A strip cast alloy containing Nd in excess of the stoichiometry of Nd.sub.2Fe.sub.14B is subjected to HDDR treatment and diffusion treatment, yielding microcrystalline alloy powder in which major phase crystal grains with a size of 0.1-1 μm are surrounded by Nd-rich grain boundary phase with a width of 2-10 nm. The powder is finely pulverized, compacted, and sintered, yielding a sintered magnet having a high coercivity.

A bond magnet includes filaments bonded with each other to form a shape of the bond magnet. Each of the filaments is a filamentous member including a resin material and magnetic powder dispersed in the resin material, and has magnetic anisotropy for high degree of freedom of magnetic flux direction and high surface magnetic flux density on a working surface.

A method for preparing a Nd—Fe—B-based sintered magnet. The method includes: 1) providing a master alloy and an auxiliary alloy, the master alloy being a Nd—Fe—B alloy ingot or cast strip, the auxiliary alloy being a heavy rare earth alloy; 2) breaking up the master alloy using a hydrogen decrepitation process to yield a crude powder, conducting hydrogen absorption treatment on the auxiliary alloy and breaking up the hydrogenated auxiliary alloy to yield hydride particles; 3) uniformly mixing and stirring the crude powder of the master alloy and the hydride particles of the auxiliary alloy to yield a mixture; 4) milling the mixture obtained in step 3) to yield powders; 5) uniformly stirring the powders obtained in step 4) and conducting orientation forming treatment on the powders, to yield a raw body of a Nd—Fe—B based magnet; and 6) sintering the raw body of the Nd—Fe—B based magnet.

This disclosure is directed to sintered bodies comprising grains and a grain boundary composition, wherein: (a) the grains comprise a composition substantially represented by a formula G.sub.2M.sub.14B, where G is Nd, Dy, Pr, Tb, or a combination thereof, and M is Co, Fe, Ni, or a combination thereof, wherein the grains are optionally doped with one or more rare earth elements; and (b) the grain boundary composition is an alloy composition substantially represented by the formula: Nd.sub.8.5-12.5Dy.sub.35-45Co.sub.32-41Cu.sub.3-6.5Fe.sub.1.5-5, wherein the subscript values are atom percent relative to the total composition of the the alloy composition. Corresponding populations of particles are also disclosed

The present invention discloses a short process preparation technology of sintered NdFeB magnets from the NdFeB sludge, which relates to a field of recycle technology of NdFeB sludge. The present invention comprises the following steps: water bath distillation of organics in sludge, ultrasonic cleaning, calcium reduction and diffusion, ultrasonic rinsing in a magnetic field and drying, powders mixing and sintering. NdFeB sludge as raw materials was directly prepared from recycled sintered magnets with high magnetic properties. Most of the organics in the sludge could be removed by a vacuum distillation process with stepwise heating. The ultrasonic rinsing process in a magnetic field could effectively remove the remaining organics. The recycled sintered magnets exhibited good maximum energy product [(BH).sub.max] of 35.26 MGOe. The present invention has important features, such as the short processing time, efficient environmental protection, high recycling rate and effective utilization rate of rare earth metals.

Disclosed herein is a method for manufacturing an R-T-B permanent magnet and the magnet made with the method. The method may include preparation of strip pieces by melting and casting, preparing coarse powder by hydrogen decrepitation of the strip pieces; milling the powder into fine powder; pressing the fine powder is pressed to form a compact, pre-sintering the compact in vacuum or inert gas, machining the pre-sintered block to a desired shape; and dispersing the heavy rare earth compound powder into an organic solvent to prepare a slurry and a second sintering step.

A sintered ferrite magnet comprising (a) a ferrite phase having a hexagonal M-type magnetoplumbite structure comprising Ca, an element R which is at least one of rare earth elements and indispensably includes La, an element A which is Ba and/or Sr, Fe, and Co as indispensable elements, the composition of metal elements of Ca, R, A, Fe and Co being represented by the general formula of Ca.sub.1-x-yR.sub.xA.sub.yFe.sub.2n-zCo.sub.z, wherein the atomic ratios (1-x-y), x, y and z of these elements and the molar ratio n meet the relations of 0.3≦(1-x-y)≦0.65, 0.2≦x≦0.65, 0≦y≦0.2, 0.03≦z≦0.65, and 4≦n≦7, and (b) a grain boundary phase indispensably containing Si, the amount of Si being more than 1% by mass and 1.8% or less by mass (calculated as SiO.sub.2) based on the entire sintered ferrite magnet, and its production method.

In an embodiment, a permanent magnet includes a composition represented by a composition formula: R(Fe.sub.pM.sub.qCu.sub.r(Co.sub.1-sA.sub.s).sub.1-p-q-r).sub.z, where, R is at least one element selected from rare earth elements, M is at least one element selected from Ti, Zr, and Hf, A is at least one element selected from Ni, V, Cr, Mn, Al, Si, Ga, Nb, Ta, and W, 0.05≦p≦0.6, 0.005≦q≦0.1, 0.01≦r≦0.15, 0≦s≦0.2, and 4≦z≦9, and a two-phase structure of a Th.sub.2Zn.sub.17 crystal phase and a copper-rich phase. In a cross-section of the permanent magnet containing a crystal c axis of the Th.sub.2Zn.sub.17 crystal phase, an average distance between the copper-rich phases is 120 nm or less.

A type of sintered Nd—Fe—B permanent magnet with high corrosion resistance is produced by dual alloy method. The method comprises the following steps: preparing the powders of master phase alloy and intergranular phase alloy respectively, mixing the powders, compacting the powders in magnetic field, sintering the compacted body at 1050˜1125° C., and annealing at 920-1020° C. and 500-650° C. successively.

There is provided a compression-bonded magnet with a case, which can realize high magnetic properties, high corrosion resistance and high durability strength even at low cost. The compression-bonded magnet with a case is a compression-bonded magnet with a case 1, comprising: a compression-bonded magnet 2 comprising a rare earth magnet powder such as an isotropic Nd—Fe—B magnet powder and a resin binder of a thermosetting resin; a case 3 for inserting the compression-bonded magnet 2; and a sealing member 4, wherein the compression-bonded magnet 2 is formed by compression-molding a mixture comprising the rare earth magnet powder and the resin binder into a green compact and curing the resin binder contained in the green compact, the rare earth magnet powder is contained in a large amount with respect to the entire compression-bonded magnet (for example, in a volume ratio of 85% to 90%), the sealing member 4 is fixed at an insertion opening part 3a of the case 3, and the compression-bonded magnet 2 is hermetically sealed by the sealing member 4 and the case 3.