A solid oxide fuel cell comprising an anode layer, an electrolyte layer, and a two phased cathode layer. The two phased cathode layer comprises praseodymium and gadolinium-doped ceria. Additionally, the solid oxide fuel cell does not contain a barrier layer.

A method of making a catalyst layer of a membrane electrode assembly (MEA) for a polymer electrolyte membrane fuel cell includes the step of preparing a porous buckypaper layer comprising at least one selected from the group consisting of carbon nanofibers and carbon nanotubes. Platinum group metal nanoparticles are deposited in a liquid solution on an outer surface of the buckypaper to create a platinum group metal nanoparticle buckypaper. A proton conducting electrolyte is deposited on the platinum group metal nanoparticles by electrophoretic deposition to create a proton-conducting layer on the an outer surface of the platinum nanoparticles. An additional proton-conducting layer is deposited by contacting the platinum group metal nanoparticle buckypaper with a liquid proton-conducting composition in a solvent. The platinum group metal nanoparticle buckypaper is dried to remove the solvent. A membrane electrode assembly for a polymer electrolyte membrane fuel cell is also disclosed.

A metal air battery includes an air electrode containing a conductive material and a catalyst, a negative electrode containing a metal, and an electrolyte having ionic conductivity. The conductive material contains a co-continuous body of a three-dimensional network structure in which nanostructure bodies are branched, and the catalyst contains oxide having a cage-shaped crystal structure.

Disclosed are non-noble element compositions of matter, structures, and methods for producing the catalysts that can catalyze oxygen reduction reactions (ORR). The disclosed composition of matter can be comprised of graphitic carbon doped with nitrogen and associated with one or two kinds of transition metals. The disclosed structure is a three dimensional, porous structure comprised of a plurality of the disclosed compositions of matter. The disclosed structure can be fashioned into an electrode of an electrochemical cell to serve as a diffusion layer and also to catalyze an ORR. Two methods are disclosed for producing the disclosed composition of matter and structure. The first method is comprised of two steps, and the second method is comprised of a single step.

An electrocatalyst including carbon and a nanosheet supported on the carbon. The nanosheet includes a metal ruthenium nanosheet, and a platinum atomic layer formed on an entire surface of the metal ruthenium nanosheet. The metal ruthenium nanosheet is a monoatomic layer, and the platinum atomic layer is a monoatomic layer or a monoatomic layer laminated body.

A lithium air battery includes: a lithium negative electrode; a positive electrode; and an ion conductive oxygen-blocking film which is disposed on the lithium negative electrode, wherein the ion conductive oxygen-blocking film includes a first polymer including a polyvinyl alcohol or a polyvinyl alcohol blend, and a lithium salt, and wherein the ion conductive oxygen-blocking film has an oxygen transmission rate of about 10 milliliters per square meter per day to about 10,000 milliliters per square meter per day. Also a method of manufacturing a lithium air battery is disclosed.

The present disclosure relates to a composition that includes a fluoropolymer, a polymerized ionic liquid block copolymer (PILBC), and a catalyst, where the fluoropolymer is configured to affect ionic mobility, and the PILBC is configured to affect a property of the catalyst. In some embodiments of the present disclosure, the property may include at least one of oxygen transport and/or an active site functionality of the catalyst.

The present invention provides a novel and improved metal-air battery in which a lot of catalyst can be disposed in a triple phase boundary, and further, battery properties can be improved. In the metal-air battery according to the present invention, a catalyst layer of an air electrode of a metal-air battery contains a catalyst element and a carbon material, the carbon material comprises two materials of a carbon material A supporting thereon the catalyst element and a carbon material B not supporting the catalyst element, the catalyst layer comprises an agglomerate X containing the catalyst element, the carbon material A and the carbon material B as main components and an agglomerate Y containing the carbon material B as a main component, and the agglomerate X is a continuum and the agglomerate Y is dispersed in the agglomerate X.

Flow cell batteries and methods of producing an electric current are provided. In some implementations, a flow cell battery includes an electrochemical cell including an ion exchange membrane, an anode current collector, and a cathode current collector. The space between the ion exchange membrane and the anode current collector forms a first channel and the space between the ion exchange membrane and the cathode current collector forms a second channel. The ion exchange membrane is configured to allow ions to pass between the first and second channel. The battery includes a first tank configured to flow an anolyte through the first channel, wherein the anolyte is hydrogen gas. The battery includes a second tank configured to flow a catholyte through the second channel, wherein the catholyte is a compound that can be reversibly hydrogenated and dehydrogenated. The flow cell battery can be used to generate electric current.

Composition includes: (A) a mixed oxide of lithium, nickel, manganese and cobalt and (B) a fluorinated anion salt of a polycationic polymer. The fluorinated anion salt of the polycationic polymer contains repeating units represented by one of formula (1) or formula (2):

##STR00001##

wherein, in the formula (1), N.sup.+ is a nitrogen atom constituting a quaternary ammonium cation, R.sup.1 and R.sup.2 being each independently a substituent containing a carbon atom bonded to the nitrogen atom,

##STR00002##

wherein, in the formula (2), R.sup.3 is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms.