A fuel cell system including: an electrochemical pump including a first anode, a first cathode, and a first electrolyte membrane including a proton conductive oxide, the electrochemical pump separating hydrogen from a gas containing the hydrogen, and a solid oxide fuel cell that includes a second anode, a second cathode, and a second electrolyte membrane including a solid oxide electrolyte, and that generates electricity by reacting a fuel gas and an oxidant gas with each other.

A fuel cell system including: an electrochemical pump including a first anode, a first cathode, and a first electrolyte membrane including a proton conductive oxide, the electrochemical pump separating hydrogen from a gas containing the hydrogen, and a solid oxide fuel cell that includes a second anode, a second cathode, and a second electrolyte membrane including a solid oxide electrolyte, and that generates electricity by reacting a fuel gas and an oxidant gas with each other.

A planar SOFC cell unit is formed from a plurality of planar elements (1100, 1200, 1300) stacked one above another. The cell unit encloses a cell chamber (1400) that includes a solid oxide fuel cell (2000) configured for electro-chemical generation, compliantly supported within the cell chamber. The plurality planar elements each comprise a thermally conductive material having a co-efficient of thermal conductivity that is a least 100 W/mK such as aluminum or copper. The planar elements are thermally conductively coupled to each other to provide a continuous thermally conductive pathway that extends from perimeter edges of the cell chamber to perimeter edges of the plurality of planar elements. An SOFC stack comprises a plurality of the planar SOFC cell units stacked one above another.

A method and a system for the coproduction of hydrogen, electrical power, and heat energy. An exemplary method includes desulfurizing a feed stream to form a desulfurized feed stream, reforming the desulfurized feed stream to form a methane rich gas, and providing the methane rich gas to a membrane separator. A hydrogen stream is produced in a permeate from the membrane separator. A retentate stream from the membrane separator is provided to a solid oxide fuel cell (SOFC). Electrical power is produced in the SOFC from the retentate stream.

A method and a system for the coproduction of hydrogen, electrical power, and heat energy. An exemplary method includes desulfurizing a feed stream to form a desulfurized feed stream, reforming the desulfurized feed stream to form a methane rich gas, and providing the methane rich gas to a membrane separator. A hydrogen stream is produced in a permeate from the membrane separator. A retentate stream from the membrane separator is provided to a solid oxide fuel cell (SOFC). Electrical power is produced in the SOFC from the retentate stream.

A method of operating a fuel cell system includes providing fuel and air to a stack of fuel cells located in a hotbox, operating the stack to generate an anode exhaust and a cathode exhaust, in a startup mode, providing a first amount of the anode exhaust and the cathode exhaust to an anode tail gas oxidizer (ATO) located in the hotbox to oxidize the anode exhaust and to generate heat which is provided to the stack, and in a steady-state mode, stopping providing the anode exhaust to the ATO or providing to the ATO a second amount of the anode exhaust which is smaller than the first amount, and providing the anode exhaust and the cathode exhaust outside the hotbox.

A method of operating a fuel cell system includes providing fuel and air to a stack of fuel cells located in a hotbox, operating the stack to generate an anode exhaust and a cathode exhaust, in a startup mode, providing a first amount of the anode exhaust and the cathode exhaust to an anode tail gas oxidizer (ATO) located in the hotbox to oxidize the anode exhaust and to generate heat which is provided to the stack, and in a steady-state mode, stopping providing the anode exhaust to the ATO or providing to the ATO a second amount of the anode exhaust which is smaller than the first amount, and providing the anode exhaust and the cathode exhaust outside the hotbox.

A fuel cell interconnect includes fuel ribs disposed on a first side of the interconnect and a least partially defining fuel channels, and air ribs disposed on an opposing second side of the interconnect and at least partially defining air channels. The fuel channels include central fuel channels disposed in a central fuel field and peripheral fuel channels disposed in peripheral fuel fields disposed on opposing sides of the central fuel field. The air channels include central air channels disposed in a central air field and peripheral air channels disposed in peripheral air fields disposed on opposing sides of the central air field. At least one of the central fuel channels or the central air channels has at least one of a different cross-sectional area or length than at least one of the respective peripheral fuel channels or the respective peripheral air channels.

A fuel cell interconnect includes fuel ribs disposed on a first side of the interconnect and a least partially defining fuel channels, and air ribs disposed on an opposing second side of the interconnect and at least partially defining air channels. The fuel channels include central fuel channels disposed in a central fuel field and peripheral fuel channels disposed in peripheral fuel fields disposed on opposing sides of the central fuel field. The air channels include central air channels disposed in a central air field and peripheral air channels disposed in peripheral air fields disposed on opposing sides of the central air field. At least one of the central fuel channels or the central air channels has at least one of a different cross-sectional area or length than at least one of the respective peripheral fuel channels or the respective peripheral air channels.

An example fuel cell stack component includes a metallic layer applied to the component and an oxide layer applied to the metallic layer. The oxide layer includes a chemical component that is not in the metallic layer.