A method of forming a catalyst layer for a fuel cell includes electrospinning a first solution of an ionomer, a binder, and a first solvent to form a porous mat having an interior and an exterior and including a plurality of ionomer nanofibers intertwined with one another to define a plurality of pores within the interior. A portion of the plurality of ionomer nanofibers define the exterior and have an internal surface facing the interior and an external surface facing away from the interior. The method also includes electrospraying a second solution of a catalyst and a second solvent onto the porous mat such that the catalyst is disposed on each external surface and is not embedded within the plurality of pores to thereby form the catalyst layer. A catalyst layer and a fuel cell are also described.

A cathode can include: an electrode substrate; a porphyrin precursor attached to the substrate; and an enzyme coupled to the electrode substrate to be associated with the porphyrin precursor, the enzyme reduces oxygen. The cathode can include a conductive material associated with the porphyrin precursor and/or the enzyme. The cathode can include 1-pyrenebutanoic acid, succinimidyl ester (PBSE) associated with the porphyrin precursor and/or the enzyme and/or the conductive material. The cathode can include 2,5-dimethyl-1-phenyl-1H-pyrrole-3-carbaldehyde (DMY-Carb) associated with the 1-pyrenebutanoic acid, succinimidyl ester (PBSE) and/or the porphyrin precursor and/or the enzyme and/or the conductive material. The porphyrin precursor is attached to the substrate through covalent coupling. In some aspects, substrate is linked to the porphyrin precursor, the porphyrin precursor is linked to the conductive material, the conductive material is linked to the PBSE, the PBSE is linked to the DMY-carb, and the DMY-carb is linked to the enzyme.

An anode can include: an electrode substrate; a first region of the substrate having a catalyst composition located thereon, wherein the catalyst composition includes an inorganic or metallic catalyst; and a second region of the substrate having an enzyme composition located thereon, wherein the combination of the catalyst composition and enzyme composition converts a fuel reagent to carbon dioxide at neutral pH. The first region and second region can be separate regions. The catalyst of the catalyst composition can include gold nanoparticles. The catalyst can include an inorganic or metallic catalyst selected from vanadium oxide, titanium (III) chloride, Pd(OAc).sub.2, MnO, zeolite, alumina, graphitic carbon, palladium, platinum, gold, ruthenium, rhodium, iridium, or combinations thereof. The catalyst can be nanoparticle, nanorod, nanodot, or combination thereof. The catalyst can have sizes that range from about 10 to 20 nm.

There is provided a fuel cell cathode electrode, comprising a porous skeletal medium, the surface of which medium is modified or otherwise arranged or constructed to induce enhanced activated behaviour, wherein the enhanced activated behaviour is induced by means of increasing the surface area for a given volume of the electrode and/or by increasing the number and/or availability of reactive sites on the electrode. A fuel cell having such a cathode electrode, a method of manufacturing such a cathode electrode, and use of such a cathode electrode in a fuel cell is also disclosed.

An adhesive layer is placed in a region outside an outer peripheral edge part of a second catalyst layer, on a second surface of an electrolyte membrane. A support frame is placed via the adhesive layer such that the second catalyst layer and a second gas diffusion layer are placed inside an opening of the support frame. A specific region as a region between the outer peripheral edge part of the second catalyst layer and an inner peripheral edge part of the opening of the support frame is present. A predetermined material is placed inside a recessed portion present on a surface of the adhesive layer inside the specific region, the predetermined material containing at least one of a first substance having an action of decomposing hydrogen peroxide and a second substance having an action of decomposing hydroxyl radicals.

A redox flow battery may include: a membrane interposed between a first electrode positioned at a first side of the membrane and a second electrode positioned at a second side of the membrane opposite to the first side; a first flow field plate comprising a plurality of positive flow field ribs, each of the plurality of positive flow field ribs contacting the first electrode at first supporting regions on the first side; and the second electrode, including an electrode spacer positioned between the membrane and a second flow field plate, the electrode spacer comprising a plurality of main ribs, each of the plurality of main ribs contacting the second flow field plate at second supporting regions on the second side, each of the second supporting regions aligned opposite to one of the plurality of first supporting regions. As such, a current density distribution at a plating surface may be reduced.

The present invention provides a highly conductive electrode material having high oxygen reduction activity. The present invention also provides an electrode material composition and a fuel cell each containing the electrode material. The present invention relates to an electrode material having a structure containing a noble metal and/or an oxide thereof supported on titanium oxynitride or a composite compound of titanium oxynitride and an oxide of titanium. The titanium oxynitride or the composite compound of titanium oxynitride and an oxide of titanium is in the form of powder. The electrode material has pore diameter distribution satisfying the following features (I) and (II): (I) a ratio (b/a) of a peak area b in a pore diameter range of 50 to 180 nm to a peak area a in a pore diameter range of 0 to 180 nm, calculated from log differential pore volume distribution, being 0.9 or more, and (II) a cumulative pore volume in a pore diameter range of 50 to 180 nm being 0.1 cm.sup.3/g or greater.

The present application relates to a method of manufacturing an anode supporter of a solid oxide fuel cell and an anode supporter of a solid oxide fuel cell, and may improve performance and durability of the fuel cell by improving an interfacial property between the anode supporter and an electrolyte.

The present subject matter relates generally to the derivatization of highly-aligned carbon nanotube sheet substrates with one or more transition metal centers and to uses of the resulting metal-derivatized CNT sheet substrates.

The present invention relates to a positive electrode of a lithium-air battery having a side reaction prevention layer with a partially introduced metal catalyst, and a method for preparing the same, and in particular, to a positive electrode of a lithium-air battery having a side reaction prevention layer with a metal catalyst sporadically partially introduced to a surface thereof, and a method for preparing the same. The lithium-air battery according to the present invention suppresses a side reaction at an interface between a positive electrode active material and an electrolyte thereby effectively reduces an overvoltage when charged, and therefore, does not cause liquid electrolyte decomposition, which is effective in enhancing a cycle life.