In a golf ball having a core, envelope layer, intermediate layer and cover, the (core diameter)/(ball diameter) value falls within a particular range, the core has a specific hardness profile, and the Shore C hardness relationships among the core center and surface hardnesses and the surface hardnesses of the envelope layer-encased sphere, intermediate layer-encased sphere and ball satisfy the following conditions:
core surface hardness<surface hardness of envelope layer-encased sphere<surface hardness of intermediate layer-encased sphere>ball surface hardness,  (1)
(surface hardness of envelope layer-encased sphere)−(core center hardness)≥28.  (2)
Also, the envelope layer, intermediate layer and cover have respective thicknesses which satisfy the condition:
cover thickness<intermediate layer thickness  (3)
cover thickness<envelope layer thickness  (4)
envelope layer thickness≥0.8 mm.  (5)
This ball enables mid-level and skilled amateur golfers to achieve superior distances on driver shots and on iron shots, and moreover has a soft yet good feel at impact.

A golf ball includes a core having an outer surface and a geometric center; an inner cover layer, and an outer cover layer. The inner cover layer includes an ionomeric material and has a material hardness of about 60 Shore D or greater. The outer cover layer is formed from a polyurea or polyurethane and has a material hardness of about 60 Shore M or greater. The outer surface of the core has a hardness of about 68 to 92 Shore C. The geometric center of the core has a hardness of about 45 to 85 Shore C. The core outer surface hardness is greater than the geometric center hardness by about 5 to 21 Shore C to define a positive hardness gradient. The core also has a volume weighted average hardness, H.sub.V, of about 70 to 80, where

[00001]${\stackrel{\_}{H}}_V=\frac{I_V}{V_c}.$

A golf ball of one aspect of the present invention includes a spherical core, one or more cover members to cover the core, and a coating layer to coat a cover member configuring an outermost layer of the one or more cover members. A plurality of dimples is formed in the cover member. Shore-D hardness of the cover member is equal to or larger than 50. A 10% modulus of the coating layer is equal to or smaller than 160 kgf/cm.sup.2. Roughness is produced on a surface of the coating layer after applying a coating material over the cover member of the outermost layer A maximum height Rz of the coating layer is equal to or larger than 3 μm.

Methods for coatings for golf balls, particularly golf balls having thermoplastic polyurethane covers, and the resulting finished balls are provided. The coating is preferably a topcoat comprising a polyurethane composition containing optical brighteners. The topcoat composition preferably comprises a low concentration of optical brighteners. For example, the concentration of optical brightener can be in the range of 0.01 to about 0.20 weight %. The optical brighteners provide the desired brightness to the golf ball without sacrificing color stability. Multi-piece golf balls having inner cores, outer cores, inner covers, and intermediate layers can be made. The finished ball with the topcoat has many advantageous physical and playing performance properties.

An object of the present invention is to provide a golf ball showing improved controllability on approach shots for less than 40 yards, in particular, on approach shots around the green (about 10 yards to 20 yards) and improved controllability on approach shots from the rough, and showing excellent shot feeling. The present invention provides a golf ball comprising a golf ball body and a paint film covering the golf ball body, wherein a loss tangent tan δ has a peak temperature of 50° C. or less and a peak height of less than 0.8, obtained by measuring dynamic viscoelasticity of the paint film under the following conditions: <Measuring conditions> Measuring mode: tensile mode Measuring temperature range: from −100° C. to 150° C. Temperature rising rate: 4° C./min Oscillation frequency: 10 Hz Measuring strain: 0.1%.

An object of the present invention is to provide a golf ball striking a good balance between flight distance on driver shots and spin rate on approach shots, and excellent in stain resistance and shot feeling. The present invention provides a golf ball comprising a paint film, wherein a base resin of the paint film contains a polyurethane obtained by a reaction between a polyisocyanate composition and a polyol composition containing a urethane polyol having a polyether diol with a number average molecular weight in a range from 800 to 3,000 as a constituent component, and the following requirements are satisfied:
Mp≦200×X−75
Mp≦100
Minm−Moum>40
Moum−Mc<5
Tinm≧Toum>Tc>Tp
(Tinm×Minm)/(Toum×Moum)>2.0
(Toum×Moum)/(Tc×Mc)<3.0
(Tc×Mc)/(Tp×Mp)>10.0
[where Mp, Minm, Moum, and Mc represent a 10% elastic modulus (kgf/cm.sup.2) of the paint film, inner intermediate layer, outer intermediate layer and cover, respectively; Tp, Tinm, Toum, and Tc represent a thicknesses (mm) of the paint film, inner intermediate layer, outer intermediate layer and cover, respectively; and X represents a molar ratio (NCO/OH) of a NCO group in the polyisocyanate composition to a OH group in the polyol composition.].

Methods for coatings for golf balls, particularly golf balls having thermoplastic polyurethane covers, and the resulting finished balls are provided. The coating is preferably a topcoat comprising a polyurethane composition containing optical brighteners. The topcoat composition preferably comprises a low concentration of optical brighteners. For example, the concentration of optical brightener can be in the range of 0.01 to about 0.20 weight %. The optical brighteners provide the desired brightness to the golf ball without sacrificing color stability. Multi-piece golf balls having inner cores, outer cores, inner covers, and intermediate layers can be made. The finished ball with the topcoat has many advantageous physical and playing performance properties.

In a multi-piece solid golf ball having a core, an intermediate layer encasing the core and a cover which encases the intermediate layer and has numerous dimples on an outside surface thereof, the intermediate layer is formed of a resin material, the cover is formed of a urethane resin material, the core has a diameter of at least 38.0 mm, the core has a deflection when compressed under a final load of 1,275 N (130 kgf) from an initial load of 98 N (10 kgf) of at least 3.9 mm, the core has a center and a surface such that the value obtained by subtracting the JIS-C hardness at the core center from the JIS-C hardness at the core surface is at least 15, the sphere obtained by encasing the core with the intermediate layer (intermediate layer-encased sphere) has a surface hardness on the Shore D hardness scale of at least 69, the ball has a surface hardness on the Shore D hardness scale of 62 or less, and the (intermediate layer thickness)/(core diameter) value is from 0.025 to 0.043, the (cover thickness)/(core diameter) value is from 0.014 to 0.027.

Golf balls having covers with decorative-effect coatings are provided. The golf balls are fashionable and decorative with unique appearances. In one embodiment, a golf ball comprising a core having at least one layer and cover having at least one layer is provided. The outer cover surface can have surface textured dimples and a decorative-effect first coating can be applied to this outer surface. A transparent second coating can be applied over the decorative-effect coating. In another embodiment, a semi-transparent metallic first coating overlies the outer cover surface and a decorative-effect second coating overlies the metallic coating.

In a multi-piece solid golf ball having a core formed of a rubber composition, an intermediate layer formed of a polyurethane material and a cover, the ball satisfies the following condition: surface hardness of ball≤surface hardness of intermediate layer-encased sphere. When the ball is struck with a driver at a head speed of 40 m/s, the sum of the time t1 required from contact initiation between the driver and ball for deformation of the ball to reach a maximum value and the time t2 required from the state of maximum ball deformation for the ball and driver clubface to separate is at least 685 microseconds, and the ratio t2/t1 is at least 1.35, and the core has a specific hardness profile. This ball has an excellent flight performance when hit by low or moderate head-speed golfers, is receptive to spin on approach shots and has a good, soft feel at impact.