An all-solid-state secondary battery has a positive electrode collector, a positive electrode active material layer, a negative electrode active material layer, a negative electrode collector, and a solid electrolyte. The solid electrolyte has an interlayer solid electrolyte located between the positive electrode active material layer and the negative electrode active material layer, and the all-solid-state secondary battery further includes a trapping layer that traps a metal of which at least one of the positive electrode collector and the negative electrode collector is formed.

Set forth herein are electrolyte compositions that include both organic and inorganic constituent components and which are suitable for use in rechargeable batteries. Also set forth herein are methods and systems for making and using these composite electrolytes.

An oxide all-solid-state battery excellent in lithium ion conductivity and joint strength between an anode active material layer and solid electrolyte layer thereof. In the oxide all-solid-state battery, the solid electrolyte layer is a layer mainly containing a garnet-type oxide solid electrolyte sintered body represented by the following formula (1): (Li.sub.x-3y-z, E.sub.y, H.sub.z)L.sub.M.sub.O.sub.; a solid electrolyte interface layer is disposed between the anode active material layer and the solid electrolyte layer; the solid electrolyte interface layer contains at least a Si element and an O element; and a laminate containing at least the anode active material layer, the solid electrolyte interface layer and the solid electrolyte layer has peaks at positions where 2=32.30.5, 37.60.5, 43.80.5, and 57.70.5 in a XRD spectrum obtained by XRD measurement using CuK irradiation.

The present disclosure provides an electrochemical storage cell including a battery. The battery includes an alkali metal anode having an anode Fermi energy, an electronically insulating, amorphous, dried solid electrolyte able to conduct alkali metal, having the general formula A.sub.3-xH.sub.xOX, in which 0x1, A is the alkali metal, and X is at least one halide, and a cathode including a cathode current collector having a cathode Fermi energy lower than the anode Fermi energy. During operation of the electrochemical storage cell, the alkali metal plates dendrite-free from the solid electrolyte onto the alkali metal anode. Also during operation of the electrochemical storage cell, the alkali metal further plates on the cathode current collector.

Method for producing a positive electrode for a solid-state lithium microbattery comprising the following successive steps: supplying of a substrate made of ceramic, glass or silicon, locally covered with a metal layer, depositing of a cathodic layer made of a positive electrode material, for example made of mixed lithium oxide, the cathodic layer having a thickness greater than 1 m, a first portion of the cathodic layer covering the substrate and a second portion of the cathodic layer covering the metal layer, intended to form the positive electrode, carrying out of a heat treatment at a temperature greater than or equal to 400 C., on the cathodic layer, in such a way as to crystallise the second portion of the cathodic layer in order to form a positive electrode, and in such a way as to delaminate the first portion of the cathodic layer.

The present disclosure provides an electrochemical storage cell including a battery. The battery includes an alkali metal anode having an anode Fermi energy, an electronically insulating, amorphous, dried solid electrolyte able to conduct alkali metal, having the general formula A.sub.3-xH.sub.xOX, in which 0x1, A is the alkali metal, and X is at least one halide, and a cathode including a cathode current collector having a cathode Fermi energy lower than the anode Fermi energy. During operation of the electrochemical storage cell, the alkali metal plates dendrite-free from the solid electrolyte onto the alkali metal anode. Also during operation of the electrochemical storage cell, the alkali metal further plates on the cathode current collector.

The present disclosure relates to a lithium ion-conducting glass ceramic which comprises a residual glass phase that is also ion-conducting, a process for the production thereof as well as its use in a battery. The glass ceramic according to the present disclosure comprises a main crystal phase which is isostructural to the NaSICon crystal phase, wherein the composition can be described with the following formula: Li.sub.1+xyM.sub.y.sup.5+M.sub.2xy.sup.4+(PO.sub.4).sub.3, wherein x is greater than 0 and at most 1, as well as greater than y. Y may take values of between 0 and 1. Here, the following boundary condition has to be fulfilled: (1+xy)>1. Here, M represents a cation with io the valence of +3, +4 or +5. M.sup.3+is selected from Al, Y, Sc or B, wherein at least Al as trivalent cation is present. Independently thereof, M.sup.4+ is selected from Ti, Si or Zr, wherein at least Ti as tetravalent cation is present. Independently thereof, M.sup.5+ is selected from Nb, Ta or La.

Set forth herein are electrolyte compositions that include both organic and inorganic constituent components and which are suitable for use in rechargeable batteries. Also set forth herein are methods and systems for making and using these composite electrolytes.

The present disclosure provides an electrochemical storage cell including a battery. The battery includes an alkali metal anode having an anode Fermi energy, an electronically insulating, amorphous, dried solid electrolyte able to conduct alkali metal, having the general formula A.sub.3-xH.sub.xOX, in which 0x1, A is the alkali metal, and X is at least one halide, and a cathode including a cathode current collector having a cathode Fermi energy lower than the anode Fermi energy. During operation of the electrochemical storage cell, the alkali metal plates dendrite-free from the solid electrolyte onto the alkali metal anode. Also during operation of the electrochemical storage cell, the alkali metal further plates on the cathode current collector.

The present invention provides an electrochemical cell that includes an anolyte compartment housing an anode electrode; a catholyte compartment housing a cathode electrode; and a solid alkali ion conductive electrolyte membrane separating the anolyte compartment from the cathode compartment. In some cases, the electrolyte membrane is selected from a sodium ion conductive electrolyte membrane and a lithium ion conductive membrane. In some cases, the at least one of anode or the cathode includes an alkali metal intercalation material.