A dye-sensitized solar panel includes a titanium nanoparticle layer and a plant-derived photo-sensitizer supported on the titanium nanoparticle layer. The photo-sensitizer can be extracted from chard (B. vulgaris subsp. cicla), and the titanium nanoparticle layer includes titanium nanoparticles synthesized using henna (Lawsonia inermis). The titanium nanoparticle layer can, in addition to titanium nanoparticles, include zinc oxide nanoparticles.

The present invention provides an improved redox couple for electrochemical and optoelectronic devices. The redox couple is based on a complex of a first row transition metal, said complex containing at least one mono-, bi-, or tridentate ligand comprising a substituted or unsubstituted ring or ring system comprising a five-membered N-containing heteroring and/or a six-membered ring comprising at least two heteroatoms, at least one of which being a nitrogen atom, said five- or six-membered heteroring, respectively, comprising at least one double bond. The invention also relates to electrolytes and to the devices containing the complex, and to the use of the complex as a redox couple. The invention further provides electrochemical and/or optoelectronic devices comprising a first and a second electrode and, between said first and second electrode, a charge transport layer, said a charge transport layer comprising tetracyanoborate ([B(CN).sub.4].sup.−) and a cationic metal complex functioning as redox-couple.

A formulation for use in the preferential formation of thin films of a perovskite material AMX 3 with a certain required crystalline structure, wherein said formulation comprises two or more compounds which between them comprise one or more first organic cations A; one or more metalcations M; one or more second cations A′; one or more first anions X and one or more second anions X′.

A photoelectric conversion element including a first substrate, a first electrode on the first substrate, a photoelectric conversion layer on the first electrode, a second electrode on the photoelectric conversion layer, a second substrate on the second electrode, and a sealing member disposed between the first electrode and the second substrate and configured to seal at least the photoelectric conversion layer, the first electrode including a through section, the sealing member being in contact with the first substrate through the through section.

This disclosure relates to photocatalytic polyoxometalate compositions of tungstovanadates and uses as water oxidation catalysts. In certain embodiments, the disclosure relates to compositions comprising water, a complex of a tetra-metal oxide cluster and VW.sub.9O.sub.34 ligands, and a photosensitizer. Typically, the metal oxide cluster is Co. In certain embodiments, the disclosure relates to electrodes and other devices comprising water oxidation catalysts disclosed herein and uses in generating fuels and electrical power from solar energy.

Transmission of low energy light is one of the primary loss mechanisms of a single junction solar cell. Molecular photon upconversion via triplet-triplet annihilation (TTA-UC)—combining two or more low energy photons to generate a higher energy excited state—is an intriguing strategy to surpass this limit. The present disclosure is directed to self-assembled multilayers, e.g., bi- or trilayers, on metal oxide surfaces as a strategy to facilitate TTA-UC emission and demonstrate direct charge separation of the upconverted state. A three-fold enhancement in transient photocurrent is achieved at light intensities as low as two equivalent suns. The multilayer structure comprises a substrate comprising a metal oxide surface and a bulk region, and a self-assembled bilayer film, the bilayer film comprising: (a) an acceptor molecule covalently bonded to the metal oxide surface; (b) a linking metal ion bonded to the acceptor molecule; and (c) one or more sensitizer molecule(s) bonded to the linking co-ordinating metal ion.

Photovoltaic devices such as solar cells, hybrid solar cell-batteries, and other such devices may include an active layer disposed between two electrodes. The active layer may have perovskite material and other material such as mesoporous material, interfacial layers, thin-coat interfacial layers, and combinations thereof. The perovskite material may be photoactive. The perovskite material may be disposed between two or more other materials in the photovoltaic device. Inclusion of these materials in various arrangements within an active layer of a photovoltaic device may improve device performance. Other materials may be included to further improve device performance, such as, for example: additional perovskites, and additional interfacial layers.

Compounds for use as sensitizer dyes in dye-sensitized solar cells.

Disclosed are a dye-sensitized solar cell including a polymer/graphene composite gel electrolyte and methods of preparing the dye-sensitized solar cell

A photoelectric conversion element includes a frame-shaped insulating sealing part that is disposed between the plurality of first electrodes and the cover and defines a space inside the photoelectric conversion element, a photoelectric conversion part formed on an upper surface of a first electrode in the space; a second electrode formed in the space, which includes a flat portion and a bent portion, and insulates the photoelectric conversion part from the second electrode, an inter-cell insulating part that insulates the first electrode from the second electrode, a carrier transporting part with which the space is filled, and an insulating bonding part that has at least a portion positioned between the porous insulating part and the cover and is brought into contact with the inter-cell insulating part and with a portion of the flat portion so as to bond the inter-cell insulating part and the second electrode to each other.