A system is disclosed for providing inerting gas to a protected space, and also providing electrical power. The system includes an electrochemical cell comprising a cathode and an anode separated by a separator comprising a proton transfer medium. Inerting gas is produced at the cathode. A fuel source comprising methanol or formaldehyde or ethanol and a water source are each in controllable operative fluid communication with the anode. A controller is configured to alternatively operate the system in a first mode of operation where water is directed to the anode fluid flow path inlet and electric power is directed from a power source to the electrochemical cell, and in a second mode of operation in which the fuel is directed from the fuel source to the anode fluid flow path inlet and electric power is directed from the electrochemical cell to the power sink.

A fuel cell system having a direct liquid fuel cell that uses a liquid containing a formic acid or an alcohol as a fuel includes: a fuel tank that stores the fuel to be supplied to the fuel cell; a fuel supply device that supplies the fuel in the fuel tank to the fuel cell; and a bubbling device that blows an inert gas into the fuel stored in the fuel tank.

A fuel cell system having a direct liquid fuel cell that uses a liquid containing a formic acid or an alcohol as a fuel includes: a fuel tank that stores the fuel to be supplied to the fuel cell; a fuel supply device that supplies the fuel in the fuel tank to the fuel cell; and a bubbling device that blows an inert gas into the fuel stored in the fuel tank.

A reformer assembly includes a vortex tube receiving heated fuel mixed with steam. A catalyst coats the inner wall of the main tube of the vortex tube and a hydrogen-permeable tube is positioned in the middle of the main tube coaxially with the main tube. With this structure the vortex tube outputs primarily Hydrogen from one end and Carbon-based constituents from the other end. In some embodiments a second vortex tube receives the Carbon output of the first vortex tube to establish a water gas shift reactor, producing Hydrogen from the Carbon output of the first vortex tube.

A reformer assembly includes a vortex tube receiving heated fuel mixed with steam. A catalyst coats the inner wall of the main tube of the vortex tube and a hydrogen-permeable tube is positioned in the middle of the main tube coaxially with the main tube. With this structure the vortex tube outputs primarily Hydrogen from one end and Carbon-based constituents from the other end. In some embodiments a second vortex tube receives the Carbon output of the first vortex tube to establish a water gas shift reactor, producing Hydrogen from the Carbon output of the first vortex tube.

Stabilized surfactant-based membranes and methods of manufacture thereof. Membranes comprising a stabilized surfactant mesostructure on a porous support may be used for various separations, including reverse osmosis and forward osmosis. The membranes are stabilized after evaporation of solvents; in some embodiments no removal of the surfactant is required. The surfactant solution may or may not comprise a hydrophilic compound such as an acid or base. The surface of the porous support is preferably modified prior to formation of the stabilized surfactant mesostructure. The membrane is sufficiently stable to be utilized in commercial separations devices such as spiral wound modules. Also a stabilized surfactant mesostructure coating for a porous material and filters made therefrom. The coating can simultaneously improve both the permeability and the filtration characteristics of the porous material.

Provided are membranes useful for electrochemical or fuel cells. A membrane may be formed of or include a sulfonated polymer whereby the sulfonated polymer is covalently or ionically associated with a multi-nitrogen containing heterocyclic molecule. The resulting membranes possess excellent ion conductivity and selectivity.

Provided are membranes useful for electrochemical or fuel cells. A membrane may be formed of or include a sulfonated polymer whereby the sulfonated polymer is covalently or ionically associated with a multi-nitrogen containing heterocyclic molecule. The resulting membranes possess excellent ion conductivity and selectivity.

Provided is an apparatus containing, as a cathode catalyst, a metal oxide/carbon catalyst composition. The metal oxide/carbon catalyst composition includes 40 to 95 wt % porous Mn—Co spinel oxide nanoparticles of the formula Mn.sub.xCo.sub.3-xO.sub.4. The nanoparticles have an octahedral morphology, an average particle size of 5-100 nm, and average pore sizes of 1-5 nm (where x is the atomic fraction of manganese and 3-x is the atomic fraction of cobalt). The metal oxide nanoparticles are supported on a carbon substrate that contains at least 96 atomic % carbon.

A direct methanol fuel cell includes a cathode electrode, an anode electrode and a membrane located between the anode electrode and the cathode electrode. An anode hydrophilic microporous plate (HMP) is located at an anode side of the fuel cell. The anode HMP has a front side and a back side opposite the front side, and the front side is positioned closer to the anode electrode than the back side. An anode gas diffusion layer is located in an anode chamber defined between the anode electrode and the anode HMP. A flow of methanol fuel is introduced into the back side of the anode hydrophilic microporous plate or to the anode chamber.