Ir/Pt metal complexes, devices containing the Ir/Pt metal complexes, and methods of making such devices are described. The Ir/Pt metal complex includes a first Ir moiety and a first Pt moiety. The first Ir moiety can be an Ir(III) six-coordinated structure. The first Pt moiety can be a Pt(II) four-coordinated tetradentate structure. The devices can have layers that include the Ir/Pt metal complexes. The layers containing the Ir/Pt metal complexes can be made by a solution process.

The invention provides compositions comprising copper(I) pyrazolate dimer compounds for use in OLEDs applications. The inventive compositions can be used to generate visible light colors or a color blend in electronic devices.

##STR00001##

Compounds, including metal borate compounds, and electronic semiconducting devices including one or more of the compounds. Compounds may be used in a hole transport layer of the electronic semiconducting devices. Display devices, which may include a plurality of OLED pixels. The OLED pixels may include one or more compounds, including metal borate compounds.

The present invention relates to an electronic device comprising between a first electrode and a second electrode at least one first hole transport layer, wherein the first hole transport layer comprises (i) at least one first hole transport matrix compound consisting of covalently bound atoms and (ii) at least one electrical p-dopant selected from metal sate and from electrically neutral metal complexes comprising a metal cation and a at least one anion and/or at least one anionic ligand consisting of at least 4 covalently bound atoms, wherein the metal cation of the electrical p-dopant is selected from alkali metals; alkaline earth metals, Pb, Me, Fe, Co, Ni, Zn, Cd; rare earth metals in oxidation state (II) or (III); Al, Ga, In; and from Sn, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo and W in oxidation state (TV) or less; provided that a) p-dopants comprising anion or anionic ligand having generic formula (Ia) or (Ib) wherein A.sup.1, A.sup.2, A.sup.3 and A.sup.4 are independently selected from CO, SO.sub.2 or POR.sup.1; R.sup.1=electron withdrawing group selected from the group comprising halide, nitrile, halogenated or perhalogenated C.sub.1 to C.sub.20 alkyl, halogenated or perhalogenated C.sub.6 to C.sub.20 aryl, or halogenated or perhalogenated heteroaryl with 5 to 20 ring-forming atoms; B.sup.1, B.sup.2, B.sup.3 and B.sup.4 are same or independently selected from substituted or unsubstituted C.sub.1 to C.sub.20 alkyl, substituted or unsubstituted C.sub.1 to C.sub.20 heteroalkyl, substituted or unsubstituted C.sub.6 to C.sub.20 aryl, substituted or unsubstituted C.sub.5 to C.sub.20 heteroaryl, or B.sup.1 and B.sup.2 form a ring; and b) p-dopants consisting of Li cation and an anion selected from perchlorate and tetrafluoroborate are excluded, and the first hole transport layer comprises a sublayer, wherein the electrical dopant is comprised in an amount, by weight and/or by volume, exceeding the total amount of other components which may additionally be comprised in the sublayer, and a method for preparing the same. ##STR00001##

The present invention relates to an organic electronic device, comprising a first electrode, a second electrode, and a substantially organic layer comprising a compound according to formula (I) between the first and the second electrode: ##STR00001##
wherein M is a metal ion, each of A.sup.1-A.sup.4 is independently selected from H, substituted or unsubstituted C6-C20 aryl and substituted or unsubstituted C2-C20 heteroaryl and n is valency of the metal ion.

Disclosed herein are precursor compounds, composite electrodes comprising the same, and methods of making and use thereof.

The invention relates to a phthalocyanine compound, which has a structure as represented by Formula I, wherein A represents a transition metal or a rare earth metal; R1 represents a phenyl group, a naphthyl group, or a C.sub.4-C.sub.16 n-alkyl group. The aromatic phthalocyanine compound having the structure of Formula I provided in the invention contains a transition metal or a rare earth metal, and introduces a peripheral substituent into a linearly extended 7c-conjugated system. It is relatively stabler at 400° C. or less and will be easily evaporated in vacuum to form a uniform thin film, and has good thermal stability, high chemical stability, and high mobility. The organic semiconductor device has the features of relatively fast on-off speed, relatively high on-off ratio, and strong reliability.

##STR00001##

An organometallic compound represented by Formula 1: ##STR00001## wherein, in Formula 1, groups and variables are the same as described in the specification.

Hole transporting material obtained through a process comprising: reacting at least one heteropoly acid containing at least one transition metal belonging to group 5 or 6 of the Periodic Table of the Elements; with an equivalent amount of at least one salt or one complex of a transition metal belonging to group 5 or 6 of the Periodic Table of the Elements with an organic anion, or with an organic ligand;
in the presence of at least one organic solvent selected from alcohols, ketones, esters. Said hole transporting material can be advantageously used in the construction of photovoltaic devices (or solar devices) such as, for example, photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), either on a rigid support, or on a flexible support. Furthermore, said hole transporting material can be advantageously used in the construction of Organic Light Emitting Diodes (OLEDs), or of Organic Field Effect Transistors (OFETs). In particular, said hole transporting material can be advantageously used in the construction of a polymer photovoltaic cell (or solar cell) with an inverted structure.

The present invention relates to a display device comprising—a plurality of OLED pixels comprising at least two OLED pixels, the OLED pixels comprising an anode, a cathode, and a stack of organic layers, wherein the stack of organic layers—is arranged between and in contact with the cathode and the anode, and—comprises a first electron transport layer, a first hole transport layer, and a first light emitting layer provided between the first hole transport layer and the first electron transport layer, and—a driving circuit configured to separately driving the pixels of the plurality of OLED pixels, wherein, for the plurality of OLED pixels, the first hole transport layer is provided in the stack of organic layers as a common hole transport layer shared by the plurality of OLED pixels, and the first hole transport layer comprises (i) at least one first hole transport matrix compound consisting of covalently bound atoms and (ii) at least one electrical p-dopant selected from metal salts and from electrically neutral metal complexes comprising a metal cation and at least one anion and/or at least one anionic ligand consisting of at least 4 covalently bound atoms, wherein the metal cation of the electrical p-dopant is selected from alkali metals; alkaline earth metals, Pb, Mn, Fe, Co, Ni, Zn, Cd; rare earth metals in oxidation state (II) or (III); Al, Ga, In; and from Sn, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo and W in oxidation state (IV) or less, a method for preparing the display device and a chemical compound for use therein.