The invention provides a lithium secondary battery including an ionic provider added to the positive electrode. The ionic provider does not involve in the electrochemical reaction of the lithium secondary battery during charging and discharging. The ionic provider can absorb thermal energy caused by the rising temperature of the lithium secondary battery to release the reactive anionic group. The reactive anionic group will react with the positive active material to reduce the reversibility of the positive active material. Also, the positive active material will become to a lower energy state from a higher energy state with lithium-ion extraction to effectively suppress the thermal runaway of the lithium secondary battery.

A non-aqueous electrolyte secondary battery including electrode body having structure in which positive electrode and negative electrode are laminated with separator and non-aqueous electrolyte. The positive electrode includes positive electrode current collector, positive electrode active material layer which is disposed on positive electrode current collector and contains first positive electrode active material, and insulating layer which is disposed along one end of positive electrode active material layer in predetermined width direction, and contains inorganic filler and second positive electrode active material. The negative electrode includes negative electrode current collector, and negative electrode active material layer which is disposed on negative electrode current collector and contains negative electrode active material, in which length in width direction is longer than length of positive electrode active material layer in width direction, and negative electrode active material layer faces positive electrode active material layer and at least part of insulating layer.

The present invention provides a nonaqueous electrolytic solution capable of improving electrochemical characteristics in the case of using an energy storage device at a high temperature and at a high voltage and further capable of inhibiting the gas generation while maintaining a capacity retention rate after storage at a high temperature and at a high voltage and also provides an energy storage device using the same. Disclosed is a nonaqueous electrolytic solution having an electrolyte salt dissolved in a nonaqueous solvent, the nonaqueous electrolytic solution containing a carboxylic acid ester compound represented by the following general formula (I). ##STR00001## In the formula, each of R.sup.1 and R.sup.2 independently represents a hydrogen atom, a —C(═O)—OR.sup.4 group, or the like, and R.sup.1 and R.sup.2 may be bonded to each other to form a ring structure. R.sup.3 represents a hydrogen atom or the like, and n represents an integer of 1 to 3. When n is 1, then L and R.sup.4 represent an alkyl group having 1 to 6 carbon atoms or the like; and when n is 2 or 3, then L represents an n-valent connecting group, X represents a —C(═O)— group, an —S(═O)— group, an —S(═O).sub.2— group, an —S(═O).sub.2—R.sup.5—S(═O).sub.2— group or a CR.sup.6R.sup.7 group, R.sup.5 represents an alkylene group having 1 to 4 carbon atoms, and each of R.sup.6 and R.sup.7 represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms.

A power storage module including: a stacked body that includes electrodes stacked along a first direction; a sealing body that includes a first sealing portion joined to an edge portion of each of the electrodes, forms an inner space between the electrodes adjacent to each other, and seals the inner space; and an electrolytic solution that is stored in the inner space and includes an alkali solution. The electrodes include bipolar electrodes, and a negative terminal electrode. The power storage module includes surplus spaces different from the inner space on a route of an alkali creep phenomenon in which the electrolytic solution reaches the outside from the inner space through the negative terminal electrode.

Cathode active materials are provided. The cathode active material can include a plurality of cathode active compound particles. A coating is disposed over each of the cathode active compound particles. The coating can include at least one of ZrO.sub.2, La.sub.2O.sub.3, a mixture of Al.sub.2O.sub.3 and ZrO.sub.2 or a mixture of Al.sub.2O.sub.3 and La.sub.2O.sub.3. The battery cells that include the cathode active material are also provided.

A strip-shaped electrode sheet includes an electrode foil including a strip-shaped foil exposed portion in which the electrode foil is exposed, a strip-shaped active material layer extending in a longitudinal direction, and a strip-shaped insulator layer containing insulating resin and formed on an insulator-layer support portion along a one-side layer edge portion of the active material layer and between the foil exposed portion of the electrode foil and an active-material-layer support portion. The insulator layer is located lower than a top face of the active material layer toward the electrode foil and includes a slant coating portion covering at least a lower portion of a one-side slant portion of the active material layer and a foil coating portion extending from the slant coating portion in a width-direction one side and covering the insulator-layer support portion of the electrode foil.

This application provides a lithium-ion battery and an apparatus. The lithium-ion battery includes an electrode assembly and an electrolyte. The electrode assembly includes a positive electrode plate, a negative electrode plate, and a separator. A positive active material of the positive electrode plate includes Li.sub.x1Co.sub.y1M.sub.1-y1O.sub.2-z1Q.sub.z1, where 0.5≤x1≤1.2, 0.8≤y1≤1.0, 0≤z1≤0.1, M is selected from one or more of Al, Ti, Zr, Y, and Mg, and Q is selected from one or more of F, Cl, and S. The electrolyte contains an additive A that is a polynitrile six-membered nitrogen-heterocyclic compound with a relatively low oxidation potential. The lithium-ion battery has superb cycle performance and storage performance, especially under high-temperature and high-voltage conditions.

A composite membrane with nanostructured inorganic and organic phases is applied as an ion-selective layer to prove processability, prevent dendrite shorting, and increase power output of lithium-metal anodes through better Li-ion conductivity. Nanoconfinement, as opposed to macroscale confinement, is known to dramatically alter the properties of bulk materials. Control over a ceramic's size, shape, and properties is achieved with polymer templates. This is a new composition of matter and unique approach to composite membrane design.

An additive for a non-aqueous electrolyte solution that can suppress the initial gas generation amount when used in a non-aqueous electrolyte solution battery. The additive for a non-aqueous electrolyte solution is represented by any one of formulae [1] to [4]: ##STR00001## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, X.sup.1, X.sup.2 and Y are as defined in the specification.

A lithium secondary battery, wherein there is a pre-lithiated negative electrode such that a total irreversible capacity of a positive electrode is greater than a total irreversible capacity of the negative electrode while satisfying 150< (negative electrode discharge capacity/lithium secondary battery discharge capacity)×100<300, and a relative potential of the negative electrode with respect to lithium metal in an operating voltage range of the lithium secondary battery is in a range of −0.1 V to 0.7 V. Such a lithium secondary battery is capable of maintaining a capacity retention of 60% or more even after 500 cycles or more while achieving an energy density per volume of 800 Wh/L or more.