A zipped ion-exchange membrane (Z-IEM) having at least one cation-exchange polyelectrolyte (CEP) crosslinked with at least one anion-exchange polyelectrolyte (AEP), wherein the CEP has a molar fraction of positive charges (x) so that: (i) when x=0.5, the Z-IEM is a completely neutralized ion-exchange membrane; (ii) when x>0.5, the Z-IEM is a cation-conducting ion-exchange membrane; (iii) when x<0.5, the Z-IEM is an anion-conducting ion-exchange membrane.

The above zipped ion-exchange membrane (Z-IEM): (i) is based on a polymeric matrix; (ii) is endowed with a high conductivity for ionic species such as either H.sub.3O.sup.+, OH.sup.− or halides such as F.sup.−, Cl.sup.−, Br.sup.−, and I.sup.−; and (iii) is able to block as much as possible the crossover of other ionic species, such as: cations such as V.sup.2+, V.sup.3+, VO.sup.2+, VO.sup.2+, Fe.sup.2+, Fe.sup.3+, Cr.sup.2+, Cr.sup.3+, Ce.sup.3+, Ce.sup.4+, Ti.sup.3+, Ti.sup.4+, Mn.sup.2+, Mn.sup.3+, Zn.sup.2+, Pb.sup.2+, Np.sup.3+, Np.sup.4+, NpO.sub.2.sup.2+, NpO.sub.2.sup.+, Li.sup.+, Na.sup.+, K.sup.+, Rb.sup.+, Cs.sup.+, Mg.sup.2+, Ca.sup.2+, Sr.sup.2+, Ba.sup.2+; and anions such as F.sup.−, BF.sub.4.sup.−, Cl.sup.−, ClO.sup.−, ClO.sub.2.sup.−, ClO.sub.3.sup.−, ClO.sub.4.sup.−, Br.sup.−, Br.sub.3.sup.−, I.sup.−, I.sub.3.sup.−.

A method for generating electrical energy includes providing an electrical energy generating element. The electrical energy generating element includes a first porous electrode, an eggshell membrane, and a second porous electrode stacked on each other in that order. The electrical energy generating element has a first side and a second side opposite to the first side. A liquid having positive ions and negative ions is allowed to penetrate the electrical energy generating element from the first side to the second side.

A method for generating electrical energy includes providing an electrical energy generating element. The electrical energy generating element includes a first porous electrode, an eggshell membrane, and a second porous electrode stacked on each other in that order. The electrical energy generating element has a first side and a second side opposite to the first side. A liquid having positive ions and negative ions is allowed to penetrate the electrical energy generating element from the first side to the second side.

The present invention relates to a solid oxide fuel cell especially protonic ceramic fuel cell which can operate at intermediate temperature and fuel cell thereof. The composition comprising a formula BaCe.sub.0.7Zr.sub.0.25-xY.sub.xZn.sub.0.05O.sub.3-δ or BaCe.sub.0.7Zr.sub.0.1Y.sub.0.2-xPr.sub.xO.sub.3-δ, wherein x=0.05, 0.1, 0.15, 0.2 or 0.25 to vary Zr and Y percentage at the B-site, and Ba=100%, Ce=70%; and Zn=5%.

The present invention relates to a solid oxide fuel cell especially protonic ceramic fuel cell which can operate at intermediate temperature and fuel cell thereof. The composition comprising a formula BaCe.sub.0.7Zr.sub.0.25-xY.sub.xZn.sub.0.05O.sub.3-δ or BaCe.sub.0.7Zr.sub.0.1Y.sub.0.2-xPr.sub.xO.sub.3-δ, wherein x=0.05, 0.1, 0.15, 0.2 or 0.25 to vary Zr and Y percentage at the B-site, and Ba=100%, Ce=70%; and Zn=5%.

A composite proton conductive membrane, comprising an inorganic filler having covalently bonded acidic functional groups and a high surface area of at least 150 m.sup.2/g; and a water insoluble ionically conductive polymer. This membrane provides advantages over traditional polymeric proton conductive membranes for redox flow battery, fuel cell, and electrolysis applications include: 1) enhanced proton conductivity/permeance due to the formation of additional nanochannels for proton conducting; 2) improved proton/electrolyte selectivity for redox flow battery application; 3) reduced membrane swelling and gas or electrolyte crossover; 4) improved chemical stability; 5) increased cell operation time with stable performance, and 6) reduced membrane cost.

The present invention to provide a highly proton conducting metal organic material constituting of phosphate ester based ligand immobilized via gelation with Fe.sup.3 ion in DMF which is used as conducting electrolyte in PEFMCs.

The present invention to provide a highly proton conducting metal organic material constituting of phosphate ester based ligand immobilized via gelation with Fe.sup.3 ion in DMF which is used as conducting electrolyte in PEFMCs.

The present invention relates to a gas diffusion layer including a porous carbonaceous film layer for a fuel cell, in which the average pore diameter of the porous carbonaceous film layer is 0.1 μm to 100 μm, a membrane-electrode assembly including the gas diffusion layer, and a fuel cell including the membrane-electrode assembly.

The present invention relates to a gas diffusion layer including a porous carbonaceous film layer for a fuel cell, in which the average pore diameter of the porous carbonaceous film layer is 0.1 μm to 100 μm, a membrane-electrode assembly including the gas diffusion layer, and a fuel cell including the membrane-electrode assembly.