A composite for a porous transport layer may include a particulate substrate including at least one selected from a group consisting of an oxide of a first metal and a second metal, and nanoparticles of a third metal formed on a surface of the particulate substrate, a sintered body thereof, and a method for preparing the same.

A fuel reformer module (8005) for initiating catalytic partial oxidation (CPOX) to reform a hydrocarbon fuel oxidant mixture (2025, 3025) to output a syngas reformate (2027) to solid oxide fuel cell stack (2080, 5040). A solid non-porous ceramic catalyzing body (3030) includes a plurality of catalyst coated fuel passages (3085). A thermally conductive element (9005, 10005, 11005, 13005), with a coefficient of thermal conductivity of 50 W/m° K or greater is thermally conductively coupled with the catalyzing body. A first thermal sensor (8030) is thermally conductively coupled with the thermally conductive element. A second thermal sensor is thermally conductively coupled with a surface of the fuel cell stack. A control method independently modulates an oxidant input flow rate, based on first thermal sensor signal values, a hydrocarbon fuel input flow rate, based on second thermal sensor signal values.

There is disclosed a method of making an electrode for an electrochemical reactor including the steps of providing a template and depositing electrode material such that the electrode material is in contact with the template. This template is provided in a form that produces channels in the electrode material. There is also disclosed an electrode for an electrochemical reactor which includes electrode material and a template, with the template occupying channels in the electrode material.

A CoVO.sub.x composite electrode and method of making is described. The composite electrode comprises a substrate with an average 0.5-5 μm thick layer of CoVO.sub.x having pores with average diameters of 2-200 nm. The method of making the composite electrode involves contacting the substrate with an aerosol comprising a solvent, a cobalt complex, and a vanadium complex. The CoVO.sub.x composite electrode is capable of being used in an electrochemical cell for water oxidation.

In certain embodiments, an apparatus includes an electrolyte membrane layer (EML), and includes a first electrode catalyst layer (ECL) and a first metallic gas diffusion layer (MGDL) positioned to a first side of the EML such that the first ECL is positioned between the first MGDL and the EML. The first MGDL includes a metal-containing layer and a coating of porous material disposed on a surface of the metal-containing layer of the first MGDL that faces the first ECL. The apparatus further includes a second ECL and a second MGDL positioned to the second side of the EML such that the second ECL is positioned between the second MGDL and the EML. The second MGDL includes a metal-containing layer and a coating of porous material disposed on a surface of the metal-containing layer of the second MGDL that faces the second ECL.

A design of and the process for forming a rigidly bonded metal supported electro-chemical device stack is provided. The electro-chemical device stack can be a solid oxide fuel cell or solid oxide electrolysis stack. The stack comprises multiple planar cells connected in serial by planar metal interconnects. The cells have metal support layers on both anode and cathode sides. The interconnect has gas channels embedded. Thin ceramic electro-chemical active electrodes and electrolyte are sandwiched between the metal support layers. The cells and interconnects are rigidly bonded to form a rigid body stack. The process comprises the steps of a). forming metal supported electro-chemical device cells with metal supports on both anode and cathode sides, b). sealing the peripherals of porous cell layers with an electrically insulating sealing material such as glass. c). bonding the cells and interconnects through commonly used metal-to-metal bonding methods, such as brazing or laser welding.

An electrochemical cell includes a fuel electrode, an air electrode containing a perovskite type oxide as a main component, the perovskite type oxide being represented by a general formula ABO.sub.3 and containing La and Sr at an A site, and a solid electrolyte layer arranged between the fuel electrode and the air electrode. The air electrode includes a first portion and a second portion, the first portion being located on a side opposite to the solid electrolyte layer, the second portion being located on the solid electrolyte layer side. A first ratio of an La concentration to an Sr concentration detected at the first portion through Auger electron spectroscopy is at least 1.1 times a second ratio of an La concentration to an Sr concentration detected at the second portion through Auger electron spectroscopy.

The present disclosure is directed to compositions and structures of supported metal catalysts for use in applications such as direct methanol fuel cells. Generally, implementations include supported metal catalysts that include Pt active sites that have been modified by addition or co-localization of a second metal such as Cu, Co, Ni, and/or other base metals to lower the inhibiting effect of strongly-adsorbed CO, an intermediate of methanol oxidation. An example aspect of the present disclosure includes catalyst compositions where the exterior metal sites in the supported catalyst include at least two metals: Pt and a competitive binder (e.g., a second metal).

Described herein are solid oxide fuel cells comprising conductive layers and methods of fabricating such cells. Specifically, a solid oxide fuel cell comprises cathode and anode layers, each comprising a porous base, catalyst sites disposed within the base, and a conductive layer. The conductive layer provides electrical conduction between the corresponding current collector and the catalyst sites. The conductive layer may at least partially extend into the porous base. For example, at least a portion of the conductive layer may be formed by infiltration of the porous base, e.g., before catalyst infiltration. In some examples, at least a portion of the conductive layer forms an interface between the corresponding porous base and the current collector. In these examples, the conductive layer is formed from an initial (green) conductive layer that is stacked between layers used to form the porous base and current collector and sintered the stack.

Disclosed is a method of manufacturing a solid oxide fuel cell including a multi-layered electrolyte layer using a calendering process. The method for manufacturing a solid oxide fuel cell is a continuous process, thus providing high productivity and maximizing facility investment and processing costs. In addition, the solid oxide fuel cell manufactured by the method includes an anode that is free of interfacial defects and has a uniform packing structure, thereby advantageously greatly improving the production yield and power density. In addition, the solid oxide fuel cell has excellent interfacial bonding strength between respective layers included therein, and includes a multi-layered electrolyte layer in which the secondary phase at the interface is suppressed and which has increased density, thereby advantageously providing excellent output characteristics and long-term stability even at an intermediate operating temperature.