A proton conductor of the present disclosure includes a compound represented by the chemical formula BaZr.sub.(1-x-y)Yb.sub.xSc.sub.yO.sub.3-δ. The chemical formula satisfies 0<x<0.5, 0 <y<0.5, (x+y)<0.5, and 0<δ<0.5.

An object of the present invention is to provide a hydrogen permeable material having excellent hydrogen permeability. Another object of the present invention is to provide a composite member and a fuel cell including the hydrogen permeable material. The hydrogen permeable material comprises a perovskite type compound represented by the following general formula (1a). In another embodiment, the hydrogen permeable material comprises a hydrogen-containing perovskite type compound, which is the perovskite type compound represented by the general formula (1a) with introduced hydride ion (H.sup.−). Wherein M is at least one alkaline earth metal selected from the group consisting of Ba, Sr and Ca, x is a numerical value of 0 or more and 0.3 or less, y is a numerical value of more than 0 and 0.75 or less, w is a value at which an average valence of In is +1.0 or more and +2.5 or less, and y≥w.

M.sub.1-xZr.sub.1-yIn.sub.yO.sub.3-x-0.5y-2  (1a)

The present specification relates to a connecting material for a solid oxide fuel cell, comprising a conductive substrate; and a ceramic protective film provided on one surface of the conductive substrate, in which the ceramic protective film comprises an oxide represented by Formula 1, a manufacturing method thereof, and a solid oxide fuel cell comprising the same.

A cell stack device includes cells, a metal member containing chromium, a covering layer, and a bonding material. The cells include a first cell and the cells includes respective element portions. The covering layer covers the metal member. The bonding material is positioned between the first cell and the covering layer. The cell stack device satisfies any one of (1) The covering layer includes at least two portions having different thicknesses or different surface roughnesses at different positions. (2) A surface roughness of the covering layer is different from that of the metal member. (3) At least one element selected from the group consisting of Mn, Ti, Ca, and Al is positioned at the interface between the metal member and the covering layer, and the content ratio of the at least one element at the interface is different from that of the metal member or the covering layer.

The invention provides a water tank heating method and unit, an electronic device and a solid oxide fuel cell (SOFC) system. Before the SOFC system is started, ice in a water tank has been heated up, so after the SOFC system is started, the heating time of the heated ice, i.e., the thawing time of the water tank, will be shortened. Further, in the ice heating process, a pre-set needed SOFC thawing time determined according to current stack outlet temperature is used as a heating control parameter. As the stack outlet temperature is a key factor influencing the starting time of the SOFC system, the heating control will be more accurate if the pre-set needed SOFC thawing time corresponding to the stack outlet temperature is used as a heating control parameter.

The invention provides a water tank heating method and unit, an electronic device and a solid oxide fuel cell (SOFC) system. Before the SOFC system is started, ice in a water tank has been heated up, so after the SOFC system is started, the heating time of the heated ice, i.e., the thawing time of the water tank, will be shortened. Further, in the ice heating process, a pre-set needed SOFC thawing time determined according to current stack outlet temperature is used as a heating control parameter. As the stack outlet temperature is a key factor influencing the starting time of the SOFC system, the heating control will be more accurate if the pre-set needed SOFC thawing time corresponding to the stack outlet temperature is used as a heating control parameter.

A perovskite-type composite oxide powder is a perovskite-type composite oxide powder represented by a general formula ABO.sub.3-δ (where δ represents an amount of deficiency of oxygen and 0≤δ<1), an element contained in an A site is La, elements contained in a B site are Co and Ni and a crystallite size determined by a Williamson-Hall method is equal to or greater than 20 nm and equal to or less than 100 nm. In this way, when the perovskite-type composite oxide powder is used as an air electrode material for a fuel cell, an air electrode in which the resistance thereof is low and the conductivity thereof is high can be obtained.

A porous body including a framework having a three-dimensional network structure, the framework having a body including nickel, cobalt, a first element and a second element as constituent elements, the cobalt having a proportion in mass of 0.2 or more and 0.8 or less relative to a total mass of the nickel and the cobalt, the first element including of at least one element selected from the group including of boron, iron and calcium, the second element including of at least one element selected from the group consisting of sodium, magnesium, aluminum, silicon, potassium, titanium, chromium, copper, zinc and tin, the first and second elements together having a proportion in mass of 5 ppm or more and 50,000 ppm or less in total relative to the body of the framework.

The purpose of the present invention is to provide fuel cell system capable of stable start-up and method for starting the fuel cell system. Fuel cell system includes SOFC, a turbocharger, oxidizing gas supply line, a control valve, oxidizing gas blow line, start-up air line for supplying the start-up air to the oxidizing gas supply line with a blower, and a control unit that, in state in which the control valve is closed and the blow valve is opened to supply the start-up air to the oxidizing gas supply line with the blower when the turbocharger is started, decreases the opening of the blow valve and, after the timing at which the opening of the blow valve starts to decrease, increases the opening of the control valve and then stops the supply of the starting air.

The purpose of the present invention is to provide fuel cell system capable of stable start-up and method for starting the fuel cell system. Fuel cell system includes SOFC, a turbocharger, oxidizing gas supply line, a control valve, oxidizing gas blow line, start-up air line for supplying the start-up air to the oxidizing gas supply line with a blower, and a control unit that, in state in which the control valve is closed and the blow valve is opened to supply the start-up air to the oxidizing gas supply line with the blower when the turbocharger is started, decreases the opening of the blow valve and, after the timing at which the opening of the blow valve starts to decrease, increases the opening of the control valve and then stops the supply of the starting air.