An electrochemical cell includes solid-state, printable anode layer, cathode layer and non-aqueous gel electrolyte layer coupled to the anode layer and cathode layer. The electrolyte layer provides physical separation between the anode layer and the cathode layer, and comprises a composition configured to provide ionic communication between the anode layer and cathode layer by facilitating transmission of multivalent ions between the anode layer and the cathode layer.

An electrolytic capacitor includes a capacitor element and electrolytic solution. The capacitor element includes an anode body with an oxide film, and a solid electrolyte contacting the oxide film. The electrolytic solution contains a solvent and a solute. The solvent contains at least one selected from the group consisting of a lactone compound, a glycol compound, and a sulfone compound. The solute includes a first acid component and a base component. The first acid component includes at least one of a benzenedicarboxylic acid and a derivative of the benzenedicarboxylic acid. The base component includes at least one of an amine and an amidine. A concentration of the solute in the electrolytic solution ranges from 15% by mass to 40% by mass, inclusive. A ratio (V/Vw) of a formation voltage V of the oxide film to a rated voltage Vw of the electrolytic capacitor is less than or equal to 1.7.

An electrolytic capacitor includes a capacitor element and electrolytic solution. The capacitor element includes an anode body with an oxide film, and a solid electrolyte contacting the oxide film. The electrolytic solution contains a solvent and a solute. The solvent contains at least one selected from the group consisting of a lactone compound, a glycol compound, and a sulfone compound. The solute includes a first acid component and a base component. The first acid component includes at least one of a benzenedicarboxylic acid and a derivative of the benzenedicarboxylic acid. The base component includes at least one of an amine and an amidine. A concentration of the solute in the electrolytic solution ranges from 15% by mass to 40% by mass, inclusive. A ratio (V/Vw) of a formation voltage V of the oxide film to a rated voltage Vw of the electrolytic capacitor is less than or equal to 1.7.

An example includes a capacitor case sealed to retain electrolyte, at least one anode disposed in the capacitor case, the at least one anode comprising a sintered portion disposed on a substrate, an anode conductor coupled to the substrate in electrical communication with the sintered portion, the anode conductor sealingly extending through the capacitor case to an anode terminal disposed on the exterior of the capacitor case with the anode terminal in electrical communication with the sintered portion, a second electrode disposed in the capacitor case, a separator disposed between the second electrode and the anode and a second electrode terminal disposed on an exterior of the capacitor case and in electrical communication with the second electrode, with the anode terminal and the second electrode terminal electrically isolated from one another.

An example includes a capacitor case sealed to retain electrolyte, at least one anode disposed in the capacitor case, the at least one anode comprising a sintered portion disposed on a substrate, an anode conductor coupled to the substrate in electrical communication with the sintered portion, the anode conductor sealingly extending through the capacitor case to an anode terminal disposed on the exterior of the capacitor case with the anode terminal in electrical communication with the sintered portion, a second electrode disposed in the capacitor case, a separator disposed between the second electrode and the anode and a second electrode terminal disposed on an exterior of the capacitor case and in electrical communication with the second electrode, with the anode terminal and the second electrode terminal electrically isolated from one another.

An issue of this invention is to enhance reliability of an electrolytic capacitor in a manner that an electrolytic solution does not leak from a sealed part while a high initial electrical conductivity is maintained even at a higher environment temperature or in a high-humidity condition. An electrolytic solution for aluminum electrolytic capacitor is described, containing a solvent (A) and an electrolyte (D) represented by general formula (1) below. In formula (1), R.sup.1 to R.sup.3 each represent alkyl having 1 to 3 carbon atoms, R.sup.4 to R.sup.7 each represent alkyl having 1 to 3 carbon atoms or a hydrogen atom, and X.sup.− represents an anion of an acid (C). ##STR00001##

An issue of this invention is to enhance reliability of an electrolytic capacitor in a manner that an electrolytic solution does not leak from a sealed part while a high initial electrical conductivity is maintained even at a higher environment temperature or in a high-humidity condition. An electrolytic solution for aluminum electrolytic capacitor is described, containing a solvent (A) and an electrolyte (D) represented by general formula (1) below. In formula (1), R.sup.1 to R.sup.3 each represent alkyl having 1 to 3 carbon atoms, R.sup.4 to R.sup.7 each represent alkyl having 1 to 3 carbon atoms or a hydrogen atom, and X.sup.− represents an anion of an acid (C). ##STR00001##

The present invention provides a novel electrolyte solution capable of providing electrochemical devices having a high storage capacity retention. The electrolyte solution of the present invention contains a fluorinated phosphoric acid ester containing a non-fluorinated alkylene group having one or more carbon atoms as a linking group.

A method for producing an electrolytic capacitor is performed in the following procedure. A solid electrolyte layer including a conductive polymer and a polyhydric alcohol is formed on an anode body on which a dielectric layer is formed. Then, the anode body on which the solid electrolyte layer is formed is impregnated with a first treatment liquid that contains an oxoacid having two or more hydroxy groups.

An aqueous electrolyte for a capacitor contains at least one transition metal complex. An aqueous electrolyte containing at least one transition metal complex can be used in a supercapacitor, in a pseudocapacitor, or in a hybrid supercapacitor. A hybrid supercapacitor contains an aqueous electrolyte, which contains at least one transition metal complex.