A fuel cell system according to one embodiment performs refresh control of an electrode catalyst of a fuel cell, by reducing a stack voltage as a voltage of the fuel cell to a refresh voltage at which the electrode catalyst is activated. The system includes the fuel cell that generates electric power by an electrochemical reaction using fuel gas and oxidation gas, a stack voltage sensor that sensors the stack voltage, and a controller that controls power of the fuel cell. When a high load demand that makes the stack voltage lower than a given voltage is made on the fuel cell, the controller causes the fuel cell to deliver power commensurate with the high load demand, and performs refresh control when the stack voltage becomes lower than the given voltage through the above control.

The present disclosure provides a method and apparatus to perform an electrochemical process by manipulating the charge on an electrode involved in the primary circuit of the electrochemical reaction. The amount of charge on the electrode can be manipulated independent of the bias voltage of the primary circuit and is accomplished by coupling the electrode with various different configurations.

A fuel cell module is configured or operated, or both, such that after a shut down procedure a fuel cell stack is discharged and has its cathode electrodes at least partially blanketed with nitrogen during at least some periods of time. If the fuel cell module is restarted in this condition, electrochemical reactions are limited and do not quickly re-charge the fuel cell stack. To decrease start up time, air is moved into the cathode electrodes before the stack is re-charged. The air may be provided by a pump, fan or blower driven by a battery or by the flow or pressure of stored hydrogen. For example, an additional fan or an operating blower may be driven by a battery until the fuel cell stack is able to supply sufficient current to drive the operating blower for normal operation.

Methods and circuits for a device for interrupting concentration-related polarisation phenomenon and for self-cleaning of electromembrane processes by application of asymmetric inverse-polarity pulses with high intensity and variable frequency are described. The device, a bipolar switch, is based on the use of solid-state electronics to carry out polarity inversion in a range of frequencies, intensities and pulse widths to prevent or reduce formation of precipitates on the surfaces of the membranes. The inversion protocol, with a frequency that varies as a function of the appearance of dirt on the membranes, as measured by the decrease in voltage or electrical resistance of the membrane cell during electromembrane processes, is also provided. This device and configuration provides application of modulated and stable high-intensity pulses using a second power source. Electromembrane processes can be updated by replacing electrodes, suitable for polarity inversion, and adding a second power source and the bipolar switch described.

A method is disclosed for regenerating an electrode of a flow battery. The method can be executed during shutdown of the flow battery from an active charge/discharge mode to an inactive, shut-down mode in which neither a negative electrolyte nor a positive electrolyte are circulated through at least one cell of the flow battery. The method includes driving voltage of the least one cell of the flow battery toward zero by converting, in-situ, the negative electrolyte in the at least one cell to a higher oxidation state. The negative electrolyte is in contact with an electrode of the at least one cell. The higher oxidation state negative electrolyte is used to regenerate, in-situ, catalytically active surfaces of the electrode of the at least one cell.

A fuel cell purging method is provided to effectively prevent fuel cell deterioration and degradation of durability of the fuel cell by performing hydrogen purging at a point in time at which negative pressure of an anode peaks after a fuel cell vehicle is stopped. The fuel cell purging method includes stopping the driving of a fuel cell vehicle and continuously measuring pressure of an anode of a fuel cell after the fuel cell vehicle is stopped. Additionally, hydrogen is supplied to the anode when the measured pressure of the anode reaches a negative pressure peak time point.

A fuel cell system of the present disclosure performs a first and a second catalyst activation process, and the first catalyst activation process is performed where a flow rate of the air supplied to the fuel cell by the air compressor is reduced to be less than that before the refresh control is performed while keeping an amount of a current drawn from the fuel cell by the fuel cell converter at the same value as that before the refresh control is performed, and the second catalyst activation process is performed where the value of the current drawn from the fuel cell by the fuel cell converter is increased to be greater than that before the refresh control is performed while keeping the flow rate of the air supplied to the fuel cell by the air compressor at the same value as that before the refresh control is performed.

A fuel cell purging method is provided to effectively prevent fuel cell deterioration and degradation of durability of the fuel cell by performing hydrogen purging at a point in time at which negative pressure of an anode peaks after a fuel cell vehicle is stopped. The fuel cell purging method includes stopping the driving of a fuel cell vehicle and continuously measuring pressure of an anode of a fuel cell after the fuel cell vehicle is stopped. Additionally, hydrogen is supplied to the anode when the measured pressure of the anode reaches a negative pressure peak time point.

The present invention is directed to a redox flow battery comprising at least one electrochemical cell in fluid communication with a balancing cell, said balancing cell comprising: a first and second half-cell chamber, wherein the first half-cell chamber comprises a first electrode in contact with a first aqueous electrolyte of the redox flow battery; and wherein the second half-cell chamber comprises a second electrode comprising a catalyst for the generation of O.sub.2; and wherein the second half-cell chamber does not contain an aqueous electrolyte.

A fuel cell module is configured or operated, or both, such that after a shut down procedure a fuel cell stack is discharged and has its cathode electrodes at least partially blanketed with nitrogen during at least some periods of time. If the fuel cell module is restarted in this condition, electrochemical reactions are limited and do not quickly re-charge the fuel cell stack. To decrease start up time, air is moved into the cathode electrodes before the stack is re-charged. The air may be provided by a pump, fan or blower driven by a battery or by the flow or pressure of stored hydrogen. For example, an additional fan or an operating blower may be driven by a battery until the fuel cell stack is able to supply sufficient current to drive the operating blower for normal operation.