H01M4/8817

Chemical bonding for catalyst/membrane surface adherence in membrane electrolyte fuel cells
10096838 · 2018-10-09 · ·

An alkaline membrane fuel cell including at least one of i) a catalyst coated OH ion conducting membrane having a catalyst layer and an OH ion conducting membrane, and ii) a catalyst coated carbonate ion conducting membrane having a catalyst layer and a carbonate ion conducting membrane, respectively, wherein the at least one catalyst layer is chemically bonded to a surface of the at least one membrane, wherein the chemical bonding is established by crosslinking of polymer constituents across an interface between the at least one catalyst layer and the at least one membrane.

Non-carbon mixed-metal oxide support for electrocatalysts

A non-carbon support particle is provided for use in electrocatalyst. The non-carbon support particle consists essentially of titanium dioxide and ruthenium dioxide. The titanium and ruthenium can have a mole ratio ranging from 1:1 to 9:1 in the non-carbon support particle. Also disclosed are methods of preparing the non-carbon support and electrocatalyst taught herein.

Non-carbon mixed-metal oxide electrocatalysts

Electrocatalysts having non-corrosive, non-carbon support particles are provided as well as the method of making the electrocatalysts and the non-corrosive, non-carbon support particles. Embodiments of the non-corrosive, non-carbon support particle consists essentially of titanium dioxide and ruthenium dioxide. Active catalyst particles of a platinum alloy are deposited onto each non-carbon composite support particle. The electrocatalyst can be used in fuel cells, for example.

METHOD FOR SPLITTING WATER

A CoVO.sub.x composite electrode and method of making is described. The composite electrode comprises a substrate with an average 0.5-5 ?m thick layer of CoVO.sub.x having pores with average diameters of 2-200 nm. The method of making the composite electrode involves contacting the substrate with an aerosol comprising a solvent, a cobalt complex, and a vanadium complex. The CoVO.sub.x composite electrode is capable of being used in an electrochemical cell for water oxidation.

Electrochemical cell for hydrogen and oxygen production

A CoVO.sub.x composite electrode and method of making is described. The composite electrode comprises a substrate with an average 0.5-5 ?m thick layer of CoVO.sub.x having pores with average diameters of 2-200 nm. The method of making the composite electrode involves contacting the substrate with an aerosol comprising a solvent, a cobalt complex, and a vanadium complex. The CoVO.sub.x composite electrode is capable of being used in an electrochemical cell for water oxidation.

ELECTROLYTE MEMBRANE FOR MEMBRANE-ELECTRODE ASSEMBLY AND METHOD OF MANUFACTURING SAME

A highly durable electrolyte membrane using cerium oxide supported with an alloy catalyst that is a hydrogen-oxygen reaction catalyst for improving chemical durability of an electrolyte membrane increases durability of a membrane-electrode assembly including the same and decreases the manufacturing cost thereof.

Gas diffusion layer for metal-air battery, method of manufacturing the same, and metal-air battery including the same

A gas diffusion layer for a metal-air battery, the gas diffusion layer including: a porous layer including non-conductive fiber structures, a conductive carbon layer including a carbon material that is disposed on a surface of a non-conductive fiber structure of the plurality of non-conductive fiber structures.

CATALYST COATED MEMBRANE (CCM) FOR ALKALINE EXCHANGE MEMBRANE FUEL CELL AND METHOD OF MAKING SAME
20180254502 · 2018-09-06 · ·

A catalyst coated membrane (CCM) for an alkaline exchange membrane fuel cell may include: a membrane including at least one of: a polymer or a copolymer having a first functional chemical group; an anode catalyst layer coated on one side of the membrane including: anode catalyst nano-particles and a polymer or a copolymer having a second functional chemical group; and a cathode catalyst layer coated on a side of the membrane opposite the anode catalyst layer, including: cathode catalyst nano-particles and a polymer or a copolymer having a third functional chemical group, wherein the first functional chemical group, the second functional chemical group and the third functional chemical group are all crosslinked with the same crosslinking chemical group.

SUBSTRATE FILM, CATALYST TRANSFER SHEET, METHOD FOR PRODUCING MEMBRANE ELECTRODE ASSEMBLY, AND METHOD FOR PRODUCING CATALYST LAYER-COATED ELECTROLYTE MEMBRANE
20180244882 · 2018-08-30 · ·

The present invention provides a substrate film that has a catalyst coating liquid having good coating properties when producing a membrane electrode assembly, has a catalyst layer and support film having good release properties after the catalyst layer is transferred to an electrolyte membrane using a catalyst transfer sheet, and does not contaminate the catalyst layer. Provided is a substrate film for a catalyst transfer sheet, said substrate film being formed by introducing fluorine atoms to at least one surface of a base film formed from one or more types of polymers selected from the group consisting of polyethylene, polypropylene, polyethylene terephthalate, polybutylene terephthalate, polyethylene napthalate, polyphenylene sulfide, polysulf ones, polyether ketone, polyether ether ketone, polyimides, polyetherimide, polyamides, polyamide-imides, polybenzimidazoles, polycarbonates, polyarylates, and polyvinyl chloride, wherein the ratio, measured by X-ray photoelectron spectroscopy, of the number of fluorine atoms/the number of carbon atoms in the surface to which the fluorine atoms are introduced, i.e. the modified surface, is 0.02-1.9, inclusive.

Composition for fuel cell electrode

In some examples, a fuel cell comprising an anode; an electrolyte; cathode barrier layer; and a nickelate composite cathode separated from the electrolyte by the cathode barrier layer; and a cathode current collector layer. The nickelate composite cathode includes a nickelate compound and an ionic conductive material, and the nickelate compound comprises at least one of Pr.sub.2NiO.sub.4, Nd.sub.2NiO.sub.4, (Pr.sub.uNd.sub.v).sub.2NiO.sub.4, (Pr.sub.uNd.sub.v).sub.3Ni.sub.2O.sub.7, (Pr.sub.uNd.sub.v).sub.4Ni.sub.3O.sub.10, or (Pr.sub.uNd.sub.vM.sub.w).sub.2NiO.sub.4, where M is an alkaline earth metal doped on an Asite of Pr and Nd. The ionic conductive material comprises a first co-doped ceria with a general formula of (A.sub.xB.sub.y)Ce.sub.1xyO.sub.2, where A and B of the first co-doped ceria are rare earth metals. The cathode barrier layer comprises a second co-doped ceria with a general formula (A.sub.xB.sub.y)Ce.sub.1xyO.sub.2, where at least one of A or B of the second co-doped ceria is Pr or Nd.