This invention provides an electrochemical system for manufacturing methanol from methane in good yields and without admixtures of methanol oxidation products. A fuel cell for methane or methanol utilization is also provided.

A direct alcohol fuel cell having a proton exchange membrane (PEM) separating an anode section from a cathode section, which cathode section contains a cathode collection element electrically connected to a cathode catalyst, the cathode catalyst being in diffusive communication with a gaseous oxidant, and which anode section comprises an anode collection element electrically connected to an anode catalyst. The anode catalyst is in diffusive communication with a fuel supply. The PEM is structured to have a bottom and walls extending from the bottom to a containment distance into the cathode section, and the cathode catalyst is located within the containment distance from the bottom. The fuel cell is suited for a microelectronic device.

A direct alcohol fuel cell having a proton exchange membrane (PEM) separating an anode section from a cathode section, which cathode section contains a cathode collection element electrically connected to a cathode catalyst, the cathode catalyst being in diffusive communication with a gaseous oxidant, and which anode section comprises an anode collection element electrically connected to an anode catalyst. The anode catalyst is in diffusive communication with a fuel supply. The PEM is structured to have a bottom and walls extending from the bottom to a containment distance into the cathode section, and the cathode catalyst is located within the containment distance from the bottom. The fuel cell is suited for a microelectronic device.

A direct alcohol fuel cell having an inner housing, and a proton exchange membrane separating an anode section from a cathode section. The anode section contains an anode collection element electrically connected to an anode catalyst that is in diffusive communication with a fuel supply. The cathode section contains a cathode collection element having one or more ventilation holes is electrically connected to a cathode catalyst. An oleophobic filter and/or an anion-exchange membrane is provided, which cathode catalyst via the one or more ventilation holes and the oleophobic filter and/or the anion-exchange membrane is in diffusive communication with a gaseous oxidant. The inner housing has a bottom and walls extending from the bottom to contain the anode section, the PEM and the cathode section, the bottom and/or the walls having holes allowing fluid communication from a fuel supply to the anode section. The fuel cell is suited for microelectronic devices.

A direct alcohol fuel cell having an inner housing, and a proton exchange membrane separating an anode section from a cathode section. The anode section contains an anode collection element electrically connected to an anode catalyst that is in diffusive communication with a fuel supply. The cathode section contains a cathode collection element having one or more ventilation holes is electrically connected to a cathode catalyst. An oleophobic filter and/or an anion-exchange membrane is provided, which cathode catalyst via the one or more ventilation holes and the oleophobic filter and/or the anion-exchange membrane is in diffusive communication with a gaseous oxidant. The inner housing has a bottom and walls extending from the bottom to contain the anode section, the PEM and the cathode section, the bottom and/or the walls having holes allowing fluid communication from a fuel supply to the anode section. The fuel cell is suited for microelectronic devices.

The present invention relates to a method of altering the relative proportions of protons, deuterons and tritons in a sample using a membrane. The membrane comprises a 2D material and an ionomer. The invention also relates to a method of making said membranes.

A system and method for refuelling a fuel cell having a fuel reservoir. The system includes a cartridge (1) having a first reservoir (2) for storing fuel for the fuel cell and a refuelling unit adapted to receive a waste liquid from the fuel reservoir of the fuel cell and provide fuel from the first reservoir (2) of the cartridge (1) to the fuel reservoir of the fuel cell. The system further includes a second reservoir for storing the waste liquid from the fuel cell, a cartridge for use with the system, a refuelling unit for use with the system.

A method for the manufacture of an oxygen reduction reaction (ORR) catalyst, the method comprising; providing a metal organic framework (MOF) material having a specific internal pore volume of 0.7 cm.sup.3g.sup.−1 or greater; providing a source of iron and/or cobalt; pyrolysing the MOF material together with the source of iron and/or cobalt to form the catalyst, wherein the MOF material comprises nitrogen and/or the MOF material is pyrolysed together with a source of nitrogen and the source of iron and/or cobalt is disclosed.

A preparation method of a direct ethanol fuel cell includes synthesizing electrolytes, preparing a cathode and an anode, and clamping the electrolytes between the cathode and the anode to get direct ethanol fuel cell. The electrolytes are synthesized by polymerizing sodium acrylate with an initiator to get a hydrogel, and the hydrogel is soaked in a harsh alkaline solution. The cathode is synthesized by coating N,S codoped carbon catalyst onto a current collector, where the N,S codoped carbon catalyst is synthesized by mixing and preheating silica powder, sucrose and trithiocyanuric acid to get a mixed powder, and mixing and heating the mixed powder with poly tetra fluoroethylene so as to get the N,S codoped carbon catalyst. The anode is synthesized by coating Pt-Ru/C catalyst onto a current collector.

A preparation method of a direct ethanol fuel cell includes synthesizing electrolytes, preparing a cathode and an anode, and clamping the electrolytes between the cathode and the anode to get direct ethanol fuel cell. The electrolytes are synthesized by polymerizing sodium acrylate with an initiator to get a hydrogel, and the hydrogel is soaked in a harsh alkaline solution. The cathode is synthesized by coating N,S codoped carbon catalyst onto a current collector, where the N,S codoped carbon catalyst is synthesized by mixing and preheating silica powder, sucrose and trithiocyanuric acid to get a mixed powder, and mixing and heating the mixed powder with poly tetra fluoroethylene so as to get the N,S codoped carbon catalyst. The anode is synthesized by coating Pt-Ru/C catalyst onto a current collector.