A method of cleaning power cells in an array of power cells, comprising coupling at least one first power cell to second power cells in an array of power cells and causing the second power cells to drive the at least one first power cell with a voltage to clean catalyst on the at least one first power cell.

A fuel cell stack, includes a plurality of fuel cells. Each fuel cell includes a shell, an anode and a cathode mounted in the shell. A liquid storage chamber used for storing electrolyte and a communicating part used for communicating the liquid storage chamber are provided in the shell of each fuel cell. The liquid storage chambers of every two adjacent fuel cells communicate by the communicating part. The liquid storage chambers of every two adjacent fuel cells communicate through the communicating part, so that the electrolyte of each fuel cell can cross flow each other to make the electrolyte of each unit highly consistent. Therefore, the performance parameters of each fuel cell in the same fuel cell stack are basically the same, rendering the working performance of fuel cell stack improved. The present invention also relates to a fuel cell and a shell.

A fuel cell stack, includes a plurality of fuel cells. Each fuel cell includes a shell, an anode and a cathode mounted in the shell. A liquid storage chamber used for storing electrolyte and a communicating part used for communicating the liquid storage chamber are provided in the shell of each fuel cell. The liquid storage chambers of every two adjacent fuel cells communicate by the communicating part. The liquid storage chambers of every two adjacent fuel cells communicate through the communicating part, so that the electrolyte of each fuel cell can cross flow each other to make the electrolyte of each unit highly consistent. Therefore, the performance parameters of each fuel cell in the same fuel cell stack are basically the same, rendering the working performance of fuel cell stack improved. The present invention also relates to a fuel cell and a shell.

Crossover of active materials in an electrochemical cell can detrimentally impact operating performance, particularly for flow batteries. Flow batteries with tolerance toward crossover of active materials can incorporate a first half-cell containing a first electrolyte solution that includes a coordination complex as a first active material, and a second half-cell containing a second electrolyte solution that includes an unbound form of an organic compound as a second active material. The coordination complex contains a redox-active metal center and an organic compound bound to the redox-active metal center. The unbound form of the organic compound in the second electrolyte solution is the same as the bound organic compound in the first electrolyte solution, or an oxidized or reduced variant thereof. Catechol and substituted catechols can be particularly desirable organic compounds for inclusion in the coordination complex and the second electrolyte solution.

Crossover of active materials in an electrochemical cell can detrimentally impact operating performance, particularly for flow batteries. Flow batteries with tolerance toward crossover of active materials can incorporate a first half-cell containing a first electrolyte solution that includes a coordination complex as a first active material, and a second half-cell containing a second electrolyte solution that includes an unbound form of an organic compound as a second active material. The coordination complex contains a redox-active metal center and an organic compound bound to the redox-active metal center. The unbound form of the organic compound in the second electrolyte solution is the same as the bound organic compound in the first electrolyte solution, or an oxidized or reduced variant thereof. Catechol and substituted catechols can be particularly desirable organic compounds for inclusion in the coordination complex and the second electrolyte solution.

Provided is a layered double hydroxide (LDH) separator including a porous substrate made of a polymeric material; and a hydroxide-ion conductive layered compound being a LDH and/or a LDH-like compound with which pores of the porous substrate are plugged. The LDH separator has a mean porosity of 0.03% to less than 1.0%.

The present disclosure is directed, in certain embodiments, to a flow cell battery system. A battery management system detects that a first power module and a second power module located adjacent to the first power module are operating at different states of charge. After determining that the second power module is at the lower state of charge than the first power module, a negative-side switch associated with the second power module is adjusted to an open position, thereby preventing flow of electrical current from a negative terminal of the second power module to electrical ground.

The present disclosure is directed, in certain embodiments, to a flow cell battery system. A battery management system detects that a first power module and a second power module located adjacent to the first power module are operating at different states of charge. After determining that the second power module is at the lower state of charge than the first power module, a negative-side switch associated with the second power module is adjusted to an open position, thereby preventing flow of electrical current from a negative terminal of the second power module to electrical ground.

An elevated target amount of electrolyte is used to initially fill a molten carbonate fuel cell that is operated under carbon capture conditions. The increased target electrolyte fill level can be achieved in part by adding additional electrolyte to the cathode collector prior to start of operation. The increased target electrolyte fill level can provide improved fuel cell performance and lifetime when operating a molten carbonate fuel cell at high current density with a low-CO.sub.2 content cathode input stream and/or when operating a molten carbonate fuel cell at high CO.sub.2 utilization.

An elevated target amount of electrolyte is used to initially fill a molten carbonate fuel cell that is operated under carbon capture conditions. The increased target electrolyte fill level can be achieved in part by adding additional electrolyte to the cathode collector prior to start of operation. The increased target electrolyte fill level can provide improved fuel cell performance and lifetime when operating a molten carbonate fuel cell at high current density with a low-CO.sub.2 content cathode input stream and/or when operating a molten carbonate fuel cell at high CO.sub.2 utilization.