The compression apparatus includes an electrolyte membrane, an anode on a principal surface of the electrolyte membrane, a cathode on another principal surface of the electrolyte membrane, an anode separator on the anode, a cathode separator on the cathode, and a voltage applicator. Upon the voltage applicator applying the voltage between the anode and the cathode, protons are extracted from an anode fluid fed onto the anode to migrate onto the cathode through the electrolyte membrane and compressed hydrogen is produced. The cathode separator has a first manifold hole and a first O-ring groove surrounding the first manifold hole. The compression apparatus includes a first O-ring held by the first O-ring groove and a face seal disposed on an outer periphery of a region of an anode-side principal surface of the anode separator which faces the anode. The first O-ring is arranged to abut against the anode-side principal surface.

A fuel cell system includes at least one hot box including a fuel cell stack and producing an anode exhaust product, at least one hydrogen pump, at least one product conduit fluidly connecting an anode exhaust product outlet of the hot box to an inlet of the at least one hydrogen pump, a compressed hydrogen product conduit connected to a compressed hydrogen product outlet of the at least one hydrogen pump, and at least one effluent conduit connected to an unpumped effluent outlet of the at least one hydrogen pump. Additional embodiments include a fuel cell system in which the anode exhaust product stream is provided to at least one carbon dioxide pump to generate a compressed carbon dioxide product and an unpumped effluent that may be recycled to the at least one hot box of the fuel cell system. In various embodiments, the fuel cell system may use or recapture essentially all of the hydrogen content and nearly all of the carbon content of the input fuel that is provided to the fuel cell system.

Processes and systems that utilize a fuel cell for carbon capture from a petrochemical stream that contains hydrogen and methane. The petrochemical stream can be the tail gas of a hydrocarbon cracking system, or any other petrochemical stream containing hydrogen and methane. The petrochemical stream can be separated into a hydrogen product stream and a methane product stream, before sending the methane product stream to the fuel cell. The fuel cell converts methane to carbon dioxide and hydrogen to water, while generating electricity that can be used to power equipment.

A load-following fuel cell system for a grid system operating with a high penetration of intermittent renewable energy sources includes a baseload power generation module and a load-following power generation module. The baseload power generation module provides a baseload power to the grid system and includes a high-efficiency fuel cell system. The high-efficiency fuel cell system includes a topping module and a bottoming module. The topping module and the bottoming module are connected in series and the topping module provides an exhaust stream to the bottoming module. The load-following power generation module provides a load-following power to the grid system and includes an energy storage system that separates and stores hydrogen contained in the exhaust stream and a power generation system having one or more fuel cells. The power generation system receives the hydrogen from the energy storage system to provide the load-following power.

A carbon dioxide capture system for capturing carbon dioxide from an exhaust stream. The system may include a fuel cell configured to output a first exhaust stream comprising carbon dioxide and water. The system may further include an electrolyzer cell configured to receive a first portion of the first exhaust stream and output a second exhaust stream comprising oxygen and carbon dioxide. The fuel cell may be a solid oxide fuel cell. The electrolyzer cell may be a molten carbonate electrolysis cell.

The present disclosure is directed to a compressed fuel storage system. The compressed fuel storage system may include an electrochemical compressor and one or more fuel dispensing units. The electrochemical compressor may be configured to compress a fuel source. Additionally, the compressed fuel storage system may include at least one low pressure compressed fuel reservoir fluidly connected to the electrochemical compressor and the fuel dispensing units and at least one high pressure compressed fuel reservoir fluidly connected to the electrochemical compressor and the fuel dispensing units.

An energy storage system for an electrical grid running on a renewable energy source includes a baseload power module, a waste converter module, and a load-following power module. The baseload power module includes a first fuel cell system configured to provide a baseload power to the electrical grid. The waste converter module is configured to extract and store hydrogen from an exhaust stream produced by the first fuel cell system. The load-following power module includes a second fuel cell system configured to receive hydrogen from the waste converter module and convert the hydrogen to electrical energy to support the electrical grid.

Embodiments of a method of removing carbonaceous deposits in a liquid-hydrocarbon fueled solid oxide fuel cell and related system are provided. The method includes providing a solid oxide fuel cell system having an anode, a cathode, a solid oxide electrolyte oriented between the anode and cathode, an amplifier cathode disposed proximate the solid oxide electrolyte and the cathode, a fuel cell electric circuit electrically connecting the anode and the cathode, and an amplifier electric circuit electrically connecting the anode and the amplifier cathode. Further, operating the amplifier electric circuit in an electrolytic mode to electrically power the amplifier cathode, wherein the amplifier cathode generates and supplies O.sup.2 or CO.sub.3.sup.2 to the anode. The method further includes removing the carbonaceous deposits on the anode by converting the carbonaceous deposits to carbon dioxide gas via reaction with the O.sup.2 or CO.sub.3.sup.2 and expelling the carbon dioxide gas.

An electrochemical system includes a hydrogen diffusion barrier physically separating the system into a hydrogen rich zone and a hydrogen poor zone, an electronic component located in the hydrogen poor zone and exposed to hydrogen diffusing from the hydrogen rich zone, a hydrogen pump, located in the hydrogen rich zone and the hydrogen poor zone, including: a cathode, an anode, an electrolyte separating the cathode and the anode, an anode encapsulation contacting the anode and a portion of the electrolyte, and an external electrical circuit biased to drive H+ current from the anode to the cathode to pump hydrogen diffusing from the hydrogen rich zone into the hydrogen poor zone back into the hydrogen rich zone.

An electrochemical hydrogen pump includes an electrolyte membrane having a pair of primary surfaces; a cathode catalyst layer provided on one primary surface of the electrolyte membrane; an anode catalyst layer provided on the other primary surface of the electrolyte membrane; a cathode gas diffusion layer provided on the cathode catalyst layer; an anode gas diffusion layer provided on the anode catalyst layer; and a voltage application device applying a voltage between the cathode catalyst layer and the anode catalyst layer, The anode gas diffusion layer includes a laminate of metal sheets which are provided with vents, and among the metal sheets, the maximum diameter of vents provided in a first metal sheet adjacent to the anode catalyst layer is smaller than the maximum diameter of vents provided in a second metal sheet adjacent to the first metal sheet.