An illustrative example fuel cell assembly includes a plurality of fuel cells arranged in a stack including a first end fuel cell near a first end of the stack and a second end fuel cell near a second end of the stack. Each of the fuel cells includes a matrix containing an electrolyte, an anode and a cathode on opposite sides of the matrix, and respective flow fields adjacent the anode and the cathode. An electrolyte supply associated with the anode flow field of the first end fuel cell includes a porous material containing electrolyte. An electrolyte collector associated with the cathode flow field of the second end fuel cell includes a porous material configured to collect electrolyte from at least the cathode of the second end fuel cell.

An illustrative example fuel cell assembly includes a plurality of fuel cells arranged in a stack including a first end fuel cell near a first end of the stack and a second end fuel cell near a second end of the stack. Each of the fuel cells includes a matrix containing an electrolyte, an anode and a cathode on opposite sides of the matrix, and respective flow fields adjacent the anode and the cathode. An electrolyte supply associated with the anode flow field of the first end fuel cell includes a porous material containing electrolyte. An electrolyte collector associated with the cathode flow field of the second end fuel cell includes a porous material configured to collect electrolyte from at least the cathode of the second end fuel cell.

An elevated target amount of electrolyte is used to initially fill a molten carbonate fuel cell that is operated under carbon capture conditions. The increased target electrolyte fill level can be achieved in part by adding additional electrolyte to the cathode collector prior to start of operation. The increased target electrolyte fill level can provide improved fuel cell performance and lifetime when operating a molten carbonate fuel cell at high current density with a low-CO.sub.2 content cathode input stream and/or when operating a molten carbonate fuel cell at high CO.sub.2 utilization.

An elevated target amount of electrolyte is used to initially fill a molten carbonate fuel cell that is operated under carbon capture conditions. The increased target electrolyte fill level can be achieved in part by adding additional electrolyte to the cathode collector prior to start of operation. The increased target electrolyte fill level can provide improved fuel cell performance and lifetime when operating a molten carbonate fuel cell at high current density with a low-CO.sub.2 content cathode input stream and/or when operating a molten carbonate fuel cell at high CO.sub.2 utilization.

Embodiments of the invention relate to a novel class of polymers with superior mechanical properties and chemical stability, as compared to known polymers. These polymers are particularly well suited for use in anion exchange membranes (AEMs), including those employed in fuel cells. Novel methods for the manufacture of these polymers are also described.

Provided is a layered double hydroxide (LDH) separator comprising a porous substrate made of a polymeric material; and a LDH with which pores of the porous substrate are plugged. A central region along the thickness of the LDH separator has a lower mean porosity than peripheral regions along the thickness of the LDH separator.

Provided is a layered double hydroxide (LDH) separator including a porous substrate made of a polymeric material; and a LDH with which pores of the porous substrate are plugged. The LDH separator has a mean porosity of 0.03% to less than 1.0%.

Provided is a layered double hydroxide (LDH) separator including a porous substrate made of a polymeric material; and a LDH with which pores of the porous substrate are plugged. The LDH separator has a mean porosity of 0.03% to less than 1.0%.

An illustrative example fuel cell device includes a cell stack assembly of a plurality of fuel cells that each include an anode and a cathode. A pressure plate is situated near one end of the cell stack assembly. An intermediate component is situated between the end of the cell stack assembly and the pressure plate. The intermediate component includes a porous material in at least two fluid reservoirs and a barrier between the two fluid reservoirs to prevent fluid communication between the reservoirs.

An illustrative example fuel cell device includes a cell stack assembly of a plurality of fuel cells that each include an anode and a cathode. A pressure plate is situated near one end of the cell stack assembly. An intermediate component is situated between the end of the cell stack assembly and the pressure plate. The intermediate component includes a porous material in at least two fluid reservoirs and a barrier between the two fluid reservoirs to prevent fluid communication between the reservoirs.