A modular fuel cell system includes a base, at least four power modules arranged in a row on the base, and a fuel processing module and power conditioning module arranged on at least one end of the row on the base. Each power module includes a separate cabinet which contains at least one fuel cell stack located in a hot box. The power modules are electrically and fluidly connected to the at least one fuel processing and power conditioning modules through the base.

A non-catalytic hydrogen generation process is provided that supplies hydrogen to a hydrodesulfurization unit and a solid oxide fuel cell system combination, suitable for auxiliary power unit application. The non-catalytic nature of the process enables use of sulfur containing feedstock for generating hydrogen which is needed to process the sulfur containing feed to specifications suitable for the solid oxide fuel cell. Also, the non-catalytic nature of the process with fast dynamic characteristics is specifically applicable for startup and shutdown purposes that are typically needed for mobile applications.

A fuel cell system includes: a fuel cell; a reformer to generate a hydrogen-containing gas; an electric power generation raw material supply unit; a reforming material supply unit configured to supply at least one of reforming water and reforming air, to the reformer; an oxidizing gas supply unit to supply an oxidizing gas to a cathode of the fuel cell; a combustor to ignite an exhaust gas discharged from the fuel cell; and a controller. In an operation stop process of the fuel cell system, the controller causes the oxidizing gas supply unit to supply the oxidizing gas, causes the electric power generation raw material supply unit and the reforming material supply unit to intermittently supply the electric power generation raw material and at least one of the water and the air to the reformer, and causes the ignitor to perform an ignition operation.

A fuel cell module according to the present embodiment includes a hydrodesulfurizer, a cell stack, an exhaust gas channel portion, and an air-preheating channel portion. The hydrodesulfurizer is configured to desulfurize fuel gas using a hydrodesulfurization catalyst. A reformer is configured to generate a hydrogen-containing gas. The cell stack is constituted by stacking a plurality of fuel cells and is configured to generate electric power. The exhaust gas channel portion is configured to discharge the hydrogen-containing gas, and discharge exhaust gas that is generated by the combustion of the oxygen-containing gas. The air-preheating channel portion is an air-preheating channel portion that is disposed so as to be adjacent to the exhaust gas channel portion and that is configured to preheat the oxygen-containing gas through heat exchange with the exhaust gas channel portion. The air-preheating channel portion is disposed between the hydrodesulfurizer and the cell stack.

A system and method for synthesizing a nanoparticle material includes dissolving a metal nitrate in deionized water, adding a hydrogel precursor in the deionized water containing the dissolved metal nitrate to create an aqueous solution, heating the aqueous solution, cooling the aqueous solution to create a solid gel, and calcinating the solid gel to create a metal oxide nanoparticle material. The metal oxide nanoparticle material may include a zinc oxide-based nanoparticle material. The hydrogel precursor may include an agarose gel. The solid gel may be calcinated at approximately 600 C. The solid gel may be calcinated for approximately five hours in the presence of air. The aqueous solution may be heated to a boil. The aqueous solution may be heated at a temperature of 100 C.

A biogas collection and purification system that includes a plurality of sources of biogas and a network of conduits configured to convey the biogas from the sources to a central processing facility for processing the biogas into methane. The central processing facility removes impurities to convert biogas to biomethane and may include an H.sub.2S removal stage; an activated carbon scrubber; a gas drier; and a carbon dioxide removal stage. The facility also has a biomethane gas compressor configured to deliver the biomethane for use in power plants, for CNG production. Ancillaries to the system include fuel cells for direct electricity generation from biogas/biomethane.

A system including biogas purification and provides biogas as feedstock to a solid oxide fuel cell. The biogas purification treatment process provides a polished biogas that is substantially free of carbonyl sulfides and hydrogen sulfide. The system uses a biogas treatment apparatus, that includes apparatus such as a packed columns, comprising copper oxide or potassium permanganate packing material, and an activated carbon component configured to treat the biogas by polishing it to remove carbonyl sulfides and deleterious trace residues, such as hydrogen sulfide, that were not removed by any prior bulk H2S removal steps. In addition, an oil removal device is used to remove any entrained fine oil droplets in the biogas. A polished biogas having in the range of 60% methane is charged to the fuel cell. Electricity generated may be fed into a grid or used directly as energy to charge electrical-powered vehicles, for example. Energy credits are tracked in real time and are appropriately assigned.

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A fuel cell system includes: a fuel cell; a reformer to generate a hydrogen-containing gas; an electric power generation raw material supply unit; a reforming material supply unit configured to supply at least one of reforming water and reforming air, to the reformer; an oxidizing gas supply unit to supply an oxidizing gas to a cathode of the fuel cell; a combustor to ignite an exhaust gas discharged from the fuel cell; and a controller. In an operation stop process of the fuel cell system, the controller causes the oxidizing gas supply unit to supply the oxidizing gas, causes the electric power generation raw material supply unit and the reforming material supply unit to intermittently supply the electric power generation raw material and at least one of the water and the air to the reformer, and causes the ignitor to perform an ignition operation.

Methods are disclosed to provide balance of plant for an electrochemical reactor. The methods include forming a vessel, wherein the vessel has at least a wall and an internal space configured to contain the reactor; forming fluid channels in or attached to at least a portion of the wall of the vessel, and where the fluid channels are configured to be in fluid communication with the reactor.

A fuel cell system including power modules including fuel cells, and an exhaust flue connected to the power modules. The exhaust flue includes an outer duct configured to receive relatively cool cabinet exhaust from the power modules, and an inner duct disposed inside of the outer duct and configured to receive relatively hot reaction exhaust from the power modules.