A method of manufacturing an all-solid-state battery and an apparatus for manufacturing the same are provided. The method of manufacturing the all-solid-state battery includes: (a) a step of forming a non-woven fabric having a fiber made of a resin; (b) a step of applying a slurry containing solid electrolyte particles onto the non-woven fabric; (c) a step of drying the slurry on the non-woven fabric by a heater; (d) a step of pressurizing the slurry on the non-woven fabric by a roller; (e) a step of forming a positive electrode member on one surface of the solid electrolyte membrane; and (f) a step of forming a negative electrode member on the other surface of the solid electrolyte membrane. The step (a) is a step of forming the non-woven fabric by making a resin containing a polar filler fibrous by a laser electrospinning method. By such a method, the all-solid-state battery (a laminated body of a positive electrode member, a solid electrolyte membrane, and a negative electrode member) can be efficiently manufactured.

A flexible energy storage device with a glycerol-based gel electrolyte is provided. The flexible energy storage device can include a pair of electrodes separated by the gel electrolyte. The electrolytes can be in gel form, bendable and stretchable in a device. The gel electrolyte can include glycerol, redox-active molybdenum-containing ions, and a secondary ionic substance. The secondary ionic substance can include a salt. The gel electrolyte can have a density of 1.4 to 1.9 g/cm.sup.3 and an ionic conductivity of 2.3?10.sup.?4 to 3.2?10.sup.?4 Scm.sup.?1. The flexible energy storage device may retain greater than 95% of an unbent energy storage capacity when bent at an angle of 10 to 170?.

Semi-solid electrolyte compositions are disclosed. The semi-solid electrolyte compositions contain a glyme or mixture of glymes, a lithium salt(s), and a polymeric complexing agent(s).

A method of manufacturing an all-solid-state battery and an apparatus for manufacturing the same are provided. The method of manufacturing the all-solid-state battery includes: (a) a step of forming a non-woven fabric having a fiber made of a resin; (b) a step of applying a slurry containing solid electrolyte particles onto the non-woven fabric; (c) a step of drying the slurry on the non-woven fabric by a heater; (d) a step of pressurizing the slurry on the non-woven fabric by a roller; (e) a step of forming a positive electrode member on one surface of the solid electrolyte membrane; and (f) a step of forming a negative electrode member on the other surface of the solid electrolyte membrane. The step (a) is a step of forming the non-woven fabric by making a resin containing a polar filler fibrous by a laser electrospinning method. By such a method, the all-solid-state battery (a laminated body of a positive electrode member, a solid electrolyte membrane, and a negative electrode member) can be efficiently manufactured.

A flexible energy storage device with a glycerol-based gel electrolyte is provided. The flexible energy storage device can include a pair of electrodes separated by the gel electrolyte. The electrolytes can be in gel form, bendable and stretchable in a device. The gel electrolyte can include glycerol, redox-active molybdenum-containing ions, and a secondary ionic substance. The secondary ionic substance can include a salt. The gel electrolyte can have a density of 1.4 to 1.9 g/cm.sup.3 and an ionic conductivity of 2.310.sup.4 to 3.210.sup.4 Scm.sup.1. The flexible energy storage device may retain greater than 95% of an unbent energy storage capacity when bent at an angle of 10 to 170.

A thread battery that includes: a thread-like solid electrolyte that extends in a longitudinal direction between a first end and a second end that face each other in the longitudinal direction; a first electrode on a first part of an outer peripheral surface of the solid electrolyte along the longitudinal direction; a second electrode on a second part of the outer peripheral surface of the solid electrolyte along the longitudinal direction, wherein the first electrode and the second electrode do not contact each other; a first current collector on an outer peripheral surface of the first electrode along the longitudinal direction; and a second current collector on an outer peripheral surface of the second electrode along the longitudinal direction.

Semi-solid electrolyte compositions are disclosed. The semi-solid electrolyte compositions contain a glyme or mixture of glymes, a lithium salt(s), and a polymeric complexing agent(s).

A flexible energy storage device with a glycerol-based gel electrolyte is provided. The flexible energy storage device can include a pair of electrodes separated by the gel electrolyte. The electrolytes can be in gel form, bendable and stretchable in a device. The gel electrolyte can include glycerol, redox-active molybdenum-containing ions, and a secondary ionic substance. The secondary ionic substance can include a salt. The gel electrolyte can have a density of 1.4 to 1.9 g/cm.sup.3 and an ionic conductivity of 2.310.sup.4 to 3.210.sup.4 Scm.sup.1. The flexible energy storage device may retain greater than 95% of an unbent energy storage capacity when bent at an angle of 10 to 170.

A method is provided for making a ceramic lithium ion conducting membrane and for making an anode pouch for a lithium-seawater battery. The method for making the ceramic membrane includes adding pore formers into a liquid slurry of LTAP (Li.sub.2OAl.sub.2O.sub.3SiO.sub.2P.sub.2O.sub.5TiO.sub.2) powder. The liquid slurry is converted into porous green tape and the porous green tape is laminated onto the top of nonporous green tapes to form a stack. The stack is sintered and the pore formers are decomposed to create pores in the top layer of the ceramic membrane. The porous ceramic membrane is used to create a more robust hermetic seal in an anode pouch for the battery compared to a seal made with a nonporous ceramic membrane.

A laminate-type power storage element is configured of an exterior body that is formed in a flat bag shape by welding a first laminated film and a second laminated film by thermocompression bonding, and an electrode body that is sealed inside the exterior body, the electrode body having a sheet-shaped positive electrode and a sheet-shaped negative electrode. The first laminated film and the second laminated film respectively includes a first resin layer that has a property of transmitting a laser beam, a metal foil that is layered to the first resin layer, and a second resin layer is layered to the metal foil and has a thermal weldability.