A thermal battery can include: an anode of lithium alloy; a metal-fluoride cathode having Ni; and an electrolyte composition in contact with the anode and cathode. A thermal battery can also include: an anode of lithium alloy; a metal-fluoride cathode having an oxide selected from V.sub.2O.sub.5 or LiVO.sub.3; and an electrolyte composition in contact with the anode and cathode. In one aspect, a metal of the metal fluoride cathode includes Ni, Fe, V, Cr, Mn, Co, or mixture thereof. In one aspect, the metal-fluoride cathode includes NiF.sub.2, FeF.sub.3, VF.sub.3, CrF.sub.3, MnF.sub.3, CoF.sub.3, or a mixture thereof. A method of providing electricity can include: providing an electronic device having a thermal battery with a metal-fluoride cathode having Ni and/or having an oxide selected from V.sub.2O.sub.5 or LiVO.sub.3; and discharging the thermal battery to provide electricity.

A thermal battery can include: an anode of lithium alloy; a metal-fluoride cathode having Ni; and an electrolyte composition in contact with the anode and cathode. A thermal battery can also include: an anode of lithium alloy; a metal-fluoride cathode having an oxide selected from V.sub.2O.sub.5 or LiVO.sub.3; and an electrolyte composition in contact with the anode and cathode. In one aspect, a metal of the metal fluoride cathode includes Ni, Fe, V, Cr, Mn, Co, or mixture thereof. In one aspect, the metal-fluoride cathode includes NiF.sub.2, FeF.sub.3, VF.sub.3, CrF.sub.3, MnF.sub.3, CoF.sub.3, or a mixture thereof. A method of providing electricity can include: providing an electronic device having a thermal battery with a metal-fluoride cathode having Ni and/or having an oxide selected from V.sub.2O.sub.5 or LiVO.sub.3; and discharging the thermal battery to provide electricity.

The present invention provides a fiber-reinforced aerogel material which can be used as insulation in thermal battery applications. The fiber-reinforced aerogel material is highly durable, flexible, and has a thermal performance that exceeds the insulation materials currently used in thermal battery applications. The fiber-reinforced aerogel insulation material can be as thin as 1 mm less, and can have a thickness variation as low as 2% or less. Also provided is a method for improving the performance of a thermal battery by incorporating a reinforced aerogel material into the thermal battery. Further provided is a casting method for producing thin fiber-reinforced aerogel materials.

The present invention provides a fiber-reinforced aerogel material which can be used as insulation in thermal battery applications. The fiber-reinforced aerogel material is highly durable, flexible, and has a thermal performance that exceeds the insulation materials currently used in thermal battery applications. The fiber-reinforced aerogel insulation material can be as thin as 1 mm less, and can have a thickness variation as low as 2% or less. Also provided is a method for improving the performance of a thermal battery by incorporating a reinforced aerogel material into the thermal battery. Further provided is a casting method for producing thin fiber-reinforced aerogel materials.

A battery includes a fluid negative electrode and a fluid positive electrode separated by a solid electrolyte at least when the electrodes and electrolyte are at an operating temperature. The solid electrolyte includes ions of the negative electrode material forming the fluid negative electrode and has a softness less than beta-alumina solid electrolyte (BASE) ceramics. In one example, the fluid negative electrode comprises lithium (Li), the fluid positive electrode comprises sulfur (S) and the solid electrolyte comprises lithium iodide (LiI).

A heat to electricity converter including a working fluid and a pair of membrane electrode assemblies (MEA) is provided. Each MEA includes a pair of electrodes which are electron conductive and permeable to the working fluid, and a thin film electrolyte membrane sandwiched between the electrodes. The membrane is conductive of ions of the working fluid and has a thickness of 0.03 μm to 10 μm. At least one electrode of each MEA includes a non-porous and dense metal. One electrode of each MEA is in contact with the working fluid at a first, higher pressure, while the other electrode is in contact with the working fluid at a second, lower pressure. The first MEA is configured to compress the working fluid from the second pressure to the first pressure, while the second MEA is configured to expand the working fluid from the first pressure to the second pressure.

A heat to electricity converter including a working fluid and a pair of membrane electrode assemblies (MEA) is provided. Each MEA includes a pair of electrodes which are electron conductive and permeable to the working fluid, and a thin film electrolyte membrane sandwiched between the electrodes. The membrane is conductive of ions of the working fluid and has a thickness of 0.03 μm to 10 μm. At least one electrode of each MEA includes a non-porous and dense metal. One electrode of each MEA is in contact with the working fluid at a first, higher pressure, while the other electrode is in contact with the working fluid at a second, lower pressure. The first MEA is configured to compress the working fluid from the second pressure to the first pressure, while the second MEA is configured to expand the working fluid from the first pressure to the second pressure.

Systems and methods are provided for generating electric power using low grade thermal energy from a vehicle. The methods may include surrounding at least a portion of a coolant conduit system with a flexible thermo-electrochemical cell including a nanoporous cathode electrode, a nanoporous anode electrode, and an electrolyte. A coolant fluid may be circulated through the coolant conduit system, which is in thermal communication with a power generating unit, such as an internal combustion engine or fuel cell stack. The method includes maintaining a temperature gradient in the electrolyte solution by contacting the anode electrode with the coolant conduit system, and exposing the cathode electrode to a temperature lower than a temperature of the coolant conduit system. Generated electrical charges can be collected for subsequent use.

Systems and methods are provided for generating electric power using low grade thermal energy from a vehicle. The methods may include surrounding at least a portion of a coolant conduit system with a flexible thermo-electrochemical cell including a nanoporous cathode electrode, a nanoporous anode electrode, and an electrolyte. A coolant fluid may be circulated through the coolant conduit system, which is in thermal communication with a power generating unit, such as an internal combustion engine or fuel cell stack. The method includes maintaining a temperature gradient in the electrolyte solution by contacting the anode electrode with the coolant conduit system, and exposing the cathode electrode to a temperature lower than a temperature of the coolant conduit system. Generated electrical charges can be collected for subsequent use.

The invention provides a water-activated, deferred-action battery having a housing containing at least one cell, comprising at least one anode selected from the group consisting of magnesium, aluminum, zinc and alloys thereof; a cathode comprising a skeletal frame including conductive metal and having a portion of its surface area formed as open spaces, and further comprising a heat-pressed, rigid static bed of active cathode material encompassing the skeletal frame, the cathode material comprising basic copper sulfate, said cathode material being compacted and fused to itself and to the skeletal frame under pressure and/or heat, to form a heat-fused, conductive, electrochemically active phase; at least one cavity separating the cathode and the at least one anode, and at least one aperture leading to the at least one cavity for the ingress of an electrolyte-forming, aqueous liquid.