H01M2008/1095

METHOD FOR STARTING UP A FUEL CELL SYSTEM AFTER A STANDSTILL
20230238554 · 2023-07-27 ·

A fuel cell system is provided that includes a fuel cell with an assembly of multiple individual cells, each of which has an anode section, an electrolyte membrane, and a cathode section, an anode gas supply, which leads to an anode gas inlet and includes a fuel cell and a fuel metering device, a cathode gas supply, and a passive anode gas recirculation device, which connects an anode gas outlet to the recirculation gas inlet of a mixer arranged in the anode gas supply. The fuel cell system is started up after a standstill in that in a first phase, the fuel cell is activated while fuel is supplied from the fuel source, and the anode recirculation is suppressed without actively blocking the anode gas recirculation device, and in a second phase, anode gas is recirculated in addition to the supply of fuel from the fuel source.

FUEL RECIRCULATION IN A FUEL CELL DEVICE HAVING A PLURALITY OF FUEL CELL STACKS
20230238551 · 2023-07-27 ·

A fuel cell device with a fuel tank which has a fuel supply line which is branched into fuel portion supply lines, having a plurality of fuel cell stacks which stacks each have, on the anode inlet side, a fuel connection which is respectively fluidically connected to one of the fuel portion supply lines. Exclusively one of the fuel cell stacks is connected on the anode outlet side to a fuel recirculation line. The flow guidance of the fuel recirculation line is selected in such a way that the fuel can be returned exclusively into the fuel cell stack connected to the fuel recirculation line. Furthermore, a method for operating the fuel cell device is provided.

CARBON-BASED CALCINED MATERIAL AND COMPLEX THEREOF AS WELL AS FUEL CELL USING THE CARBON-BASED CALCINED MATERIAL

A stable form which uses a carbon material having electrical conductivity as a raw material and that the electrical conductivity of the carbon material is retained and/or improved, and which improves the electricity generation properties when used in a catalyst layer for a fuel cell. The present invention is directed to, e.g., a calcined material of a mixture of an aromatic compound having a phenolic hydroxyl group and a carbon material having electrical conductivity.

MEMBRANE ELECTRODE ASSEMBLY AND POLYMER ELECTROLYTE FUEL CELL
20230238558 · 2023-07-27 · ·

To provide a membrane electrode assembly capable of forming a fuel cell excellent in power generation efficiency, and a polymer electrolyte fuel cell. The membrane electrode assembly of the present invention comprises an anode having a catalyst layer containing a proton-conducting polymer and a catalyst, a cathode having a catalyst layer containing a proton-conducting polymer and a catalyst, and a solid polymer electrolyte membrane disposed between the anode and the cathode, wherein the proton-conducting polymer contained in the catalyst layer of at least one of the anode and the cathode, is a polymer (H) having a cyclic ether structural unit and an ion exchange group, and the solid polymer electrolyte membrane contains a fluorinated polymer (S) having an ion exchange group; and the thickness of the solid polymer electrolyte membrane is from 5 to 15 μm, and the ratio of the content M1 [mol %] of the cyclic ether structure unit to the thickness T1 [μm] of the solid polymer electrolyte membrane is 4.5 or more.

BIOMASS-BASED SOLID COMPOSITE ELECTROLYTES FOR BATTERIES

Provided are composite electrolytes having a bio-based gel electrolyte in an ordered structure of a porous solid. In some embodiments, the gel electrolyte includes a glycolate gel, a glycerate gel, a bio-based compound-derived gel or a combination thereof. Also provided are electrochemical systems (electrodeposition), redox flow batteries, fuel cells, lithium-ion batteries and lithium-metal batteries including the composite electrolytes, and methods for producing gel electrolytes. In some embodiments, the methods including reacting a polyol, optionally ethylene glycol, propanediol, butanediol, pentanediol, diethylene glycol, glycerol, or any combination thereof, with a lithium metal and/or a lithium salt, optionally lithium hydroxide, a sodium salt, optionally sodium hydroxide (NaOH), NaTFSI, NaBF.sub.4, or NaPF.sub.6; an aluminum salt; a potassium salt, a magnesium salt; a calcium salt; a zinc salt; or any combination thereof.

POLYMER ELECTROLYTE MEMBRANE, MANUFACTURING METHOD THEREFOR, AND ELECTROCHEMICAL DEVICE COMPRISING SAME
20230006231 · 2023-01-05 ·

Disclosed are a polymer electrolyte membrane having high flexibility, high ionic conductivity, and excellent mechanical durability, a method for manufacturing same, and an electrochemical device comprising same. The polymer electrolyte membrane of the present invention comprises a polymer electrolyte material, wherein the polymer electrolyte material comprises: an ion conductor having an ion-exchange group; and an organic compound which binds to the ion-exchange group via an ionic bond or a hydrogen bond, thereby allowing the polymer electrolyte material to have an ionic crosslink structure or a hydrogen bond crosslink structure.

SYSTEM FOR REGENERATING A FUEL CELL AND REGENERATION METHOD

A fuel cell and a method for regenerating this fuel cell, including a supply of the fuel cell by the main supply conduit by a fluid having a nominal flow rate and a nominal molar fraction of combustion agent, during a regeneration phase of a given group, a switching of the inlet, outlet and recirculation switches of the fluid circuit so as to supply the given group from the recirculation line of the given group and from a fluid discharge line of at least one other group, an application of a regeneration voltage Ve to the cells of the given group, Ve being less than or equal to 0.3V.

Method for manufacturing membrane electrode assembly for fuel cell

The present disclosure provides a method for manufacturing a membrane electrode assembly for a fuel cell in which a transfer failure is suppressed. The present disclosure relates to a method for manufacturing a membrane electrode assembly for a fuel cell, which comprises intermittently applying a catalyst ink on a substrate sheet and drying the catalyst ink to form a catalyst layer on the substrate sheet, and transferring the catalyst layer from the substrate sheet onto an electrolyte membrane. The catalyst ink contains catalyst particles, an ionomer, an alcohol, and water, and a water content in the catalyst ink is 57% to 61% by weight of a total weight of the catalyst ink.

Flow field designs for tailored permeability fuel cell bipolar plates

A bipolar plate with an enhanced fluid flow field design is provided for a fuel cell. The bipolar plate includes an inlet, an outlet, and a flow field having a pattern defining a plurality of microchannels configured to provide fluid communication between the inlet and the outlet. The pattern is designed using an inverse permeability field, and is based on a reaction-diffusion algorithm to model channel spacing, thereby providing a variable pitch microchannel pattern to direct fluid from the inlet to the outlet. In various aspects, the reaction-diffusion algorithm utilize Gray-Scott reaction-diffusion equations, which may be used to obtain an anisotropic microchannel layout. The variable pitch microchannel pattern may include a channel spacing based on effective medium theory.

Polymer electrolyte membrane for medium and high temperature, preparation method thereof and high temperature polymer electrolyte membrane fuel cell comprising the same

The present disclosure relates to a polymer electrolyte membrane for medium and high temperature, a preparation method thereof and a high-temperature polymer electrolyte membrane fuel cell including the same, more particularly to a technology of preparing a composite membrane including an inorganic phosphate nanofiber incorporated into a phosphoric acid-doped polybenzimidazole (PBI) polymer membrane by adding an inorganic precursor capable of forming a nanofiber in a phosphoric acid solution when preparing phosphoric acid-doped polybenzimidazole and using the same as a high-temperature polymer electrolyte membrane which is thermally stable even at high temperatures of 200-300° C. without degradation of phosphoric acid and has high ion conductivity.