector, wherein the film comprises an organic semiconductor material and one selected from a carbon material, a metal oxide and a conductive polymer; a method for manufacturing the electrode; and a supercapacitor comprising the electrode.
Aluminum foil for a current collector and method of manufacturing the same
At least one foil surface of an aluminum foil is roughened; and in arithmetic mean roughnesses Ra, stipulated in JIS B 0601:2001, of the roughened surface(s), A, which is the arithmetic mean roughness Ra measured in a direction at a right angle to a rolling direction during foil rolling, and B, which is the arithmetic mean roughness Ra measured in a direction parallel to the rolling direction during foil rolling, satisfy the following relationships: 0.15 μm≦A≦2.0 μm; 0.15 μm≦B≦2.0 μm; and 0.5≦B/A≦1.5. Preferably 50-1000 μg/m.sup.2 of oil is adhered to the roughened foil surface. The oil is preferably rolling oil.
Aluminum foil for a current collector and method of manufacturing the same
At least one foil surface of an aluminum foil is roughened; and in arithmetic mean roughnesses Ra, stipulated in JIS B 0601:2001, of the roughened surface(s), A, which is the arithmetic mean roughness Ra measured in a direction at a right angle to a rolling direction during foil rolling, and B, which is the arithmetic mean roughness Ra measured in a direction parallel to the rolling direction during foil rolling, satisfy the following relationships: 0.15 μm≦A≦2.0 μm; 0.15 μm≦B≦2.0 μm; and 0.5≦B/A≦1.5. Preferably 50-1000 μg/m.sup.2 of oil is adhered to the roughened foil surface. The oil is preferably rolling oil.
Current collector, electrode, secondary battery and capacitor
Provided are a current collector which has an excellent high-rate property and exerts a sufficient safety function when employed in a secondary battery or a capacitor, as well as an electrode, a secondary battery or a capacitor in which said current collector is employed. According to the invention, a current collector is provided which comprises: metal foil; and a conductive layer with a film thickness of 0.1 μm to 10 μm formed on a surface of said metal foil. Here, said conductive layer includes a conductive material and a binder material. A melting point of said binder material is 80° C. to 150° C. Further, said binder material shows, in differential scanning calorimetry (DSC) in a range from room temperature to 200° C., one or more endothermic peaks in the heating-up process. In a case where said binder material shows two or more endothermic peaks, each difference between said peaks is 15° C. or more. Moreover, said binder material shows one or more exothermic peaks in the cooling-down process. In a case where said binder material shows only one exothermic peak, said exothermic peak falls within a range of 50 to 120° C., and a width at half maximum of said exothermic peak is 10° C. or less. On the other hand, in a case where said binder material shows two or more exothermic peaks, a maximum exothermic peak among said exothermic peaks falls within a range of 50 to 120° C., and a width at half maximum of said exothermic peak is 10° C. or less.
Current collector, electrode, secondary battery and capacitor
Provided are a current collector which has an excellent high-rate property and exerts a sufficient safety function when employed in a secondary battery or a capacitor, as well as an electrode, a secondary battery or a capacitor in which said current collector is employed. According to the invention, a current collector is provided which comprises: metal foil; and a conductive layer with a film thickness of 0.1 μm to 10 μm formed on a surface of said metal foil. Here, said conductive layer includes a conductive material and a binder material. A melting point of said binder material is 80° C. to 150° C. Further, said binder material shows, in differential scanning calorimetry (DSC) in a range from room temperature to 200° C., one or more endothermic peaks in the heating-up process. In a case where said binder material shows two or more endothermic peaks, each difference between said peaks is 15° C. or more. Moreover, said binder material shows one or more exothermic peaks in the cooling-down process. In a case where said binder material shows only one exothermic peak, said exothermic peak falls within a range of 50 to 120° C., and a width at half maximum of said exothermic peak is 10° C. or less. On the other hand, in a case where said binder material shows two or more exothermic peaks, a maximum exothermic peak among said exothermic peaks falls within a range of 50 to 120° C., and a width at half maximum of said exothermic peak is 10° C. or less.
ALUMINUM MEMBER FOR ELECTRODES AND METHOD OF PRODUCING ALUMINUM MEMBER FOR ELECTRODES
Provided is an aluminum member for electrodes capable of stably maintaining a low electric resistance state, and a method of producing an aluminum member for electrodes. An aluminum member for electrodes includes an aluminum substrate and an oxide film that is laminated on at least one main surface of the aluminum substrate, and the oxide film has a density of 2.7 to 4.1 g/cm.sup.3 and a thickness of 5 nm or less.