The invention relates to electrochemical current sources, more particularly to metal-air current sources, and even more particularly to lithium-air current sources and their electrodes. A cathode comprises a base made of a porous electrically conducting material that is permeable to molecular oxygen, the working surface of which has a copolymer applied thereto, which is produced by the copolymerization of a monomeric transition metal coordination complex having a Schiff base and a thiophene group monomer. The monomeric transition metal coordination complex having a Schiff base can be, for example, a compound of the [M(R,R′-Salen)], [M(R,R′-Saltmen)] or [M(R,R′-Salphen)] type, and the thiophene group monomer can be a compound selected from a thiophene group consisting of 3-alkylthiophenes, 3,4-dialkylthiophenes, 3,4-ethylenedioxythiophene or combinations thereof. A current source comprises the described cathode and an anode made from an active metal, in particular lithium, wherein the cathode and the anode are separated by an electrolyte containing ions of the metal from which the anode is made. It has been established that in this system, the copolymer exhibits the properties of an effective catalyst. The technical result is an increase in the specific energy, specific power and number of charge and discharge cycles of a metal-air current source.

A metal-air battery from which leakage of an electrolytic solution is reduced is provided. The metal-air battery includes: a positive electrode including: a current collector; and a catalyst layer formed on the current collector and capable of reducing oxygen; a negative electrode disposed to face the positive electrode; an exterior body housing a stacked portion including the positive electrode and the negative electrode, and having an opening formed to open to the positive electrode; an electrolyte disposed inside the exterior body; and a water-repellent film covering the opening, including a joint portion joined to the exterior body, and transparent to oxygen. The catalyst layer includes a portion positioned between the joint portion and the current collector.

A metal-air battery from which leakage of an electrolytic solution is reduced is provided. The metal-air battery includes: a positive electrode including: a current collector; and a catalyst layer formed on the current collector and capable of reducing oxygen; a negative electrode disposed to face the positive electrode; an exterior body housing a stacked portion including the positive electrode and the negative electrode, and having an opening formed to open to the positive electrode; an electrolyte disposed inside the exterior body; and a water-repellent film covering the opening, including a joint portion joined to the exterior body, and transparent to oxygen. The catalyst layer includes a portion positioned between the joint portion and the current collector.

A process of producing a cathode electrocatalyst for metal-air batteries includes providing a carbon source suspension, a metal source solution, and a nitrogen source solution, subjecting the carbon source suspension and the metal source solution to a low-temperature hydrothermal reaction, subjecting a first precursor-containing product thus formed and the nitrogen source solution to a high-temperature hydrothermal reaction, and subjecting a second precursor thus formed to a heating treatment under a protective atmosphere. A cathode electrocatalyst produced by the process is also disclosed.

A process of producing a cathode electrocatalyst for metal-air batteries includes providing a carbon source suspension, a metal source solution, and a nitrogen source solution, subjecting the carbon source suspension and the metal source solution to a low-temperature hydrothermal reaction, subjecting a first precursor-containing product thus formed and the nitrogen source solution to a high-temperature hydrothermal reaction, and subjecting a second precursor thus formed to a heating treatment under a protective atmosphere. A cathode electrocatalyst produced by the process is also disclosed.

An aircraft has an aircraft propulsor and/or an aircraft propulsor drive. The aircraft propulsor and/or an aircraft propulsor drive acts as a waste heat source. The aircraft has a metal-air fuel cell. The aircraft has a waste heat transfer system configured to thermally couple the metal-air fuel cell and a waste heat source. The aircraft includes a control system configured to operate the waste heat transfer system to selectively transfer waste heat from the waste heat source to the metal-air fuel cell.

Multi-phase electrochemical cells and related systems and methods are generally described.

Multi-phase electrochemical cells and related systems and methods are generally described.

An electrochemical system, the system including an aqueous electrolyte, at least one chelating agent configured to bind to at least one detrimental ionic species, and a particulate precipitation site. A method of forming an electrochemical system including creating a housing with an interior volume, placing at least one electrode within the interior volume, adding at least one chelating agent configured to bind to at least one detrimental ionic species into the interior volume, and adding a particulate precipitation site to the interior volume.

Disclosed are a metal/carbon-dioxide battery and a hydrogen production and carbon dioxide storage system including the same.