A redox flow battery includes first and second cells. Each cell has electrodes and a separator layer arranged between the electrodes. A first circulation loop is fluidly connected with the first electrode of the first cell. A polysulfide electrolyte solution has a pH 11.5 or greater and is contained in the first recirculation loop. A second circulation loop is fluidly connected with the second electrode of the second cell. An iron electrolyte solution has a pH 3 or less and is contained in the second circulation loop. A third circulation loop is fluidly connected with the second electrode of the first cell and the first electrode of the second cell. An intermediator electrolyte solution is contained in the third circulation loop. The cells are operable to undergo reversible reactions to store input electrical energy upon charging and discharge the stored electrical energy upon discharging.

A redox flow battery includes first and second cells. Each cell has electrodes and a separator layer arranged between the electrodes. A first circulation loop is fluidly connected with the first electrode of the first cell. A polysulfide electrolyte solution has a pH 11.5 or greater and is contained in the first recirculation loop. A second circulation loop is fluidly connected with the second electrode of the second cell. An iron electrolyte solution has a pH 3 or less and is contained in the second circulation loop. A third circulation loop is fluidly connected with the second electrode of the first cell and the first electrode of the second cell. An intermediator electrolyte solution is contained in the third circulation loop. The cells are operable to undergo reversible reactions to store input electrical energy upon charging and discharge the stored electrical energy upon discharging.

An electrode assembly for a flow battery is disclosed comprising a porous electrode material, a frame surrounding the porous electrode material, at least a distributor tube embedded in the porous electrode material having an inlet for supplying electrolyte to the porous electrode material and at least another distributor tube embedded in the porous electrode material having an outlet for discharging electrolyte out of the porous material. The walls of the distributor tubes are preferably provided with holes or pores for allowing a uniform distribution of the electrolyte within the electrode material. The distributor tubes provide the required electrolyte flow path length within the electrode material to minimize shunt current flowing between the flow cells in the battery stack.

An electrode assembly for a flow battery is disclosed comprising a porous electrode material, a frame surrounding the porous electrode material, at least a distributor tube embedded in the porous electrode material having an inlet for supplying electrolyte to the porous electrode material and at least another distributor tube embedded in the porous electrode material having an outlet for discharging electrolyte out of the porous material. The walls of the distributor tubes are preferably provided with holes or pores for allowing a uniform distribution of the electrolyte within the electrode material. The distributor tubes provide the required electrolyte flow path length within the electrode material to minimize shunt current flowing between the flow cells in the battery stack.

A method of cleansing a redox flow battery system may include operating the redox flow battery system in a charge, discharge, or idle mode, and responsive to a redox flow battery capacity being less than a threshold battery capacity, mixing the positive electrolyte with the negative electrolyte. In this way, battery capacity degradation following cyclic charging and discharging of the redox flow battery system can be substantially reduced.

A method of cleansing a redox flow battery system may include operating the redox flow battery system in a charge, discharge, or idle mode, and responsive to a redox flow battery capacity being less than a threshold battery capacity, mixing the positive electrolyte with the negative electrolyte. In this way, battery capacity degradation following cyclic charging and discharging of the redox flow battery system can be substantially reduced.

A fuel cell system having a fuel cell cooling circuit coupled to a battery cooling circuit through a coolant/coolant heat exchanger for removing heat from the fuel cell cooling circuit through the battery cooling circuit during normal steady state operation of the fuel cell system.

A redox matched flow battery utilizes insoluble functionalized catholyte and anolyte beads to store charge on redox-active moieties tethered to the beads, with charge being transferred between the electrodes and the bead using a soluble, redox-matched mediator.

A redox flow battery and battery system are provided. In one example, the redox flow battery includes a set of pressure plates having a first pressure plate at a first terminal end and a second pressure plate at a second terminal end, the second terminal end and the first terminal end positioned on opposing longitudinal sides of the redox flow battery. The redox flow battery further includes a first cell stack positioned longitudinally between the first pressure plate and the second pressure plate, each of the first and second pressure plates includes a plurality stacking detents on a first flange and a plurality of stacking protrusions on a second flange, and the first flange and the second flange arranged on opposing vertical sides of the redox flow battery.

The invention relates to an electrode (1) for a flow battery (B) and a method for producing said electrode (1), wherein said electrode (1) comprises a first portion (12) consisting of particles (11) of electrically conductive material having nanometric dimensions, wherein said first portion (12) is mesoporous and its porosity is such as to increase the quantity of redox reactions per time unit in a flow of an electrolytic solution of said battery (B).