A solid, ionically conductive, non-electrically conducting polymer material with a plurality of monomers and a plurality of charge transfer complexes, wherein each charge transfer complex is positioned on a monomer.

Ceramic-polymer film includes a polymer matrix, plasticizers, a lithium salt, and a ceramic nanoparticle, LLZO: Al.sub.xLi.sub.7-xLa.sub.3Zr.sub.1.75Ta.sub.0.25O.sub.12 where x ranges from 0 to 0.85. The nanoparticles have diameters that range from 20 to 2000 nm and the film has an ionic conductivity of greater than 1×10.sup.−4 S/cm (−20° C. to 10° C.) and larger than 1×10.sup.−3 S/cm (≥20° C.). Using a combination of selected plasticizers to tune the ionic transport temperature dependence enables the battery based on the ceramic-polymer film to be operable in a wide temperature window (−40° C. to 90° C.). Large size nanocomposite film (area ≥8 cm×6 cm) can be formed on a substrate and the concentration of LLZO nanoparticles decreases in the direction of the substrate to form a concentration gradient over the thickness of the film. This large size film can be employed as a non-flammable, solid-state electrolyte for lithium electrochemical pouch cell and further assembled into battery packs.

A method of forming a package is provided and includes providing two laminate edge portions of the package, each of which includes a foil layer between first and second resin layers; and welding together the respective first resin layers at a first position spaced apart from the edges while not welding the respective first resin layers at the edges, wherein the edge portions include edges from which electrode terminals extend such that portions of the electrode terminals are exposed beyond the edges, and wherein the edge portions are between a sealing portion and exposed portions of positive and negative electrode terminals.

A bipolar battery having a solid ionically conductive polymer material as its electrolyte enabling high voltage discharge.

Separator and electrolyte composites include a porous self-supporting separator film between or adjacent one or two electrolyte films. The electrolyte films may contain a glyme or mixture of glymes, LiX salt and complexing agent, such as PEO. The porous self-supporting separator film may be used dry or wetted with a liquid electrolyte composition. Solid state batteries include the described separator and electrolyte composites in combination with an anode and a cathode.

Provided herein are ionically conductive solid-state compositions that include ionically conductive inorganic particles in a matrix of an organic material. The resulting composite material has high ionic conductivity and mechanical properties that facilitate processing. In particular embodiments, the ionically conductive solid-state compositions are compliant and may be cast as films. In some embodiments of the present invention, solid-state electrolytes including the ionically conductive solid-state compositions are provided. In some embodiments of the present invention, electrodes including the ionically conductive solid-state compositions are provided. The present invention further includes embodiments that are directed to methods of manufacturing the ionically conductive solid-state compositions and batteries incorporating the ionically conductive solid-state compositions.

A lithium-ion battery includes multiple electrodes. At least one of the electrodes is comprised of multiple sheets of electrode mixture, and each of the sheets includes a different percentage of a solid-state electrolyte within the electrode mixture. The sheets are laminated together and to a current collector such that a bottom sheet nearest the current collector comprises a lowest percentage of the solid-state electrolyte. A gradient of percentages of the solid-state electrolyte is formed from the bottom sheet to a topmost sheet comprised of a highest percentage of the solid-state electrolyte.

A bipolar battery having a solid ionically conductive polymer material as its electrolyte enabling high voltage discharge.

Separator and electrolyte composites include a porous self-supporting separator film between or adjacent one or two electrolyte films. The electrolyte films may contain a glyme or mixture of glymes, LiX salt and complexing agent, such as PEO. The porous self-supporting separator film may be used dry or wetted with a liquid electrolyte composition. Solid state batteries include the described separator and electrolyte composites in combination with an anode and a cathode.

The disclosure concerns an electrolyte, an electrolyte ink, a battery or other electrochemical cell including the same, and methods of making the electrolyte and electrochemical cell. The electrolyte includes an ionic liquid comprising a hydrophilic or hydrophobic anion, a multi-valent metal cation suitable for use in a battery cell, a polymer binder, and optional additives (e.g., a solid filler). The electrolyte ink includes components of the electrolyte and a solvent. The solvent and the polymer binder (or, when present, the solid filler) have a hydrophilicity, hydrophobicity or polarity similar to or matching that of the ionic liquid's anion, or form hydrogen bonds with the ionic liquid's anion. The electrolyte includes a solid inorganic filler that provides mechanical support form hydrogen bonds with the anion and/or a counterpart anion of the multi-valent metal cation, and links with a material in an adjacent layer of the electrochemical cell.