In a golf ball having a core, envelope layer, intermediate layer and cover, the (core diameter)/(ball diameter) value falls within a particular range, the core has a specific hardness profile, and the Shore C hardness relationships among the core center and surface hardnesses and the surface hardnesses of the envelope layer-encased sphere, intermediate layer-encased sphere and ball satisfy the following conditions:
core surface hardness<surface hardness of envelope layer-encased sphere<surface hardness of intermediate layer-encased sphere>ball surface hardness,  (1)
(surface hardness of envelope layer-encased sphere)−(core center hardness)≥28.  (2) Also, the envelope layer, intermediate layer and cover have respective thicknesses which satisfy the condition:
cover thickness<intermediate layer thickness envelope layer thickness.  (3) This ball enables mid-level and skilled amateur golfers to achieve superior distances on driver shots and on iron shots, and moreover has a soft yet good feel at impact.

An object of the present invention is to provide a novel golf ball having excellent spin performance on approach shots. The present invention provides a golf ball comprising a golf ball body, and a paint film formed on a surface of the golf ball body and composed of at least one layer, wherein a base resin constituting an outermost layer of the paint film includes a polyurethane, and the polyurethane has a loss elastic modulus (E″) of 0.2×10.sup.8 Pa or more at −50° C. and a loss tangent (tan δ) having a peak temperature of 0° C. or less, obtained by measuring dynamic viscoelasticity of the polyurethane under specific conditions.

Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. Polyurethane primer coatings and polyurethane top-coatings are applied to the thermoplastic polyurethane cover. Different coating methods can be used. Isocyanate-rich and polyol-rich polyurethane coatings can be applied. In one embodiment, the golf ball can be treated with a multi-functional isocyanate prior to applying the coatings. The polyurethane cover composition and surface coatings can further include catalysts, ultraviolet (UV)—light stabilizers, and other additives. Heat is used to cure the coatings. The coating methods have many benefits and the finished balls have good physical properties.

A golf ball has a plurality of dimples 12 and a land 14 on a surface thereof. The golf ball further has a large number of minute projections 18 formed on surfaces of the dimples 12 and the land 14. The surface of the golf ball has an arithmetic average height Sa of not less than 0.5 μm and not greater than 30 μm. An average value Hav of heights H of the minute projections 18 is not less than 0.5 μm and not greater than 50 μm. A ratio Pp of a sum of areas of all the minute projections 18 to a surface area of a phantom sphere of the golf ball is not less than 7%. An average value Dav of diameters D of the minute projections 18 is not less than 5 μm and not greater than 50 μm.

In a golf ball comprising a core, a cover layer, an intermediate layer between the core and the cover layer, the cover layer is formed of a resin material composed primarily of polyurethane or polyurea, a sphere obtained by encasing the core with the intermediate layer (intermediate layer-encased sphere) has a lightness (Li value) in the L*a*b* color space of at least 25 on its surface, and the cover layer has a visible light transmittance of at least 0.6%. The golf ball has a surface with a distinctive aesthetic appearance and retains both a good spin performance and a good scuff resistance, making it useful as a ball for professional and skilled amateur golfers.

In a multi-piece solid golf ball having a core, an intermediate layer encasing the core and a cover which encases the intermediate layer and has numerous dimples on an outside surface thereof, the core is formed of a rubber composition including the specific ingredient compounding ingredients, the intermediate layer is formed of a resin material, the cover is formed of a urethane resin material, the core has a diameter of at least 38.0 mm, the core has a deflection when compressed under a final load of 1,275 N (130 kgf) from an initial load of 98 N (10 kgf) of at least 3.9 mm, the sphere obtained by encasing the core with the intermediate layer (intermediate layer-encased sphere) has a surface hardness on the Shore D hardness scale of at least 69, the ball has a surface hardness on the Shore D hardness scale of 62 or less, and the (intermediate layer thickness)/(core diameter) value is from 0.025 to 0.043, the (cover thickness)/(core diameter) value is from 0.014 to 0.027.

An object of the present invention is to provide a golf ball having excellent spin performance on approach shots under a wet condition and excellent spin performance on approach shots under a condition that there is grass between the golf ball and the club face. The present invention provides a golf ball comprising a golf ball body and a paint film composed of at least one layer and formed on a surface of the golf ball body, wherein an outermost layer of the paint film located at the outermost layer of the golf ball contains a base resin and a porous filler, the base resin contains a polyurethane obtained by a reaction between a polyisocyanate composition and a polyol composition, and the porous filler contains SiO.sub.2 in an amount of 50 mass % or more as a constituent component.

An object of the present invention is to provide a golf ball having excellent spin performance on approach shots under a wet condition and excellent spin performance on approach shots under a condition that there is grass between the golf ball and the dub face. The present invention provides a golf ball comprising a golf ball body and a paint film composed of at least one layer and formed on a surface of the golf ball body, wherein an outermost layer of the paint film located at the outermost layer of the golf ball contains a base resin and a porous filler, the base resin contains a polyurethane obtained by a reaction between (A) a polyisocyanate composition and (B) a polyol composition containing a urethane polyol as a polyol component, the porous filler contains SiO.sub.2 in an amount of 50 mass % or more as a constituent component, and a loss tangent (tan δ) of the outermost layer of the paint film measured with a dynamic viscoelasticity measuring apparatus under following conditions has a peak temperature in a range of from −43° C. to 40° C.

An object of the present invention is to provide a golf ball having excellent spin performance on approach shots under a wet condition and excellent spin performance on approach shots under a condition that there is grass between the golf ball and the club face. The present invention provides a golf ball comprising a golf ball body and a paint film composed of at least one layer and formed on a surface of the golf ball body, wherein an outermost layer of the paint film located at the outermost layer of the golf ball contains a base resin and a porous filler, the base resin contains a polyurethane obtained by a reaction between a polyisocyanate composition and a polyol composition, and the porous filler contains SiO.sub.2 in an amount of 50 mass % or more as a constituent component.

An object of the present invention is to provide a golf ball having excellent spin performance on approach shots under a wet condition and excellent spin performance on approach shots under a condition that there is grass between the golf ball and the club face. The present invention provides a golf ball comprising a golf ball body and a paint film composed of at least one layer and formed on a surface of the golf ball body, wherein an outermost layer of the paint film located at the outermost layer of the golf ball contains a base resin and a porous filer, the base resin contains a polyurethane obtained by a reaction between (A) a polyisocyanate composition and (B) a polyol composition containing a urethane polyol as a polyol component, the porous filler contains SiO.sub.2 in an amount of 50 mass % or more as a constituent component, and a loss tangent (tan δ) of the outermost layer of the paint film measured with a dynamic viscoelasticity measuring apparatus under following conditions has a peak temperature in a range of from −40° C. to 40° C.