A fuel cell system includes a fuel cell that includes an anode and a cathode and generates electricity by reducing a mediator at the cathode, a regenerator that oxidizes the mediator, a fuel gas feed path through which fuel gas to be supplied to the anode flows, a humidifier that is disposed in the fuel gas feed path and humidifies the fuel gas, and a water collection path that extends from the regenerator to the humidifier and guides to the humidifier at least one selected from steam produced at the regenerator and condensation formed from the steam.

A fuel cell system includes a removal treatment execution unit configured to execute an oxide layer removal treatment that removes an oxide layer generated on a catalyst of a fuel cell. The removal treatment execution unit is configured to execute the oxide layer removal treatment by adjusting a voltage of the fuel cell to be within a predetermined second voltage range lower than a predetermined first voltage range that is lower than an open-circuit voltage, when an operation of the fuel cell system shifts from a first operation, where a current value of the fuel cell is zero and the flow rate is controlled to maintain the voltage of the fuel cell within the first voltage range, to a second operation, where the current value is larger than zero and the flow rate is controlled in response to an output request to the fuel cell.

A fuel cell reversal event is diagnosed by integrating current density via a controller in response to determine an accumulated charge density. The controller executes a control action when the accumulated charge density exceeds a threshold, including recording a diagnostic code indicative of event severity. The control action may include continuing stack operation at reduced power capability when the accumulated charge density exceeds a first threshold and shutting off the stack when the accumulated charge density exceeds a higher second threshold. The event may be detected by calculating a voltage difference between an average and a minimum cell voltage, and then determining if the difference exceeds a voltage difference threshold. The charge density thresholds may be adjusted based on age, state of health, and/or temperature of the fuel cell or stack. A fuel cell system includes the stack and controller.

The present invention is directed to a redox flow battery comprising at least one electrochemical cell in fluid communication with a balancing cell, said balancing cell comprising: a first and second half-cell chamber, wherein the first half-cell chamber comprises a first electrode in contact with a first aqueous electrolyte of the redox flow battery; and wherein the second half-cell chamber comprises a second electrode comprising a catalyst for the generation of O.sub.2; and wherein the second half-cell chamber does not contain an aqueous electrolyte.

A fuel cell system comprises an electrochemical fuel cell stack for generating electrical power. A load circuit is switchably coupled to the fuel cell stack for periodically receiving a discharge current from the fuel cell stack during an energy dissipation phase, such as an air stall operation for conditioning the fuel cell stack. A protection circuit is coupled to the load circuit, configured to monitor a cumulative energy dissipation level during an energy dissipation phase and to abort an energy dissipation phase if the cumulative energy level reaches a predetermined threshold. In this way, lower specification resistor components can be used for stack conditioning.

A fuel cell system and a method of operating the same is provided that is capable of reducing degradation of a cathode catalyst of a fuel cell. A fuel cell system is provided that includes a fuel cell having a catalyst used for an anode, wherein a carrier of the catalyst is composed of a material with a property where electric resistance in an oxygen containing atmosphere is greater than electric resistance in a hydrogen atmosphere; and a control device configured to control the fuel cell, when supply of fuel gas is stopped during stoppage of operation of the fuel cell, to consume all or part of the fuel gas in a fuel gas chamber, followed by introducing oxygen containing gas into the fuel gas chamber.

A fuel cell system includes: a fuel cell; a voltage regulator that regulates an output voltage of the fuel cell; and a controller configured to perform a refresh process of decreasing the output voltage of the fuel cell to a reduction voltage at which an oxide film formed on the cathode is reduced, by controlling the voltage regulator. The controller, before the refresh process, calculates a first amount, the first amount being an amount by which the oxide film is to be removed from the cathode. The controller determines, as the output voltage of the fuel cell, a refresh voltage that enables the first amount of the oxide film to be removed within a preset reference time. The controller operates the voltage regulator so as to cause the output voltage of the fuel cell to become the refresh voltage when the refresh process is performed.

A method for recovering performance of a degraded polymer electrolyte fuel cell stack through electrode reversal. In detail, oxide films formed on the surface of platinum of a cathode is removed through an electrode reversal process that creates a potential difference between an anode and the cathode by supplying air to the anode instead of hydrogen and supplying a fuel to the cathode instead of air, thus rapidly recovering the performance of a degraded polymer electrolyte fuel cell stack.

The fuel cell system of the present disclosure includes: a fuel cell that includes a membrane electrode assembly including a proton conducting ceramic electrolyte membrane, a cathode disposed on a first surface of the electrolyte membrane, and an anode disposed on a second surface of the electrolyte membrane, the fuel cell generating electric power through an electrochemical reaction using a fuel gas and an oxidant gas; a power source that applies a voltage to the fuel cell; and a controller. In a shutdown process, the controller controls the power source to apply the voltage to the fuel cell such that a terminal voltage of the fuel cell is equal to or higher than an open circuit voltage of the fuel cell.

A system and method of controlling a performance of a fuel cell stack is provided. In particular, the output performance of the fuel cell stack is determined by comparing the difference between an initial voltage and a voltage after a predetermined time lapses with the difference between the initial voltage and a preset minimum voltage.