An electricity storage device includes a positive electrode containing a positive electrode active material, a negative electrode containing a negative electrode active material, and an electrolyte that includes an organic crystal layer including a layered structure and an organic solvent introduced into the organic crystal layer and that is interposed between the positive electrode and the negative electrode to conduct alkali metal ions. The layered structure includes an organic backbone layer containing an aromatic dicarboxylic acid anion having an aromatic ring structure, and an alkali metal element layer containing an alkali metal element that is coordinated with oxygen contained in a carboxylic acid of the organic backbone layer to form a framework. At least one of the positive electrode and the negative electrode adsorbs and desorbs the ions to store and release electric charge.

A power system adapted for supplying power in a high temperature environment is disclosed. The power system includes a rechargeable energy storage that is operable in a temperature range of between about seventy degrees Celsius and about two hundred and fifty degrees Celsius coupled to a circuit for at least one of supplying power from the energy storage and charging the energy storage; wherein the energy storage is configured to store between about one one hundredth (0.01) of a joule and about one hundred megajoules of energy, and to provide peak power of between about one one hundredth (0.01) of a watt and about one hundred megawatts, for at least two charge-discharge cycles. Methods of use and fabrication are provided. Embodiments of additional features of the power supply are included.

A power system adapted for supplying power in a high temperature environment is disclosed. The power system includes a rechargeable energy storage that is operable in a temperature range of between about seventy degrees Celsius and about two hundred and fifty degrees Celsius coupled to a circuit for at least one of supplying power from the energy storage and charging the energy storage; wherein the energy storage is configured to store between about one one hundredth (0.01) of a joule and about one hundred megajoules of energy, and to provide peak power of between about one one hundredth (0.01) of a watt and about one hundred megawatts, for at least two charge-discharge cycles. Methods of use and fabrication are provided. Embodiments of additional features of the power supply are included.

An energy storage device, especially a super capacitor, useful for high temperature applications has current collector elements supporting a carbonaceous matrix modified or doped with pseudo-capacitive materials, including one or more transition metal dichalcogenides, transition metal oxides and mixtures thereof, in contact with a non-aqueous electrolyte composition whereby it is possible to exploit the faradic mechanism in addition to the electric double layer mechanism as an energy storage principle.

An energy storage device, especially a super capacitor, useful for high temperature applications has current collector elements supporting a carbonaceous matrix modified or doped with pseudo-capacitive materials, including one or more transition metal dichalcogenides, transition metal oxides and mixtures thereof, in contact with a non-aqueous electrolyte composition whereby it is possible to exploit the faradic mechanism in addition to the electric double layer mechanism as an energy storage principle.

There is provided a metal or metal-ion battery comprising an aluminum current collector and a low-corrosiveness non-aqueous electrolyte comprising, as a solvent, a carbonate compound of formula (I):

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This battery has an upper voltage limit of about 4.2 V or more and anodic dissolution of aluminum during battery operation at said voltage is suppressed.

An electrolyte solution contains tris(trimethylsilyl) phosphite and at least one fluorinated saturated cyclic carbonate (1) selected from pentafluoropropylethylene carbonate and heptafluoroisobutylethylene carbonate. Also disclosed is an electrochemical device including the electrolyte solution.

An electrolyte solution contains tris(trimethylsilyl) phosphite and at least one fluorinated saturated cyclic carbonate (1) selected from pentafluoropropylethylene carbonate and heptafluoroisobutylethylene carbonate. Also disclosed is an electrochemical device including the electrolyte solution.

Provided is a positive electrode active material which suppresses a reduction in capacity due to charge and discharge cycles when used in a lithium ion secondary battery. A covering layer is formed by segregation on a superficial portion of the positive electrode active material. The positive electrode active material includes a first region and a second region. The first region exists in an inner portion of the positive electrode active material. The second region exists in a superficial portion of the positive electrode active material and part of the inner portion thereof. The first region includes lithium, a transition metal, and oxygen. The second region includes magnesium, fluorine, and oxygen.

Provided is a positive electrode active material which suppresses a reduction in capacity due to charge and discharge cycles when used in a lithium ion secondary battery. A covering layer is formed by segregation on a superficial portion of the positive electrode active material. The positive electrode active material includes a first region and a second region. The first region exists in an inner portion of the positive electrode active material. The second region exists in a superficial portion of the positive electrode active material and part of the inner portion thereof. The first region includes lithium, a transition metal, and oxygen. The second region includes magnesium, fluorine, and oxygen.