The invention relates to polymer compositions that conduct lithium ions including the following ingredients: at least one ionic polymer from the polymerization of an ionic liquid, the cation of which bears at least one polymerizable function; at least one lithium salt; and at least one non-ionic polymer, the composition being a solid composition, i.e., a composition devoid of water and organic solvent(s). The invention also relates to the use of the polymer compositions for entering into the formation of electrolytic membranes of electrochemical lithium generators.

Systems and methods of providing self-healing gel-type electrolyte composites for metal batteries are disclosed. According to aspects of the disclosure, a method includes preparing a ternary mixture including an electrolyte portion, a matrix precursor portion, and a self-healing portion, forming a self-healing gel-electrolyte membrane by initiating polymerization of the gel-forming precursor and the gel-forming initiator to thereby form a polymer matrix, and disposing the self-healing gel-electrolyte membrane between an anode and a cathode. The self-healing portion includes a self-healing precursor that is flowable and a self-healing initiator. The matrix precursor portion includes a gel-forming precursor and a gel-forming initiator. The electrolyte portion and the self-healing portion are disposed substantially throughout the polymer matrix and the polymer matrix includes a plurality of gel-forming active sites.

An all-solid-state secondary battery has a positive electrode collector, a positive electrode active material layer, a negative electrode active material layer, a negative electrode collector, and a solid electrolyte. The solid electrolyte has an interlayer solid electrolyte located between the positive electrode active material layer and the negative electrode active material layer, and the all-solid-state secondary battery further includes a trapping layer that traps a metal of which at least one of the positive electrode collector and the negative electrode collector is formed.

An electrochemical device (100) includes an ion exchange membrane (120), a first electrode (110) adjacent to a first side thereof and a second electrode (130) adjacent to a second side thereof. At least one of the first electrode (110) and the second electrode (130) includes a current collector layer (112, 132) and a catalyzing layer (114, 134) applied thereto. The catalyzing layer (114, 134) includes an ion-conducting polymer (116), a plurality of electroactive catalyst particles (115, 118) and an adhesive (118) that binds the polymer (116), the catalyst particles (115, 118) and the current collector layer together (112, 132). In a method of making an electrode, an ion-conducting polymer, a plurality of electroactive catalyst particles and an adhesive are mixed in a solvent, which is applied to a current collector layer. The solvent is evaporated so that the adhesive binds the polymer and the catalyst particles to the current collector.

Set forth herein are electrolyte compositions that include both organic and inorganic constituent components and which are suitable for use in rechargeable batteries. Also set forth herein are methods and systems for making and using these composite electrolytes.

A method of forming a package is provided and includes providing two laminate edge portions of the package, each of which includes a foil layer between first and second resin layers; and welding together the respective first resin layers at a first position spaced apart from the edges while not welding the respective first resin layers at the edges, wherein the edge portions include edges from which electrode terminals extend such that portions of the electrode terminals are exposed beyond the edges, and wherein the edge portions are between a sealing portion and exposed portions of positive and negative electrode terminals.

Provided are primary electrochemical cells having a stable operating voltage of 0.3 V to 2.0 V that include a Li anode coupled to a cathode that is formed of one or more Group 4A, 3A, or 5A elements provided alone or as an alloy with a second, third or other Group 4A, 3A, or 5A element or one or more transition metals. The cells further include a non-aqueous electrolyte optionally with low volatility such as having a vapor pressure of 5 mm Hg or lower at STP, and optionally a lithium-ion conductive and electrically insulating separator inserted between the anode and the cathode. The cells provide stable operating voltage that in some aspects can serve to power ultra-low power devices for 10 or more years without the need for expensive or inefficient circuitry to alter the cell voltage.

Separator and electrolyte composites include a porous self-supporting separator film between or adjacent one or two electrolyte films. The electrolyte films may contain a glyme or mixture of glymes, LiX salt and complexing agent, such as PEO. The porous self-supporting separator film may be used dry or wetted with a liquid electrolyte composition. Solid state batteries include the described separator and electrolyte composites in combination with an anode and a cathode.

A method for fabricating the electrochemical device includes provision of a first stack. This first stack successively includes: a first electrode, an electrically insulating liquid electrolyte in contact with the first electrode, a second electrode separated from the first electrode by the liquid electrolyte. The method includes an at least partial polymerisation step of the liquid electrolyte.

Set forth herein are electrolyte compositions that include both organic and inorganic constituent components and which are suitable for use in rechargeable batteries. Also set forth herein are methods and systems for making and using these composite electrolytes.