An electrochemical cell including a container including an electrochemical spiral bundle including: a positive electrode including an active material selected from among SOCl.sub.2, SO.sub.2, SO.sub.2Cl; CF.sub.x where x1.5; MnO.sub.2, FeS.sub.2, V.sub.2O.sub.5, I.sub.2, Bi.sub.2O.sub.3, Bi.sub.2Pb.sub.2O.sub.5, CuCl.sub.2, CuF.sub.2, CuO, Cu.sub.4O(PO.sub.4).sub.2, CuS, FeS, MoO.sub.3, Ni.sub.3S.sub.2, AgCl, Ag.sub.2CrO.sub.4, SVO, MO.sub.6S.sub.8, and a mixture of a plurality thereof; a separator; and a negative electrode including an active material made of lithium metal or of a lithium-based alloy. The outer face of the spiral, facing the container, is formed by the positive electrode, and a strip of lithium or of a lithium-based alloy at least partially covers the inner face of the container. The strip pressed against the inner face of the container makes it possible to make use of an outer face of the positive electrode which forms the last turn of the spirally-wound electrode plate group.

A battery includes a first chamber with a first electrode and a second chamber with a second electrode. An intercalation membrane between the first chamber and the second chamber is configured to retain an electrolyte in the first chamber and to accept therein migrating ions of the electrolyte in the presence of an electrical field and lose mechanical integrity permitting the electrolyte to enter the second chamber in order to activate the battery.

Various embodiments of solid-state conductors containing solid polymer electrolytes, electronic devices incorporating the solid-sate conductors, and associated methods of manufacturing are described herein. In one embodiment, a solid-state conductor includes poly(ethylene oxide) having molecules with a molecular weight of about 200 to about 810.sup.6 gram/mol, and a soy protein product mixed with the poly(ethylene oxide), the soy protein product containing glycinin and -conglycinin and having a fine-stranded network structure. Individual molecules of the poly(ethylene oxide) are entangled in the fine-stranded network structure of the soy protein product, and the poly(ethylene oxide) is at least 50 % amorphous.

Disclosed are a non-aqueous electrolyte for a rechargeable lithium battery and a rechargeable lithium battery including the non-aqueous electrolyte, and the non-aqueous electrolyte for a rechargeable lithium battery includes a lithium salt; a non-aqueous organic solvent; and trialkylsilyl borate as an additive, wherein the non-aqueous organic solvent may include a solvent having a low melting point of less than or equal to about 50 C. and ionic conductivity of greater than or equal to about 6 mS/cm at 25 C.

One aspect of this invention relates to hexagonal boron nitride (hBN) ionogel inks using exfoliated hBN nanoplatelets as the solid matrix. The hBN nanoplatelets are produced from bulk hBN powders by liquid-phase exfoliation, allowing printable hBN ionogel inks to be formulated following the addition of an imidazolium ionic liquid and ethyl lactate. The resulting inks are reliably printed with variable patterns and controllable thicknesses by aerosol jet printing, resulting in hBN ionogels that possess high room-temperature ionic conductivities and storage moduli of >3 mS cm1 and >1 MPa, respectively. By integrating the hBN ionogel with printed semiconductors and electrical contacts, fully-printed thin-film transistors with operating voltages below 1 V are demonstrated on polyimide films. These devices exhibit desirable electrical performance and robust mechanical tolerance against repeated bending cycles, thus confirming the suitability of hBN ionogels for printed and flexible electronics.