The present disclosure is directed to fluoride (F) ion batteries and F shuttle batteries comprising an anode with a solid electrolyte interphase (SEI) layer, a cathode comprising a core shell structure, and a liquid fluoride battery electrolyte. According to some aspects, the components therein enable discharge and recharge at room-temperature.

A printed energy storage device includes a first electrode including zinc, a second electrode including manganese dioxide, and a separator between the first electrode and the second electrode, the first electrode, second, electrode, and separator printed onto a substrate. The device may include a first current collector and/or a second current collector printed onto the substrate. The energy storage device may include a printed intermediate layer between the separator and the first electrode. The first electrode, and the second electrode may include 1-ethyl-3-methylimidazolium tetrafluoroborate (C.sub.2mimBF.sub.4). The first electrode and the second electrode may include an electrolyte having zinc tetrafluoroborate (ZnBF.sub.4) and 1-ethyl-3-methylimidazolium tetrafluoroborate (C.sub.2mimBF.sub.4). The first electrode, the second electrode, the first current collector, and/or the second current collector can include carbon nanotubes. The separator may include solid microspheres.

A non-aqueous electrolyte battery includes a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, and a nonaqueous electrolytic solution. The positive electrode, the separator, and the negative electrode are spirally wound. The positive electrode includes a positive electrode active material and an expanded metal. The positive electrode has a thickness larger than or equal to 0.8 mm and smaller than or equal to 3 mm. A thickness T of the expanded metal satisfies 0.15 mm≤T≤0.3 mm. A center-to-center distance SW of the expanded metal in a shorter direction in mesh and a center-to-center distance LW of the expanded metal in a longer direction in mesh satisfy 6 mm.sup.2≤LW.Math.SW≤20 mm.sup.2. A feed width W of the expanded metal satisfies 0.15 mm≤W≤0.3 mm.

A nonaqueous electrolyte secondary battery includes a positive electrode, a negative electrode and an electrolyte solution, wherein the negative electrode includes a negative active material layer, the electrolyte solution contains fluoroethylene carbonate, and when a content (mg) of the fluoroethylene carbonate is denoted as X and a reaction area (m.sup.2) of the negative active material layer is denoted as Y, X and Y satisfy a relation of 10≦(X/Y)≦100.

A battery configured to support a relatively high rate of energy discharge relative to its capacity for energy intensive therapy delivery. The battery includes a feedthrough insulator cap disposed within the interior of the battery on at least a portion of a ferrule, at least a portion of an insulator, and at least a portion of a pin, which define a feedthrough extending through an enclosure of the battery; a first electrode disposed within the enclosure and electrically coupled to the pin; a second electrode disposed within the enclosure and separated a distance from the first electrode; and an electrolyte disposed between the first electrode and the second electrode. During operation of the battery, the feedthrough insulator cap reduces dendrite formation on at least a portion of the ferrule, the pin, or both.

A DME-free lithium battery includes a positive electrode, a negative electrode, a separator arranged between the positive electrode and the negative electrode, and a liquid electrolyte composed of a solvent and at least one lithium electrolyte salt and with which the electrode and the separator are impregnated, wherein the solvent includes propylene carbonate (PC) as a first solvent component and 1,3-dioxolane (DOL) as a second solvent component, and the positive electrode and/or the negative electrode have a proportion of carbon black having a BET surface area of at least 1 m.sup.2/g.

A nonaqueous electrolyte primary battery with improved storage properties at high temperatures and excellent reliability, and a method for producing the battery are provided. The nonaqueous electrolyte primary battery includes a negative electrode containing metallic lithium or a lithium alloy, a positive electrode, a separator, and a nonaqueous electrolyte solution. The nonaqueous electrolyte solution contains at least LiClO.sub.4 as an electrolyte and 0.1 to 5% by mass of LiB(C.sub.2O.sub.4).sub.2.

An electrochemical cell comprising a cathode and an anode residing within a casing, the anode being positioned distal of the cathode. The cathode having a cathode current collector having an angled configuration that encourages the cathode active material to move in an axial distal direction during cell discharge. The cathode current collector may be configured having at least one fold thereby dividing the current collector into at least two portions having an angle therebetween. The cathode current collector may comprise a wire having a helical configuration or the cathode current collector may comprise a post with a thread having a helical orientation about the post exterior. A preferred chemistry is a lithium/CF.sub.x activated with a nonaqueous electrolyte.

The present disclosure relates to the field of energy storage materials, and particularly, to an electrolyte and an electrochemical device. The electrolyte includes an additive A and an additive B, the additive A is selected from a group consisting of multi-cyano six-membered N-heterocyclic compounds represented by Formula I-1, Formula I-2 and Formula I-3, and combinations thereof, and the additive B is at least one halogenated cyclic carbonate compound. The electrochemical device includes the above electrolyte. The electrolyte of the present disclosure can effectively passivate surface activity of the positive electrode material, inhibit oxidation of the electrolyte, and effectively reduce gas production of the battery, while an anode SEI film can be formed to avoid a contact between the anode and the electrode and thus to effectively reduce side reactions.

Cathodes containing active materials and carbon nanotubes are described. The use of carbon nanotubes in cathode materials can provide a battery having increased longevity and volumetric capacity over batteries that contain a cathode that uses conventional conductive additives such as carbon black or graphite.