Systems and methods are provided for operating molten carbonate fuel cells to allow for periodic regeneration of the fuel cells while performing elevated CO.sub.2 capture. In some aspects, periodic regeneration can be achieved by shifting the location within the fuel cells where the highest density of alternative ion transport is occurring. Such a shift can result in a new location having a highest density of alternative ion transport, while the previous location can primarily transport carbonate ions. Additionally or alternately, periodic regeneration can be performed by modifying the input flows to the fuel cell and/or relaxing the operating conditions of the fuel cell to reduce or minimize the amount of alternative ion transport.

A reinforced electrolyte matrix for a molten carbonate fuel cell includes a porous ceramic matrix, a molten carbonate salt provided in the porous ceramic matrix, and at least one reinforcing structure comprised of at least one of yttrium, zirconium, cerium or oxides thereof. The reinforcing structure does not react with the molten carbonate salt. The reinforced electrolyte matrix separates a porous anode and a porous cathode in the molten carbonate fuel cell.

A fuel cell system includes an anode configured to output an anode exhaust stream comprising hydrogen, carbon dioxide, and water; and a membrane dryer configured to receive the anode exhaust stream, remove water from the anode exhaust stream, and output a membrane dryer outlet stream. The membrane dryer includes a first chamber configured to receive the anode exhaust stream; a second chamber configured to receive a purge gas; and a semi-permeable membrane separating the first chamber and the second chamber. The semi-permeable membrane is configured to allow water to diffuse therethrough, thereby removing water from the anode exhaust stream. The membrane dryer may further be configured to remove hydrogen from the anode exhaust stream.

A drive system (1) having a unipolar machine (2) and a fuel cell (3) for supplying the unipolar machine (2) with electrical energy. The fuel cell (3) can be arranged in a ring shape around a rotor shaft (5) of a rotor (4) of the unipolar machine (2). The unipolar machine (2) can be provided in a motor vehicle (600) to supply a traction torque.

An anode of a fuel cell has an anode current collector defining an inlet configured to receive fuel gas and an outlet configured to output the fuel gas, a barrier that divides an active area of the anode current collector into a first area and a second area, and a flow passage configured to allow a flow of fuel gas from the inlet through the first area and the second area to the outlet. An obstacle is located in the flow passage in an inactive area of the anode current collector and is configured to change a flow direction of the fuel gas in the flow passage from the first area to the second area to achieve intra-cell mixing of the fuel gas.

A power production system includes a fuel cell separation system configured to receive a flue gas and to produce electrical power therefrom; a flue gas polishing system positioned upstream of the fuel cell separation system and configured to remove contaminants in the flue gas; a flue gas analyzer configured to measure in real-time an amount of the contaminants in the flue gas; and a plant control system operatively coupled to the flue gas polishing system, the flue gas analyzer, and the fuel cell separation system and configured to adjust operational parameters of the flue gas polishing system.

A method of fabricating a three-dimensional (3D) architectured anode. The method comprises immersing a fabric textile in a precursor solution, the precursor solution comprising a nickel salt and gadolinium doped ceria (GDC). The nickel salt and GDC are absorbed to the fabric textile. The fabric textile comprising the absorbed nickel salt and GDC is removed from the precursor solution and calcined to form a 3D architectured anode comprising nickel oxide and GDC. Additional methods and a direct carbon fuel cell including the 3D architectured anode are also disclosed.

A reforming element for a molten carbonate fuel cell stack and corresponding methods are provided that can reduce or minimize temperature differences within the fuel cell stack when operating the fuel cell stack with enhanced CO.sub.2 utilization. The reforming element can include at least one surface with a reforming catalyst deposited on the surface. A difference between the minimum and maximum reforming catalyst density and/or activity on a first portion of the at least one surface can be 20% to 75%, with the highest catalyst densities and/or activities being in proximity to the side of the fuel cell stack corresponding to at least one of the anode inlet and the cathode inlet.

An elevated target amount of electrolyte is used to initially fill a molten carbonate fuel cell that is operated under carbon capture conditions. The increased target electrolyte fill level can be achieved in part by adding additional electrolyte to the cathode collector prior to start of operation. The increased target electrolyte fill level can provide improved fuel cell performance and lifetime when operating a molten carbonate fuel cell at high current density with a low-CO.sub.2 content cathode input stream and/or when operating a molten carbonate fuel cell at high CO.sub.2 utilization.

Disclosed here is a supported catalyst comprising a thermally stable core, wherein the thermally stable core comprises a metal oxide support and nickel disposed in the metal oxide support, wherein the metal oxide support comprises at least one base metal oxide and at least one transition metal oxide or rare earth metal oxide mixed with or dispersed in the base metal oxide. Optionally the supported catalyst can further comprise an electrolyte removing layer coating the thermally stable core and/or an electrolyte repelling layer coating the electrolyte removing layer, wherein the electrolyte removing layer comprises at least one metal oxide, and wherein the electrolyte repelling layer comprises at least one of graphite, metal carbide and metal nitride. Also disclosed is a molten carbonate fuel cell comprising the supported catalyst as a direct internal reforming catalyst.