An ultracapacitor that comprises a first and second electrochemical cell that are connected in parallel is provided. The cells are define by a first electrode that contains a current collector having opposing sides coated with a carbonaceous material, a second electrode that contains a current collector having opposing sides coated with a carbonaceous material, and a separator positioned between the first electrode and the second electrode. The second cell is by the second electrode, a third electrode that contains a current collector having opposing sides coated with a carbonaceous material, and a separator positioned between the second electrode and the third electrode. The ultracapacitor also contains a nonaqueous electrolyte that is in ionic contact with the electrodes and contains a nonaqueous solvent and an ionic liquid. A package encloses the first cell, the second cell, and the nonaqueous electrolyte.

Provided are an electrode capable of maintaining electrical conductivity during elongation and shrinkage, a method for manufacturing the same, and electrochemical device including the same.

Provided is a bi-polar electrode for a battery, wherein the bi-polar electrode comprises: (a) a current collector comprising a conductive material foil (e.g. metal foil) having a thickness from 10 nm to 100 μm and two opposed, parallel primary surfaces, wherein one or both of the primary surfaces is coated with a layer of graphene material having a thickness from 10 nm to 10 μm; and (b) a negative electrode layer and a positive electrode layer respectively disposed on the two sides of the current collector, each in physical contact with the layer of graphene material or directly with a primary surface of the conductive material foil (if not coated with a graphene material layer). Also provided is a battery comprising multiple (e.g. 2-300) bipolar electrodes internally connected in series. There can be multiple bi-polar electrodes that are connected in parallel.

Current collector, an electrode structure, a non-aqueous electrolyte battery, and an electrical storage device having superior shut down function are provided. According to the present invention, a current collector having a resin layer on at least one side of a conductive substrate is provided. Here, thermoplastic resin particles substantially free of a conductive agent are dispersed in a thermosetting resin base material containing the conductive agent to structure the resin layer; a value of mass ratio given by (thermoplastic resin particles)/(conductive agent) is 0.3 to 1.5; and a value given by (average thickness of conductive agent)/(average thickness of thermoplastic resin particles) is 0.3 to 4.0.

Current collector, an electrode structure, a non-aqueous electrolyte battery, and an electrical storage device having superior shut down function are provided. According to the present invention, a current collector having a resin layer on at least one side of a conductive substrate is provided. Here, thermoplastic resin particles substantially free of a conductive agent are dispersed in a thermosetting resin base material containing the conductive agent to structure the resin layer; a value of mass ratio given by (thermoplastic resin particles)/(conductive agent) is 0.3 to 1.5; and a value given by (average thickness of conductive agent)/(average thickness of thermoplastic resin particles) is 0.3 to 4.0.

One embodiment is an EDLC with a capacitor cell that includes two electrodes of opposite polarity aligned in parallel, and a peptide separator disposed between the electrodes. The separator may be a peptide coating on an electrode surface. Another embodiment is an electrode for an electrochemical energy storage device, such as an EDLC, the electrode including graphene and coated with peptide. The peptide may act as a separator for the EDLC. A further embodiment is an electrode for an electrochemical energy storage device, the electrode-unit including: two graphene layers, CNTs, and electrolyte. The graphene layers are arranged separated along a first axis and aligned with parallel surfaces, where at least one graphene layer is coated with peptide. The CNTs are arranged along a second axis orthogonal to the first axis and disposed between the graphene layers. The electrolyte is impregnated within the volume defined between the graphene layers and CNTs.

One embodiment is an EDLC with a capacitor cell that includes two electrodes of opposite polarity aligned in parallel, and a peptide separator disposed between the electrodes. The separator may be a peptide coating on an electrode surface. Another embodiment is an electrode for an electrochemical energy storage device, such as an EDLC, the electrode including graphene and coated with peptide. The peptide may act as a separator for the EDLC. A further embodiment is an electrode for an electrochemical energy storage device, the electrode-unit including: two graphene layers, CNTs, and electrolyte. The graphene layers are arranged separated along a first axis and aligned with parallel surfaces, where at least one graphene layer is coated with peptide. The CNTs are arranged along a second axis orthogonal to the first axis and disposed between the graphene layers. The electrolyte is impregnated within the volume defined between the graphene layers and CNTs.

The present disclosure further provides an exemplary energy storage device fabricated from rectangular-tube polyaniline (PANI) that is chemically synthesized by a simple and convenient method. The rectangular-tube PANI, as an active material, is synthesized on a functionalized carbon cloth (FCC) as a substrate, and the obtained composite is immobilized on a stainless steel mesh as a current collector. The present disclosure additionally presents a facile technique for the direct synthesis of PANI nanotubes, with rectangular pores, on chemically activated CC.

Provided is an adhesive composition for an electrochemical device capable of forming an adhesive layer that has excellent adhesiveness in electrolysis solution and can improve electrical characteristics of an electrochemical device. The adhesive composition can be used for adhering an electrode assembly and a casing to one another. The adhesive composition contains organic particles having a core-shell structure including a core portion and a shell portion that partially covers an outer surface of the core portion. A polymer of the core portion has a degree of swelling in electrolysis solution of at least a factor of 5 and no greater than a factor of 30, whereas a polymer of the shell portion has a degree of swelling in electrolysis solution of greater than a factor of 1 and no greater than a factor of 4.

Provided is an adhesive composition for an electrochemical device capable of forming an adhesive layer that has excellent adhesiveness in electrolysis solution and can improve electrical characteristics of an electrochemical device. The adhesive composition can be used for adhering an electrode assembly and a casing to one another. The adhesive composition contains organic particles having a core-shell structure including a core portion and a shell portion that partially covers an outer surface of the core portion. A polymer of the core portion has a degree of swelling in electrolysis solution of at least a factor of 5 and no greater than a factor of 30, whereas a polymer of the shell portion has a degree of swelling in electrolysis solution of greater than a factor of 1 and no greater than a factor of 4.