An energy storage system includes a hermetically-sealed casing defining a volume whose relative humidity is a range of 30-90%. At least one energy storage capacitor disposed in the volume has a solid dielectric sandwiched between two electrodes with the solid dielectric being a lanthanum-doped barium titanate-based ceramic material.

A method for the formation of lithium includes a layer on a substrate using an atomic layer deposition method. The method includes the sequential pulsing of a lithium precursor through a reaction chamber for deposition upon a substrate. Using further oxidizing pulses and or other metal containing precursor pulses, an electrolyte suitable for use in thin film batteries may be manufactured.

An energy storage capacitor has a solid dielectric sandwiched between two electrodes. The solid dielectric is a lanthanum-doped barium titanate-based ceramic material. A dopant is selected from the group consisting of lanthanum hydroxide and lanthanum oxide, and a co-dopant is an alkali hydroxide selected from the group consisting of potassium hydroxide, sodium hydroxide, rubidium hydroxide, and lithium hydroxide.

A solid dielectric for an energy storage capacitor is a lanthanum-doped barium titanate-based ceramic material. A dopant is selected from the group consisting of lanthanum hydroxide and lanthanum oxide, and a co-dopant is an alkali hydroxide selected from the group consisting of potassium hydroxide, sodium hydroxide, rubidium hydroxide, and lithium hydroxide.

A multi-faceted zinc-air electrochemical cell design holistically leverages interactions between components, especially with respect to conductive carbons from differing sources, lamination and the resulting impact it has on the air electrode's surface and other additives that impact the relative hydrophilicity of the membrane and/or performance of the anode, to improve the overall reliability and performance of the resulting battery.

A multi-faceted zinc-air electrochemical cell design holistically leverages interactions between components, especially with respect to conductive carbons from differing sources, lamination and the resulting impact it has on the air electrode's surface and other additives that impact the relative hydrophilicity of the membrane and/or performance of the anode, to improve the overall reliability and performance of the resulting battery.

A method for manufacturing an all-solid battery that includes preparing a first green sheet as a green sheet for at least any one of a positive electrode layer and a negative electrode layer and a second green sheet as a green sheet for a solid electrolyte layer, stacking the first green sheet and the second green sheet to form a stacked body, and firing the stacked body with a setter placed in contact with at least one surface of the stacked body. The setter in contact with the at least one surface of the stacked body is 0.11 mRa or more and 50.13 mRa or less in surface roughness.

In accordance with the present invention, deposition of LiCoO.sub.2 layers in a pulsed-dc physical vapor deposition process is presented. Such a deposition can provide a low-temperature, high deposition rate deposition of a crystalline layer of LiCoO.sub.2 with a desired <101> or <003> orientation. Some embodiments of the deposition address the need for high rate deposition of LiCoO.sub.2 films, which can be utilized as the cathode layer in a solid state rechargeable Li battery, Embodiments of the process according to the present invention can eliminate the high temperature (>700 C.) anneal step that is conventionally needed to crystallize the LiCoO.sub.2 layer.

Provided are a transition metal mixed hydroxide comprising an alkali metal other than Li, SO.sub.4 and a transition metal element, wherein the molar ratio of the molar content of the alkali metal to the molar content of the SO.sub.4 is not less than 0.05 and less than 2, and a lithium mixed metal oxide obtained by calcining a mixture of the transition metal mixed hydroxide and a lithium compound by maintaining the mixture at a temperature of 650 to 1000 C.

An energy storage system includes a hermetically-sealed casing defining a volume whose relative humidity is a range of 30-90%. At least one energy storage capacitor disposed in the volume has a solid dielectric sandwiched between two electrodes with the solid dielectric being a lanthanum-doped barium titanate-based ceramic material.