According to this method for producing an electrode, a fibrous binder is produced by fibrillating a particulate binder, which has a volume-based median diameter of from 5 to 100 .Math.m, by means of the application of a shear force, and an electrode mixture is produced by mixing the fibrous binder with an active material, said electrode mixture having a solid content concentration of substantially 100%. It is preferable that the fibrillation is carried out so that the breaking peripheral velocity ratio of the electrode mixture is 8 or more. In addition, an electrode mixture sheet is produced by shaping the electrode mixture into a sheet form by rolling, and the electrode mixture sheet is subsequently bonded to a core material.

An electrochemical apparatus, including a positive electrode, a negative electrode, and an electrolyte, where the positive electrode includes a positive electrode active material layer, and the positive electrode active material layer has a relatively small contact angle with respect to a non-aqueous solvent. The electrochemical apparatus has improved cycling performance, rate performance, and direct-current resistance.

The power storage device comprises an electrode assembly including a positive electrode, a separator, and a negative electrode, and an electrolyte solution. The negative electrode comprises a negative electrode current collector and a negative electrode active material layer. The active material layer comprises a surplus region A not facing the positive electrode active material layer, an end region B facing a region in the positive electrode active material layer, the region extending from an end of the positive electrode active material layer toward a center of the positive electrode active material layer by a length of 5% of a length from the center to the end, and a center region C. A negative electrode potential VA and a negative electrode potential VC after the positive electrode and the negative electrode are short-circuited satisfy Formulas below: (1): VA≤2.0 V, (2): VC≤1.0 V, (3): VA/VC≥0.7.

The power storage device comprises an electrode assembly including a positive electrode, a separator, and a negative electrode, and an electrolyte solution. The negative electrode comprises a negative electrode current collector and a negative electrode active material layer. The active material layer comprises a surplus region A not facing the positive electrode active material layer, an end region B facing a region in the positive electrode active material layer, the region extending from an end of the positive electrode active material layer toward a center of the positive electrode active material layer by a length of 5% of a length from the center to the end, and a center region C. A negative electrode potential VA and a negative electrode potential VC after the positive electrode and the negative electrode are short-circuited satisfy Formulas below: (1): VA≤2.0 V, (2): VC≤1.0 V, (3): VA/VC≥0.7.

An electrochemical device of the present invention includes a positive electrode, a negative electrode, and a separator disposed between the positive electrode and the negative electrode. The positive electrode includes a positive current collector containing aluminum, a positive electrode material layer containing a conductive polymer, and an aluminum oxide layer disposed on a surface of the positive current collector. The aluminum oxide layer contains fluorine.

An electrochemical device of the present invention includes a positive electrode, a negative electrode, and a separator disposed between the positive electrode and the negative electrode. The positive electrode includes a positive current collector containing aluminum, a positive electrode material layer containing a conductive polymer, and an aluminum oxide layer disposed on a surface of the positive current collector. The aluminum oxide layer contains fluorine.

The present invention discloses a method for lead carbon compression moulding comprising a first stacking step and a first compressing step so that a lead-carbon electrode is obtained through compressing a lead-carbon sandwich stacked of a lead material and a carbon material. Pressurization of the working environment or heating both the lead material and the carbon material is not required during the procedure. A massive production of lead-carbon electrode at room temperature can be anticipated. The lead-carbon electrode produced thereby enhance tolerance of the battery against instable electric current or voltage, and performance remains steady after multiple times of charge-discharge cycles. The lead-carbon electrode produced thereby demonstrates high potentials for application with low cost, low loss and high capacity.

A binder for an electrochemical device made of a polymer material including a first polymer containing a first constituent unit having a guest group in a side chain; and a second polymer containing a second constituent unit having a host group in a side chain. Also disclosed is an electrode mixture containing the binder, an electrode active material and a dispersion medium; an electrode containing the binder, an electrode active material and a current collector; an electrochemical device including the electrode; and a secondary battery including the electrode.

Provided are new solid-state electrochemical cells and methods for fabricating these cells. In some examples, a solid-state electrochemical cell is assembled using a negative electrode, a positive electrode, and a gel-polymer electrolyte layer, which is disposed and provides ionic communications between these electrodes. Prior to this assembly, the negative electrode is free from electrolytes. The negative electrode is fabricated using a coating technique, e.g., forming a slurry, comprising a polymer binder and one or more negative active materials structures, such as silicon, graphite, and the like. The porosity, size, and other characteristics of the negative active materials structures and of the resulting coated later are specifically controlled to ensure operation with the gel-polymer electrolyte layer or, more specifically, high-rate charge and discharge, e.g., greater than 1 mA/cm.sup.2. The gel-polymer electrolyte layer releases some of its liquid electrolyte after the interface with the negative electrode is formed.

One aspect of the present invention is a positive electrode for an energy storage device including a positive active material layer, in which the positive active material layer includes a positive active material particle having a ratio of a secondary particle size to a primary particle size of 3 or less, and a fibrous conductive agent.